黔湘渝毗邻区南华纪武陵裂谷盆地结构及其对锰矿的控制作用

周琦; 杜远生; 袁良军; 张遂; 余文超; 杨胜堂; 刘雨

doi:10.3799/dqkx.2016.014

黔湘渝毗邻区南华纪武陵裂谷盆地结构及其对锰矿的控制作用

doi: 10.3799/dqkx.2016.014

周琦^1,2,,
杜远生³,
袁良军¹,
张遂¹,
余文超³,
杨胜堂¹,
刘雨⁴

1.
贵州省地质矿产勘查开发局103地质大队,贵州铜仁 554300
2.
贵州省地质矿产勘查开发局,贵州贵阳 550004
3.
中国地质大学生物地质与环境地质国家重点实验室,湖北武汉 430074
4.
长江大学地球环境与资源学院,湖北武汉 430100

基金项目:

国土资源部公益性行业科研专项项目 No.201411051

中国地质调查局项目 No.12120114016701

详细信息

作者简介:
周琦 (1964-), 男, 研究员, 博士, 从事矿产地质研究及评价工作

中图分类号: P618.32
计量
- 文章访问数: 7002
- HTML全文浏览量: 1880
- PDF下载量: 241
- 被引次数: 0
出版历程
- 收稿日期: 2015-09-10
- 刊出日期: 2016-02-15

The Structure of the Wuling Rift Basin and Its Control on the Manganese Deposit during the Nanhua Period in Guizhou-Hunan-Chongqing Border Area, South China

1.
103 Geological Party, Bureau of Geology and Mineral Exploration & Development of Guizhou Province, Tongren 554300, China
2.
Bureau of Geology and Mineral Exploration and Development of Guizhou Province, Guiyang 550004, China
3.
State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430074, China
4.
School of Earth Environment and Water Resource, Yangtze University, Wuhan 430100, China

摘要

摘要: 黔湘渝毗邻区南华纪“大塘坡式”锰矿是我国最重要的锰资源基地，现已发现沉积型菱锰矿上亿吨，占全国已探明锰矿资源量的50%左右.通过对南华纪地层系统和地层分区的研究，提出在Rodinia超大陆裂解背景下，南华裂谷盆地 (I级) 西段分别由武陵、雪峰次级裂谷盆地和其间的天柱-怀化隆起 (地垒)3个Ⅱ级构造单元构成.武陵次级裂谷盆地控制形成了黔渝湘毗邻区锰矿成矿带，内部由3个Ⅲ级断陷 (地堑) 盆地、2个Ⅲ级隆起 (地垒) 和至少16个Ⅳ级断陷 (地堑) 盆地组成.3个Ⅲ级断陷 (地堑) 盆地分别控制形成了松桃-古丈、玉屏-芷江以及溪口-小茶园锰矿成矿亚带.其中，松桃-古丈锰矿成矿亚带是武陵次级裂谷盆地的裂陷中心，锰矿成矿作用强烈，形成的锰矿资源量巨大，已成为世界级锰矿资源富集区之一.Ⅳ断陷 (地堑) 盆地则控制形成研究区各锰矿床；提出南华纪早期同沉积断层是锰矿床形成的前提，并识别恢复出研究区15条同沉积断层及所控制形成的断陷 (地堑) 盆地和主要锰矿床.同沉积断层不但是深部锰质和古天然气上升的通道，更是连接古天然气渗漏沉积型锰矿成矿系统中地内系统与表层系统的纽带.
- 南华纪 /
- 裂谷盆地 /
- 锰矿 /
- 华南 /
- 矿床地质
Abstract: The "Datangpo type" manganese deposits in Guizhou-Hunan-Chongqing border area is an important manganese resource base since its hundreds of million tons of sedimentary rhodochrosite accounts for about half of manganese resource of China. In this paper, based on the study about the formation system of Nanhua period and stratigraphic regionalization, we find under the background of Rodinia supercontinent breakup, the Nanhua rift basin (level I) consisted of the Wuling and Xuefeng secondary rift basin and the Tianzhu-Huaihua uplift. Wuling secondary rift basin controlled and formed the manganese metallogenic area in the Guizhou-Hunan-Chongqing border area, and its inside consisted of three level Ⅲ depression basins, one level Ⅲ uplift and sixteen level IV rift basins. The three level Ⅲ depression basins controlled Songtao-Guzhang, Yiping-Zhijiang and Xikou-Xiaochayuan secondary manganese metallogenic area. Among them, the Songtao-Guzhang depression basin (Level Ⅲ) is the rifting center of the Wuling secondary rift basin, where the manganese mineralization is strong, and the quantity of resource is huge, which has became a world-level manganese concentrated area. The IV rift basins controlled and formed the manganese deposits in the target area. It's suggested that the syn-sedimentary fault in Nanhua period is the premise of manganese deposit formation, fifteen syn-sedimentary faults, the controlled depression basins and the major manganese in the target area are distinguished and recovered. The syn-sedimentary fault is not only the transporting tunnel of deep manganese material and ancient natural gas but also the link of inside system and surface system of ancient natural gas seepage sedimentary-type manganese metallogenic system.
- Nanhua period /
- rift basin /
- manganese deposit /
- South China /
- ore deposit geology

