环氧树脂/沸石纳米复合材料的制备及表征

陈艳玲; 袁军华; 范畴; 叶立庭

Volume 27 Issue 4

Jul. 2002

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Article Navigation > Earth Science > 2002 > 27(4): 403-407

CHEN Yan-ling, YUAN Jun-hua, FAN Chou, YE Li-ting, 2002. Characterization and Preparation of Epoxy Resin/Zeolite Nanocomposite. Earth Science, 27(4): 403-407.

Citation:

CHEN Yan-ling, YUAN Jun-hua, FAN Chou, YE Li-ting, 2002. Characterization and Preparation of Epoxy Resin/Zeolite Nanocomposite. Earth Science, 27(4): 403-407.

CHEN Yan-ling, YUAN Jun-hua, FAN Chou, YE Li-ting, 2002. Characterization and Preparation of Epoxy Resin/Zeolite Nanocomposite. Earth Science, 27(4): 403-407.

Citation:

CHEN Yan-ling, YUAN Jun-hua, FAN Chou, YE Li-ting, 2002. Characterization and Preparation of Epoxy Resin/Zeolite Nanocomposite. Earth Science, 27(4): 403-407.

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Characterization and Preparation of Epoxy Resin/Zeolite Nanocomposite

Faculty of Material Sciences and Chemistry Engineering, China University of Geosciences, Wuhan 430074, China

Received Date: 2002-04-23
Publish Date: 2002-07-25

Abstract

Abstract

This paper proposes a new method to synthesize the epoxy resin/zeolite nanocomposite. In this method, zeolite was previously treated with sodium nitrate, and organized with ceyltrimethyl ammonium bromide. Epoxy resin was interposed in the cavity of zeolite and polymerized in situ. Then, the polymer mixtures were solidified by pp' diaphenyl methane to prepare for nanocomposite. The synthesis condition such as mixing temperature, mixing time and concentrations are discussed extensively, and the epoxy resin/zeolite nanocomposite was characterized by XRD and TEM. This composite is found to be formed by the nanometer aggregated particles, ranging from 50 to 60 nm in diameter based on the analysis of the TEM image. The epoxy resin/zeolite nanocomposite exhibits dramatic increases in their mechanical properties, which can be used in engineering plastic and high quality adhesive.
- nanocomposite,
- zeolite,
- epoxy resin,
- interpose,
- solidify

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References(14)

References

[1]	严东生. 纳米材料的合成和制备[J]. 无机材料学报, 1995, 1(10) : 1. https://www.cnki.com.cn/Article/CJFDTOTAL-WGCL501.000.htm YAN D S. Sy nthesis and fabrication of nanostructured materials[J]. Journal of Inorganic M aterials, 1995, 1(10) : 1. https://www.cnki.com.cn/Article/CJFDTOTAL-WGCL501.000.htm
[2]	汪信, 陆路德. 纳米金属氧化物的制备及应用的若干进展[J]. 无机化学学报, 2000, 2(16) : 14. https://www.cnki.com.cn/Article/CJFDTOTAL-WJHX200002006.htm WANG X, LU L D. Progress of preparation and applications of metal ox ide nanocry stallines[J]. Chinese Journal of Inorganic Chemistry, 2000, 2(16) : 14. https://www.cnki.com.cn/Article/CJFDTOTAL-WJHX200002006.htm
[3]	Theng B K G. The chemistry of clay-org anic reactions [M]. London: Adam Hilger, 1979.
[4]	Theng B K G. Formation and proper ties of clay-polymer complexes[M]. A msterdam : Elsevier, 1979.
[5]	刘晓辉, 范家起, 李强, 等. 聚丙烯/蒙脱土纳米复合材料I. 制备、表征及动态力学[J]. 高分子学报, 2000, 5: 563. doi: 10.3321/j.issn:1000-3304.2000.05.009 LIU X H, FAN J Q, LI Q, et al. Polypropylene/ montmo rillonite nanoco mposites preparation characterisation and dy namic methnical propertites[J]. A cta Poly merica Sinica, 2000, 5: 563. doi: 10.3321/j.issn:1000-3304.2000.05.009
[6]	徐卫兵, 何平笙. A rrami法研究环氧树脂/ 蒙脱土/ 咪唑纳米复合材料的固化动力学[J]. 功能高分子学报, 2001, 14(1) : 66. https://www.cnki.com.cn/Article/CJFDTOTAL-GNGF200101015.htm XU W B, HE P S. Study on cure kinetics of epoxy resin/ montmorillonite/midazole nanocomposite by A rrami equation[J]. Journal of Functional Polymers, 2001, 14(1) : 66. https://www.cnki.com.cn/Article/CJFDTOTAL-GNGF200101015.htm
[7]	陈光明, 毛永梅, 漆宗能. 甲苯-2, 4 -二异氰酸酯修饰蒙脱土及聚苯乙烯/ 蒙脱土纳米复合材料的制备与表征[J]. 高分子学报, 2000, 10(5) : 599. doi: 10.3321/j.issn:1000-3304.2000.05.017 CHEN G M, MAO Y M, QI Z N. M odification of montmo rillonite with toluene-2, 4-di -isocy anate and preparatio n and characterization of polysty rene/montmorillonite nanocomposite[J]. A cta Polymerica Sinica, 2000, 10(5) : 599. doi: 10.3321/j.issn:1000-3304.2000.05.017
[8]	刘立敏, 朱晓光, 漆宗能. 尼龙6/ 蒙脱土纳米复合材料的等温结晶动力学研究[J]. 高分子学报, 1997, (5) : 519. doi: 10.3321/j.issn:1000-3304.1997.05.002 LIU I M, ZHU X G, QI Z N. Kinetics of iso thermal crystallizatio n for nylo n 6/montmorillonite nano composites[J]. Acta Polymerica Sinica, 1997, (5) : 519. doi: 10.3321/j.issn:1000-3304.1997.05.002
[9]	赵竹第, 李强, 欧玉春, 等. 尼龙6/蒙脱土纳米复合材料的制备、结构与力学性能的研究[J]. 高分子学报, 1999, 71 : 1133. https://www.cnki.com.cn/Article/CJFDTOTAL-GFXB705.001.htm ZHAO Z D, LI Q, OU Y C, et al. Sy nthesis, structure and mechanical proper ties o f nylon 6/montmorillonite nanocompo sites[J]. Acta Poly merica Sinica, 1999, 71 : 1133. https://www.cnki.com.cn/Article/CJFDTOTAL-GFXB705.001.htm
[10]	中国科学院地质研究所. 沸石矿物与应用研究论文集[M]. 北京: 科学出版社, 1979. Geology Institute of Chinese Academy of Sciences. The research paper series of zeolite and its application[M]. Beijing: Science Press, 1979.
[11]	Akane O, Masaya K, Toshio, et al. Synthesis and characterization of a nilon 6-clay hybrid[J]. Polymer P reprints, 1987, 28(2) : 447-451.
[12]	Philip B M, Emmanuel P, Giannelis E. Synthesis and barrier properties of poly (ε-caprolactone)-layered silicate naocomposites[J]. Journal of Polymer Science, 1995, 33 (5) : 1047-1051.
[13]	Kelly P, Akelah A, Qutubuddin S, et al. Reduction of residual stress in montmorillonite/ epoxy compounds[J]. Journal M aterials Science, 1994, 29 : 2274-2278.
[14]	Luca B, Mauro A R, Francesco C. Functionalization of montmorillonite by methyl methacrylate polymers containing side-chain ammonium cations[J]. Polymer, 1994, 35(15) : 3296 -3301. doi: 10.1016/0032-3861(94)90138-4