铁基阴离子黏土改性材料在地热水处理中的应用

曹耀武; 唐保春

doi:10.3799/dqkx.2022.342

Volume 48 Issue 3

Mar. 2023

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Cao Yaowu, Tang Baochun, 2023. Application of Modified Iron-Based LDH Materials in Geothermal Water Treatment. Earth Science, 48(3): 1146-1155. doi: 10.3799/dqkx.2022.342

Citation:

Cao Yaowu, Tang Baochun, 2023. Application of Modified Iron-Based LDH Materials in Geothermal Water Treatment. Earth Science, 48(3): 1146-1155. doi: 10.3799/dqkx.2022.342

Cao Yaowu, Tang Baochun, 2023. Application of Modified Iron-Based LDH Materials in Geothermal Water Treatment. Earth Science, 48(3): 1146-1155. doi: 10.3799/dqkx.2022.342

Citation:

Cao Yaowu, Tang Baochun, 2023. Application of Modified Iron-Based LDH Materials in Geothermal Water Treatment. Earth Science, 48(3): 1146-1155. doi: 10.3799/dqkx.2022.342

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Application of Modified Iron-Based LDH Materials in Geothermal Water Treatment

doi: 10.3799/dqkx.2022.342

Cao Yaowu^{1
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Tang Baochun^{2, 3
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1.
Faculty of Resources and Environmental Science, Hubei University, Wuhan 430062, China
2.
Qinghai Institute of Hydrogeology, Engineering Geology and Environmental Geology, Xining 810008, China
3.
Key Laboratory of Hydrogeology and Geothermal Geology of Qinghai Province, Xining 810008, China

Received Date: 2022-08-20
Available Online: 2023-03-27
Publish Date: 2023-03-25

Abstract

Abstract

Geothermal waters are generally enriched in multiple groups of harmful components, which threaten the safety of drinking water for the surrounding residents when non-concentrated discharged in the form of hot springs. In this paper, five iron-based LDH (Fe-LDH) modified materials were prepared and used in the treatment of hot springs in typical geothermal areas of Yunnan. The results show that Fe-LDH has the best removal of arsenic, followed by fluoride and tungsten, and the removal of antimony and boron was influenced by coexisting ions; whereas, the modified materials effectively narrow the gap of competitive sorption between different harmful components, which shows that ion exchange capacity of the lactate intercalated Fe-LDH was significantly improved and the removal of fluorine and boron was enhanced, while the delaminated Fe-LDHs exposed more active sites and increased the interlayer contact, thus it had a greater enhancement on the removal of arsenic and tungsten, which are primarily complexed with iron, along with the removal of fluoride and boron by ion exchange. Finally, the best sorbent in static sorption performance, L-asparagine delaminated Fe-LDH, could dynamically and effectively remove multiple groups of harmful components from hot springs as a filling material for small water treatment devices, which provides a practical method for the remediation of geothermal waters.
- geothermal water treatment,
- iron-based LDH,
- delamination,
- dynamic sorption,
- competitive sorption,
- water pollution control,
- environmental protection

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References(45)

References

Aksoy, N., Şimşek, C., Gunduz, O., 2009. Groundwater Contamination Mechanism in a Geothermal Field: A Case Study of Balcova, Turkey. Journal of Contaminant Hydrology, 103(1-2): 13-28. https://doi.org/10.1016/j.jconhyd.2008.08.006

Ashekuzzaman, S. M., Jiang, J. Q., 2017. Strategic Phosphate Removal/Recovery by a Re-Usable Mg-Fe-Cl Layered Double Hydroxide. Process Safety and Environmental Protection, 107: 454-462. https://doi.org/10.1016/j.psep.2017.03.009

Abdelkader, N. B. H., Bentouami, A., Derriche, Z., et al., 2011. Synthesis and Characterization of Mg-Fe Layer Double Hydroxides and Its Application on Adsorption of Orange G from Aqueous Solution. Chemical Engineering Journal, 169(1-3): 231-238. https://doi.org/10.1016/j.cej.2011.03.019