HTML全文

图 1 华南新元古代黔湘渝毗邻区南华纪裂谷盆地结构示意图 (a) 及研究区南华系划分方案 (b)

图中剖面分别为：1.重庆秀山小茶园；2.重庆秀山盐井沟；3.重庆秀山笔架山；4.贵州松桃杨家湾ZK402；5.贵州松桃牛峰包；6.贵州松桃道坨ZK301；7.贵州松桃茶叶坳ZK108；8.贵州松桃大屋ZK1703；9.贵州松桃两界河；10.贵州松桃西溪堡ZK1010；11.贵州江口桃映；12.贵州江口雷家；13.贵州铜仁半溪；14.贵州万山盆架山ZK2208

Fig. 1. The geological sketch of the Early Cryogenian Nanhua rift basin in the Guizhou-Hunan-Chongqing border area, South China (a) and stratigraphic classification scheme of Nanhua System stratum in research area (b)

下载: 全尺寸图片幻灯片

图 2 黔渝湘毗邻区南华系分区示意

Ⅲ₁.玉屏-石竹溪地层小区；Ⅲ₂.铜仁-凤凰地层小区；Ⅲ₃.松桃-古丈地层小区；Ⅲ₄.甘龙-秀山地层小区；Ⅲ₅.小茶园-溪口地层小区；II.天柱-怀化地层区

Fig. 2. The geological sketch of the Early Nanhua period stratigraphic regionalization in the Guizhou-Hunan-Chongqing border area, South China

下载: 全尺寸图片幻灯片

图 3 黔渝湘毗邻区南华纪两界河-大塘坡期南华裂谷盆地复原

1.重庆秀山小茶园；2.重庆秀山盐井沟；3.重庆秀山笔架山；4.贵州松桃道坨；5.贵州松桃两界河；6.贵州松桃西溪堡；7.贵州万山盆架山；8.贵州从江八当；9.两界河期 (富禄)-铁丝坳期砂砾岩沉积；10.大塘坡早期黑色碳质页岩 (夹菱锰矿)；11.大塘坡中晚期粉砂质页岩；12.同沉积断层

Fig. 3. Reconstruction of the Nanhua rift basin in the Nanhua period Liangjiehe-Datangpo stages in the Guizhou-Hunan-Chongqing border area, South China

