地热水中多种甲基硫代砷酸盐的同时定量测定

郭清海; 孟越; 严克涛

doi:10.3799/dqkx.2022.250

Volume 48 Issue 3

Mar. 2023

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Guo Qinghai, Meng Yue, Yan Ketao, 2023. Simultaneous Quantitative Analysis of Multiple Methylthiolated Arsenates in Geothermal Water. Earth Science, 48(3): 1138-1145. doi: 10.3799/dqkx.2022.250

Citation:

Guo Qinghai, Meng Yue, Yan Ketao, 2023. Simultaneous Quantitative Analysis of Multiple Methylthiolated Arsenates in Geothermal Water. Earth Science, 48(3): 1138-1145. doi: 10.3799/dqkx.2022.250

Guo Qinghai, Meng Yue, Yan Ketao, 2023. Simultaneous Quantitative Analysis of Multiple Methylthiolated Arsenates in Geothermal Water. Earth Science, 48(3): 1138-1145. doi: 10.3799/dqkx.2022.250

Citation:

Guo Qinghai, Meng Yue, Yan Ketao, 2023. Simultaneous Quantitative Analysis of Multiple Methylthiolated Arsenates in Geothermal Water. Earth Science, 48(3): 1138-1145. doi: 10.3799/dqkx.2022.250

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Simultaneous Quantitative Analysis of Multiple Methylthiolated Arsenates in Geothermal Water

doi: 10.3799/dqkx.2022.250

Guo Qinghai^{1, 2
,
,},
Meng Yue^{1, 2},
Yan Ketao^{1, 2}

1.
Key Laboratory of Deep Geothermal Resources, MNR, China University of Geosciences, Wuhan 430078, China
2.
School of Environmental Studies, China University of Geosciences, Wuhan 430078, China

Received Date: 2022-04-14
Available Online: 2023-03-27
Publish Date: 2023-03-25

Abstract

Abstract

Geothermal waters generally have far higher arsenic concentrations than other types of natural waters, and analysis of arsenic speciation in geothermal waters is of great environmental geochemical significance. Methylthiolated arsenates are non-negligible arsenic species under special aqueous environmental conditions, while little environmental geochemical studies of methylthiolated arsenates have been done so far. In this work, various methylthiolated arsenates standards were synthesized, and an ion chromatography coupled to inductively coupled plasma-mass spectrometry, capable of determining concentrations of common arsenic species as well as methylthiolated arsenates in natural waters including monomethylmonothioarsenate (MMMTA), monomethyldithioarsenate (MMDTA), monomethyltrithioarsenate (MMTTA), dimethylmonothioarsenate (DMMTA), and dimethyldithioarsenate (DMDTA), was set up. Furthermore, the arsenic speciation in a typical geothermal water sample was analyzed. The efforts made in this study produced an analytical method basis for future geochemical studies of methylthiolated arsenates in aqueous environments.
- geothermal water,
- methylthiolated arsenate,
- quantitative analysis,
- IC-ICP-MS,
- groundwater geochemistry

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References(30)

References

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Simultaneous Quantitative Analysis of Multiple Methylthiolated Arsenates in Geothermal Water

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