Brown, K. L., Simmons, S. F., 2003. Precious Metals in High-Temperature Geothermal Systems in New Zealand. Geothermics, 32(4-6): 619-625. https://doi.org/10.1016/S0375-6505(03)00049-X

Bunani, S., Arda, M., Kabay, N., 2018. Effect of Operational Conditions on Post-Treatment of RO Permeate of Geothermal Water by Using Electrodeionization (EDI) Method. Desalination, 431: 100-105. https://doi.org/10.1016/j.desal.2017.10.032

Cao, Y. W., Guo, Q. H., Liang, M. S., et al., 2020. Sb(Ⅲ) and Sb(Ⅴ) Removal from Water by a Hydroxyl-Intercalated, Mechanochemically Synthesized Mg-Fe-LDH. Applied Clay Science, 196: 105766. https://doi.org/10.1016/j.clay.2020.105766

Cao, Y. W., Guo, Q. H., Shu, Z., et al., 2019. Tungstate Removal from Aqueous Solution by Nanocrystalline Iowaite: An Iron-Bearing Layered Double Hydroxide. Environmental Pollution, 247: 118-127. https://doi.org/10.1016/j.envpol.2019.01.021

Cao, Y. W., Guo, Q. H., Shu, Z., et al., 2016. Application of Calcined Iowaite in Arsenic Removal from Aqueous Solution. Applied Clay Science, 126: 313-321. https://doi.org/10.1016/j.clay.2016.04.002

Cao, Y. W., Guo, Q. H., Sun, W. H., et al., 2021. Simultaneous Removal of Harmful Anions from Geothermal Waters Using OH^- Intercalated Mg-Fe-LDH: Batch and Field Column Studies. Environmental Science and Pollution Research, 28(29): 39345-39356. https://doi.org/10.1007/s11356-021-12939-1

Chen, S. H., Yue, Q. Y., Gao, B. Y., et al., 2012. Adsorption of Hexavalent Chromium from Aqueous Solution by Modified Corn Stalk: A Fixed-Bed Column Study. Bioresource Technology, 113: 114-120. https://doi.org/10.1016/j.biortech.2011.11.110

Das, J., Sairam, P. B., Baliarsingh, N., et al., 2007. Calcined Mg-Fe-CO(3) LDH as an Adsorbent for the Removal of Selenite. Journal of Colloid and Interface Science, 316(2): 216-223. https://doi.org/10.1016/j.jcis.2007.07.082

Guo, Q. H., 2022. Environmental Effects of Harmful Constituents Derived from Geothermal Systems and Their Treatments. Acta Geologica Sinica, 96(5): 1767-1773 (in Chinese with English abstract). doi: 10.3969/j.issn.0001-5717.2022.05.016

Guo, Q. H., Cao, Y. W., Yin, Z. W., et al., 2017. Enhanced Removal of Arsenic from Water by Synthetic Nanocrystalline Iowaite. Scientific Reports, 7: 17546. https://doi.org/10.1038/s41598-017-17903-z

Guo, Q. H., Li, Y. M., Luo, L., 2019. Tungsten from Typical Magmatic Hydrothermal Systems in China and Its Environmental Transport. Science of the Total Environment, 657: 1523-1534. https://doi.org/10.1016/j.scitotenv.2018.12.146

Hudcová, B., Veselská, V., Filip, J., et al., 2017. Sorption Mechanisms of Arsenate on Mg-Fe Layered Double Hydroxides: A Combination of Adsorption Modeling and Solid State Analysis. Chemosphere, 168: 539-548. https://doi.org/10.1016/j.chemosphere.2016.11.031

Jarma, Y. A., Karaoğlu, A., Tekin, Ö., et al., 2022. Integrated Pressure-Driven Membrane Separation Processes for the Production of Agricultural Irrigation Water from Spent Geothermal Water. Desalination, 523: 115428. https://doi.org/10.1016/j.desal.2021.115428

Jiang, J. Q., Ashekuzzaman, S. M., Hargreaves, J. S. J., et al., 2015. Removal of Arsenic (Ⅲ) from Groundwater Applying a Reusable Mg-Fe-Cl Layered Double Hydroxide. Journal of Chemical Technology & Biotechnology, 90(6): 1160-1166. https://doi.org/10.1002/jctb.4607