下载: 全尺寸图片幻灯片

图 4 黔渝湘毗邻区南华纪早期武陵次级裂谷盆地结构与构造古地理

1.控制Ⅲ级断陷 (地堑) 盆地和隆起 (地垒) 的同沉积断层；2.控制Ⅳ级断陷 (地堑) 盆地和隆起 (地垒) 的同沉积断层；3.Ⅳ级断陷 (地堑) 盆地及所控制的锰矿床名称；4.Ⅲ级断陷 (地堑) 盆地范围；5.Ⅲ级隆起 (地垒) 范围；6.研究区大地构造位置；7.同沉积断层编号

Fig. 4. Structural and tectonic paleogeographic sketch of the Early Nanhua period Wuling secondary rift basin in the Guizhou-Hunan-Chongqing border area, South China

下载: 全尺寸图片幻灯片

图 5 黔渝湘毗邻区南华裂谷盆地武陵次级裂谷盆地盆地复原与演化

1.大塘坡组第2、3段；2.大塘坡组第1段；3.铁丝坳组；4.两界河组；5.冰碛砾岩；6.砂岩；7.粉砂质页岩；8.碳质页岩；9.白云岩透镜体；10.白云岩；11.含砾白云岩；12.同沉积断层；13.地层对比线；14.菱锰矿体；剖面位置见图 1

Fig. 5. Reconstruction of the Nanhua rift basin in the Guizhou-Hunan-Chongqing border area, South China

下载: 全尺寸图片幻灯片

表 1 武陵次级裂谷盆地结构划分

Table 1. The structure of the Wuling 2nd rift basin

Ⅰ级	Ⅱ级	Ⅲ级	Ⅳ级	备注
南华裂谷盆地	武陵次级裂谷盆地	溪口-小茶园断陷(地堑)盆地	秀山小茶园断陷 (地堑) 盆地	武陵次级裂谷盆地的Ⅳ级结构单元划分仅限于两界河至大塘坡早期
		甘龙-秀山隆起 (地垒)	/
		松桃-古丈断陷 (地堑) 盆地	松桃道坨-李家湾、西溪堡、大塘坡、大屋、杨家湾、凉风坳、举贤、普觉，花垣民乐、古丈烂泥田、秀山笔架山、石阡石板溪、镇远都坪断陷 (地堑) 和秀山椅子山、松桃牛峰包以及和尚坪隆起 (地垒)
		镇远-铜仁-凤凰隆起 (地垒)
		玉屏-芷江断陷 (地堑) 盆地	/
			万山盆架山以及玉屏新寨断陷 (地堑) 盆地

下载: 导出CSV

表 2 武陵次级裂谷盆地南华纪早期主要同沉积断层及特征

Table 2. Major syn-sedimentary faults and their characteristics of Wuling secondary rift basin in early Nanhua Period

编号	主要特征	控制Ⅳ级断陷盆地等
SF1	沿该断层延长方向两界河组 (394 m)、含锰岩系 (50~70 m)、大塘坡组第2、3段 (583 m) 厚度异常增大等，两侧迅速减薄	松桃大塘坡
SF3	断层北西含锰岩系厚度为零，南东则迅速增厚；出现两界河组沉积等	松桃大屋
SF5	断层南东侧含锰岩系厚度迅速减薄为零，大塘坡第2段也大幅减薄；北西侧含锰岩系迅速增厚，出现两界河组沉积.被沥青充填的气泡状菱锰矿石、底劈构造及软沉积变形纹理沿NE 60°方向展布	松桃锅厂-李家湾-道坨、花垣民乐、古丈烂泥田等
SF7	断层南东侧含锰岩系厚度为零，大塘坡组第2、3段也迅速减薄直至为零；北西侧含锰岩系厚度则迅速增厚 (最厚大于80 m)，大塘坡组第2、3段也迅速增厚等	松桃杨家湾
SF9	断层南东侧含锰岩系厚度为零，大塘坡组第2、3段也迅速减薄；北西侧出现含锰岩系，厚度迅速增厚.含锰岩系中出现来自隆起区的小型盆地扇沉积物	松桃凉风坳以及秀山革里坳
SF15	沿断层含锰岩系较大厚度沉积，出现被沥青充填的气泡状菱锰矿石	秀山小茶园
SF2	沿断层延长方向出现两界河组 (大于140 m)、含锰岩系 (96 m)、大塘坡组第2、3段 (652 m) 大厚度沉积等，沿两侧迅速减薄	松桃西溪堡、松桃举贤等
SF4	沿断层延长方向出现两界河组和含锰岩系 (40 m)、大塘坡组第2、3段 (300 m) 较大厚度沉积等	松桃普觉
SF6SF8	沿断层均出现两界河组较大厚度沉积和含锰岩系，沿两侧迅速减薄等	石阡石板溪以及镇远袁家山
SF14	沿断层方向含锰岩系相对较厚，沿两侧迅速减薄，直至为零	万山盆架山
SF10SF12	两同沉积断层之间均缺失含锰岩系，大塘坡组很薄或缺失；之外则迅速出现含锰岩系、大塘坡组沉积	系控制Ⅲ级单元的边界
SF11SF13	两同沉积断层之间均缺失含锰岩系，大塘坡组很薄或缺失；之外则迅速出现含锰岩系以及大塘坡组沉积	系控制Ⅲ级单元的边界

