新疆喀什噶尔河下游平原区地下咸水中碘形态及碘富集成因

孙英; 周殷竹; 周金龙; 鲁涵; 葛婷婷; 纪媛媛

doi:10.3799/dqkx.2022.178

Volume 49 Issue 2

Feb. 2024

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Sun Ying, Zhou Yinzhu, Zhou Jinlong, Lu Han, Ge Tingting, Ji Yuanyuan, 2024. Iodine Species and Causes of Iodine Enrichment in Saline Groundwater in Plain Area of Lower Reaches of Kashigar River. Earth Science, 49(2): 781-792. doi: 10.3799/dqkx.2022.178

Citation:

Sun Ying, Zhou Yinzhu, Zhou Jinlong, Lu Han, Ge Tingting, Ji Yuanyuan, 2024. Iodine Species and Causes of Iodine Enrichment in Saline Groundwater in Plain Area of Lower Reaches of Kashigar River. Earth Science, 49(2): 781-792. doi: 10.3799/dqkx.2022.178

Citation:

Sun Ying, Zhou Yinzhu, Zhou Jinlong, Lu Han, Ge Tingting, Ji Yuanyuan, 2024. Iodine Species and Causes of Iodine Enrichment in Saline Groundwater in Plain Area of Lower Reaches of Kashigar River. Earth Science, 49(2): 781-792. doi: 10.3799/dqkx.2022.178

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Iodine Species and Causes of Iodine Enrichment in Saline Groundwater in Plain Area of Lower Reaches of Kashigar River

doi: 10.3799/dqkx.2022.178

Sun Ying^{1, 2, 3
,
,},
Zhou Yinzhu⁴,
Zhou Jinlong^{1, 2, 3
,
,
,},
Lu Han^{1, 2, 3},
Ge Tingting^{1, 2, 3},
Ji Yuanyuan^{1, 2, 3, 5}

1.
College of Water Conservancy and Civil Engineering, Xinjiang Agricultural University, Urumqi 830052, China
2.
Xinjiang Hydrology and Water Resources Engineering Research Center, Urumqi 830052, China
3.
Xinjiang Key Laboratory of Hydraulic Engineering Security and Water Disasters Prevention, Urumqi 830052, China
4.
Center for Hydrogeology and Environmental Geology, CGS, Baoding 071051, China
5.
Xinjiang Agricultural Professional Technological College, Changji 831100, China

Received Date: 2022-12-30
Publish Date: 2024-02-25

Abstract

Abstract

Kashgar River in Xinjiang is located in a typical arid and semi-arid area. The abnormal contents of total dissolved solids (TDS) and iodine in groundwater in the lower reaches of the river seriously threaten the local water security. Taking the plain area in the lower reaches of Kashigar River as the study area, the distribution of iodine in saline groundwater and its influence on iodine enrichment were determined through analysis of the hydrochemical characteristics, Cl/Br mole ratio, stable isotopes of hydrogen and oxygen, occurrence environment of groundwater and hydrogeochemical process. The results showed that the iodine content of groundwater in the study area varies from < 0.40 μg/L to 435.00 μg/L (mean 123.50 μg/L). The mean iodine content of unconfined groundwater and confined groundwater is 58.75 μg/L and 188.25 μg/L, respectively, and the proportion of high iodine groundwater is 25.0% and 75.0%, respectively. The main hydrochemical types are Cl·SO₄ and SO₄·Cl. TDS of groundwater ranged from 3 079.13 mg/L to 15 249.50 mg/L, mainly in neutral to slightly alkaline saline groundwater (87.5%), followed by saline groundwater (12.5%). The main form of iodine is I^- (87.5%), followed by IO₃^-(12.5%), and there is no coexistence form. The existence of iodine in IO₃^- and I^- forms in the suboxidizing environment and the subreducing environment is favorable, respectively. High TDS, fine lithology, gentle topography, shallow burial conditions of groundwater and alkaline environment are all conducive to the accumulation of iodine in groundwater. The iodine enrichment in unconfined groundwater is mainly affected by evaporation concentration and the dissolution of evaporite, while the iodine enrichment in confined groundwater is mainly affected by the dissolution of iron-bearing minerals under reduction conditions and alluvial-lacustrine sediments. The Cl^- to Cl/Br mole ratio indicates that the high iodine water in unconfined groundwater is obviously affected by evaporation.
- high iodine,
- Kashgar River,
- groundwater,
- saline groundwater,
- iodine species,
- hydrogeochemical process

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References(58)

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Iodine Species and Causes of Iodine Enrichment in Saline Groundwater in Plain Area of Lower Reaches of Kashigar River

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