Kang, D. J., Yu, X. L., Tong, S. R., et al., 2013. Performance and Mechanism of Mg/Fe Layered Double Hydroxides for Fluoride and Arsenate Removal from Aqueous Solution. Chemical Engineering Journal, 228: 731-740. https://doi.org/10.1016/j.cej.2013.05.041

Kelly, A. D. R., Lemaire, M., Young, Y. K., et al., 2013. In Vivo Tungsten Exposure Alters B-Cell Development and Increases DNA Damage in Murine Bone Marrow. Toxicological Sciences: An Official Journal of the Society of Toxicology, 131(2): 434-446. https://doi.org/10.1093/toxsci/kfs324

Khatibikamal, V., Torabian, A., Ahmad, P. H., et al., 2019. Stabilizing of Poly(Amidoamine) Dendrimer on the Surface of Sand for the Removal of Nonylphenol from Water: Batch and Column Studies. Journal of Hazardous Materials, 367: 357-364. https://doi.org/10.1016/j.jhazmat.2018.12.106

Koutsospyros, A. D., Strigul, N., Braida, W., et al., 2011. Tungsten: Environmental Pollution and Health Effects. Encyclopedia of Environmental Health. Amsterdam: Elsevier, 418-426. https://doi.org/10.1016/b978-0-444-52272-6.00650-4

Landrum, J. T., Bennett, P. C., Engel, A. S., et al., 2009. Partitioning Geochemistry of Arsenic and Antimony, El Tatio Geyser Field, Chile. Applied Geochemistry, 24(4): 664-676. https://doi.org/10.1016/j.apgeochem.2008.12.024

Li, Y. L., Yu, C. S., Jiang, Z. C., et al., 2021. An Experimental Study of Heating Tail Water Treatment of the Lindian Geothermal Fields in the Northern Songnen Basin. Hydrogeology & Engineering Geology, 48(1): 188-194 (in Chinese with English abstract).

Luo, L., Guo, Q. H., Cao, Y. W., 2019. Uptake of Aqueous Tungsten and Molybdenum by a Nitrate Intercalated, Pyroaurite-Like Anion Exchangeable Clay. Applied Clay Science, 180: 105179. https://doi.org/10.1016/j.clay.2019.105179

Mandal, S., Mayadevi, S., 2008. Cellulose Supported Layered Double Hydroxides for the Adsorption of Fluoride from Aqueous Solution. Chemosphere, 72(6): 995-998. https://doi.org/10.1016/j.chemosphere.2008.03.053

Recepoğlu, Y. K., Kabay, N., Ipek, I. Y., et al., 2018. Packed Bed Column Dynamic Study for Boron Removal from Geothermal Brine by a Chelating Fiber and Breakthrough Curve Analysis by Using Mathematical Models. Desalination, 437: 1-6. https://doi.org/10.1016/j.desal.2018.02.022

Rives, V., Ulibarri, M. A., 1999. Layered Double Hydroxides (LDH) Intercalated with Metal Coordination Compounds and Oxometalates. Coordination Chemistry Reviews, 181(1): 61-120. https://doi.org/10.1016/ S0010-8545(98)00216-1 doi: 10.1016/S0010-8545(98)00216-1

Sasaki, K., Hayashi, Y., Toshiyuki, K., et al., 2018. Simultaneous Immobilization of Borate, Arsenate, and Silicate from Geothermal Water Derived from Mining Activity by Co-Precipitation with Hydroxyapatite. Chemosphere, 207: 139-146. https://doi.org/10.1016/j.chemosphere.2018.05.074

Tomaszewska, B., Akkurt, G. G., Kaczmarczyk, M., et al., 2021. Utilization of Renewable Energy Sources in Desalination of Geothermal Water for Agriculture. Desalination, 513: 115151. https://doi.org/10.1016/j.desal.2021.115151

Tyszer, M., Tomaszewska, B., Kabay, N., 2021. Desalination of Geothermal Wastewaters by Membrane Processes: Strategies for Environmentally Friendly Use of Retentate Streams. Desalination, 520: 115330. https://doi.org/10.1016/j.desal.2021.115330

Wang, R. Z., Liu, J., Wu, J. H., et al., 2019. Preparation of Magnetic Nanocomposite and Their Removal Properties of F and As in Geothermal Water. The Journal of New Industrialization, 9(6): 82-85 (in Chinese with English abstract).