下载: 导出CSV

参考文献(64)

Bureau of Geology and Mineral Rersources of Guizhou Provincce, 1987.Regional Geology of the Guizhou Province.Geological Press House, Beijing (in Chinese).
Cai, X.L., Cao, J.M., Zhu, J.S., et al., 2008.The System of Crust-Mantle Ductile Shear Zones in China Continental Lithosphere.Earth Science Frontiers, 15(3):36-54 (in Chinese with English abstract). doi: 10.1016/S1872-5791(08)60061-5
de Vries, S.T.D., Pryer, L.L., Fry, N., 2008.Evolution of Neoarchaean and Proterozoic Basins of Australia.Precambrian Research, 166(1-4):39-53.doi: 10.1016/j.precamres.2008.01.005
Dehler, C.M., Fanning, C.M., Link, P.K., et al., 2010.Maximum Depositional Age and Provenance of the Uinta Mountain Group and Big Cottonwood Formation, Northern Utah:Paleogeography of Rifting Western Laurentia.Bulletin, 122(9-10):1686-1699.doi: 10.1130/B30094.1
He, W.H., Tang, T.T., Yue, M.L., et al., 2014.Sedimentary and Tectonic Evolution of Nanhuan-Permianin South China.Earth Science, 39(8):929-953 (in Chinese with English abstract). http://www.gsm.org.my/products/702001-100957-PDF.pdf
He, Z.W., Yang, R.D., Gao, J.B., et al., 2014.The Geochemical Characteristics and Sedimentary Environment of Manganese-Bearing Rock Series of Daotuo Manganese Deposit, Songtao County of Guizhou Province.Geological Review, 60(5):1061-1075 (in Chinese with English abstract). https://www.researchgate.net/publication/292021634_The_geochemical_characteristics_and_sedimentary_environment_of_manganese-bearing_rock_series_of_Daotuo_manganese_deposit_Songtao_County_of_Guizhou_Province
Hoffman, P.F., 1991.Did the Breakout of Laurentia Turn Gondwanaland Inside-Out? Science, 252(5011):1409-1412.doi: 10.1126/science.252.5011.1409
Lan, Z.W., Li, X.H., Zhu, M.Y., et al., 2015.Revisiting the Liantuo Formation in Yangtze Block, South China:SIMS U-Pb Zircon Age Constraints and Regional and Global Significance.Precambrian Research, 263:123-141.doi: 10.1016/j.precamres.2015.03.012
Li, X.H., Li, W.X., He, B., 2012.Building of the South China Block and Its Relevance to Assembly and Breakup of Rodinia Supercontinent:Observations, Interpretations and Tests.Bulletin of Mineralogy, Petrology and Geochemistry, 31(6):543-559 (in Chinese with English abstract). https://www.researchgate.net/publication/286123654_Building_of_the_South_China_Block_and_its_relevance_to_assembly_and_breakup_of_Rodinia_supercontinent_Observations_interpretations_and_tests
Li, Z.X., Bogdanova, S.V., Collins, A.S., et al., 2008.Assembly, Configuration, and Break-Up History of Rodinia:A Synthesis.Precambrian Research, 160(1-2):179-210.doi: 10.1016/j.precamres.2007.04.021
Maynard, J.B., 2010.The Chemistry of Manganese Ores through Time:A Signal of Increasing Diversity of Earth-Surface Environments.Economic Geology, 105(3):535-552.doi: 10.2113/gsecongeo.105.3.535
