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    Volume 48 Issue 9
    Sep.  2023
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    Li Wenqi, Liu Huichuan, Li Pingping, Ni Zhiyong, Wang Yiren, 2023. Diverse Fluids in Dolomitization and Petrogenesis of the Dengying Formation Dolomite in the Sichuan Basin, SW China. Earth Science, 48(9): 3360-3377. doi: 10.3799/dqkx.2022.126
    Citation: Li Wenqi, Liu Huichuan, Li Pingping, Ni Zhiyong, Wang Yiren, 2023. Diverse Fluids in Dolomitization and Petrogenesis of the Dengying Formation Dolomite in the Sichuan Basin, SW China. Earth Science, 48(9): 3360-3377. doi: 10.3799/dqkx.2022.126

    Diverse Fluids in Dolomitization and Petrogenesis of the Dengying Formation Dolomite in the Sichuan Basin, SW China

    doi: 10.3799/dqkx.2022.126
    • Received Date: 2022-03-07
      Available Online: 2023-10-07
    • Publish Date: 2023-09-25
    • The dolomite in the Sinian Dengying Formation is a new and significant field for ultra-deep oil and gas exploration in the Sichuan basin. However, the forming model remains controversial without systematic research. In this study, detailed C-O-Sr and the rare earth element (REE) analyses were carried out on the Dengying Formation dolomites to investigate the geochemical characteristics and the source of dolomitization fluids, and further to constrain the differences of their origins. (1) The carbon isotopic values of the dolomites in the Dengying Formation are relatively homogeneous (0‰ to +5.0‰), while their oxygen isotopic values range widely. The dolomitic matrix and early dolomite cement in the near-surface realm show higher δ18O values than -8.0‰, δ18O values of the dolomite cement in the burial condition are more negative than -8.0‰, and those of the hydrothermal dolomite are more negative than -10.0‰. (2) The strontium isotopic ratios of the dolomitic matrix and early dolomite cement vary in a narrow range of 0.708-0.709, which is close to the Ediacaran marine carbonate, indicating the source of seawater. While those of dolomite cement in burial realm are more positive than the coeval seawater, indicating the source of formation fluids. (3) The dolomites in the Dengying Formation show depletion of light rare earth elements (LREEs) and enrichment of heavy rare earth elements (HREEs). The matrix and early dolomite cement have negative Ce anomalies with the absence of Eu anomalies, indicating a marine source. The dolomitic cements in the burial condition have negative Ce anomalies and significant positive Eu anomalies. The geochemical features and the origin of dolomitization fluids in different sedimentary environments are the essential factors controlling the formation of the Dengying Formation dolomite in the Sichuan basin. Dolomitization fluid in the near-surface environment is mainly derived from seawater, which is controlled by high-frequency sea-level fluctuations in an 'aragonite-dolomite sea' environment during the Sinian. By contrast, dolomitization fluids in burial environments are formation fluids and mantle-sourced hydrothermal fluid, which are mainly controlled by tectonic events. This research could facilitate further studies on the dolomite origin, the geochemical conditions of the terminal Neoproterozoic Ediacaran seawater, and the exploration and development of the ultra-deep oil and gas.

       

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