Wang, X. X., Yu, S. Q., Wu, Y. H., et al., 2018. The Synergistic Elimination of Uranium (Ⅵ) Species from Aqueous Solution Using Bi-Functional Nanocomposite of Carbon Sphere and Layered Double Hydroxide. Chemical Engineering Journal, 342: 321-330. https://doi.org/10.1016/j.cej.2018.02.102

Wilson, N., Webster-Brown, J., Brown, K., 2012. The Behaviour of Antimony Released from Surface Geothermal Features in New Zealand. Journal of Volcanology and Geothermal Research, 247-248: 158-167. https://doi.org/10.1016/j.jvolgeores.2012.08.009

Witten, M. L., Sheppard, P. R., Witten, B. L., 2012. Tungsten Toxicity. Chemico-Biological Interactions, 196(3): 87-88. https://doi.org/10.1016/j.cbi.2011.12.002

Yan, K. T., Guo, Q. H., Luo, L., 2022. Methylation and Thiolation of Arsenic in Tengchong Hot Springs. Earth Science, 47(2): 622-632 (in Chinese with English abstract).

Yang, T. M., 2018. Test Engineering of Heat-Supply System Using Geothermal Tail Water Treated by Reverse Osmosis Method as Secondary Network Make-Up Water. Guangdong Chemical Industry, 45(1): 61-62, 68 (in Chinese with English abstract).

İpek, İ. Y., Kabay, N., Yüksel, M., 2013. Modeling of Fixed Bed Column Studies for Removal of Boron from Geothermal Water by Selective Chelating Ion Exchange Resins. Desalination, 310: 151-157. https://doi.org/10.1016/j.desal.2012.10.009

Yu, Z. Y., Cao, Y. W., Guo, Q. H., 2018. Removing Harmful Constituents from Geothermal Water Using Selected Anion Clays. Environmental Science & Technology, 41(3): 109-117 (in Chinese with English abstract).

Zaneva, S., Stanimirova, T., 2004. Crystal Chemistry, Classification Position and Nomenclature of Layered Double Hydroxydes. Bulgarian Geological Society, Annual Scientific Conference "Geology 2004", Sofia.

郭清海, 2022. 地热系统来源有害组分的环境效应及其处理. 地质学报, 96(5): 1767-1773. doi: 10.3969/j.issn.0001-5717.2022.05.016

李永利, 于长生, 姜智超, 等, 2021. 松嫩盆地北部林甸地热田供暖尾水处理试验. 水文地质工程地质, 48(1): 188-194. https://www.cnki.com.cn/Article/CJFDTOTAL-SWDG202101023.htm

王睿智, 刘建, 吴金辉, 等, 2019. 磁性纳米复合物的制备及其在地热水中F和As的去除性能研究. 新型工业化, 9(6): 82-85. https://www.cnki.com.cn/Article/CJFDTOTAL-XXHG201906018.htm

严克涛, 郭清海, 罗黎, 2022. 腾冲热泉中砷的甲基化和巯基化过程. 地球科学, 47(2): 622-632. doi: 10.3799/dqkx.2021.105

杨天明, 2018. 反渗透法处理地热尾水作为采暖二次网补水试验工程. 广东化工, 45(1): 61-62, 68. https://www.cnki.com.cn/Article/CJFDTOTAL-GDHG201801029.htm

余正艳, 曹耀武, 郭清海, 2018. 基于阴离子粘土去除地热水中多种有害组分. 环境科学与技术, 41(3): 109-117. https://www.cnki.com.cn/Article/CJFDTOTAL-FJKS201803017.htm

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Application of Modified Iron-Based LDH Materials in Geothermal Water Treatment

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