Preiss, W.V., 2000.The Adelaide Geosyncline of South Australia and Its Significance in Neoproterozoic Continental Reconstruction.Precambrian Research, 100(1-3):21-63.doi: 10.1016/s0301-9268(99)00068-6
Qin, Y.J., Du, Y.S., Mou, J., et al., 2015.Geochronology of Neoproterozoic Xiajiang Group in Southeast Guizhou, South China, and Its Geological Implications.Earth Science, 40(7):1107-1121 (in Chinese with English abstract). https://www.researchgate.net/publication/282712930_Geochronology_of_neoproterozoic_Xiajiang_group_in_southeast_Guizhou_South_China_and_its_geological_implications
Rao, J.R., Wang, J.H., Cao, Y.Z., 1993.Deep Structure in Hunan.Geology of Hunan, (Suppl.7):1-103 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-HNDZ1993S1000.htm
Roy, S., 2006.Sedimentary Manganese Metallogenesis in Response to the Evolution of the Earth System.Earth Science Reviews, 77(4):273-305.doi: 10.1016/j.earscirev.2006.03.004
Thomson, D., Rainbird, R.H., Krapez, B., 2015.Sequence and Tectonostratigraphy of the Neoproterozoic (Tonian-Cryogenian) Amundsen Basin Prior to Supercontinent (Rodinia) Breakup.Precambrian Research, 263:246-259.doi: 10.1016/j.precamres.2015.03.001
Wang, J., 2005.New Advances in the Study of "the Nanhua System"—With Particular Reference to the Stratigraphic Division and Correlation of the Nanhua System, South China.Geological Bulletin of China, 24(6):491-495 (in Chinese with English abstract). https://www.researchgate.net/publication/279707907_SHRIMP_II_U-Pb_zircon_date_from_the_Nanhuan_Datangpo_Formation_in_Songtao_County_Guizhou_Province
Wang, J., Pan, G.T., 2009.Neoproterozoic South China Palaeocontinents:An Overview.Acta Sedimentologica Sinica, 27(5):818-825 (in Chinese with English abstract).
Wang, J., Li, Z.X., 2003.History of Neoproterozoic Rift Basins in South China:Implications for Rodinia Break-Up.Precambrian Research, 122(1-4):141-158.doi: 10.1016/s0301-9268(02)00209-7
Wang, Z.J., Xu, X.S., Du, Q.D., et al., 2013.Discussion on the Bottom of Nanhua System:Evidences from Sedimentology and Isotopic Geochronology.Advances in Earth Science, 28(4) :477-489 (in Chinese with English abstract). http://www.adearth.ac.cn/EN/abstract/abstract11071.shtml
Wang, Z.Q., Gao, L.Z., Ding, X.Z., et al., 2012.Tectonic Environment of the Metamorphosed Basement in the Jiangnan Orogen and Its Evolutional Features.Geological Review, 58(3):401-413 (in Chinese with English abstract). https://www.researchgate.net/publication/285504302_Tectonic_environment_of_the_metamorphosed_basement_in_the_Jiangnan_orogen_and_its_evolutional_features
Xu, X., Huang, H., Liu, B., 1990.Manganese Deposits of the Proterozoic Datangpo Formation South China:Genesis and Palaeogeography, In:Parnell, J., Ye, L.J., Chen, C.M., eds., Black Scientific, Boston, 39-50.doi: 10.1002/9781444303872.ch4
Yin, C.Y., Gao, L.Z., 2013.Definition, Time Limit and Stratigraphic Subdivision of the Nanhuan System in China.Journal of Stratigraphy, 37(4):534-541 (in Chinese with English abstract). https://www.researchgate.net/profile/Yin_Chongyu/citations?sorting=citationCount&page=3
Yin, C.Y., Wang., Y.G., Tang, F., et al., 2006.SHRIMP Ⅱ U-Pb Zircon Date from the Nanhuan Datangpo Formation in Songtao County, Guizhou Province.Acta Geologica Sinica, 80(2):273-278 (in Chinese with English abstract). https://www.researchgate.net/publication/279707907_SHRIMP_II_U-Pb_zircon_date_from_the_Nanhuan_Datangpo_Formation_in_Songtao_County_Guizhou_Province
Yuan, X.C., Hua, J.R., 2011.3D Lithospheric Structure of South China.Geology in China, 38(1):1-19 (in Chinese with English abstract). https://www.researchgate.net/publication/287909268_3D_Lithospheric_structure_of_South_China
Zhai, Y.S., Zhang, H., Song, H, L., et al., 1997.Macroscopic Structures and Superlarge Ore Depositis.Geological Press House, Beijing (in Chinese).
Zhang, F.F., Yan, B., Guo, Y.L., et al., 2013.Precipitation Form of Manganese Ore Deposit in Gucheng, Hubei Province, and Its Paleoenvironment Implication.Acta Geologica Sinica, 87(2):245-258 (in Chinese with English abstract). https://www.researchgate.net/publication/277583814_Precipitation_Form_of_Manganese_Ore_Deposits_in_Gucheng_Hubei_Province_and_Its_Paleoenvironment_Implication
Zhang, J.L., 2001.Inorganic Origin of Petroleum.Petroleum Industry Press, Beijing (in Chinese).
Zhang, J.L., 2014.Again on the Inorganic Origin of Petroleum.Petroleum Industry Press, Beijing (in Chinese).
Zhang, S., Zhou, Q., Zhang, P.Y., et al., 2015.Geological Characteristics and Prospecting Prediction of Xixibao Super-Large Manganese Deposit in Songtao of Eastern Guizhou.Geological Science and Technology Information, 34(6):8-16 (in Chinese with English abstract).
Zhou, C.M., Tucker, R., Xiao, S.H., et al., 2004.New Constraints on the Ages of Neoproterozoic Glaciations in South China.Geology, 32(5):437-440.doi: 10.1130/g20286.1
Zhou, Q., 1989.A Perlimilary Discussion on the Formation Mechanism of Ore Pillows of Datangpo Rhodochrosite Deposit in Songtao Country, Guizhou Province.Geology of Guizhou, 6(1):1-7 (in Chinese with English abstract).
Zhou, Q., 2008.Geologieal and Geochemical Characteristics of Cold Seek Carbonates of Neoproterozoic Nanhua Period and Their Significance for Manganese Ore Deposits in East Guzhou (Dissertation).China University of Geosciences, Wuhan (in Chinese with English abstract).
Zhou, Q., Du, Y.S., 2012.Palaeo-Gas Seek and Manganese Metallogeny.Geological Press House, Beijing (in Chinese).
Zhou, Q., Du, Y.S., Qin, Y., 2013.Ancient Natural Gas Seepage Sedimentary-Type Manganese Metallogenic System and Ore-Forming Model:A Case Study of 'Datangpo Type' Manganese Deposits Formed in Rift Basin of Nanhua Period along Guizhou-Hunan-Chongqing.Mineral Deposits, 32(3):457-466 (in Chinese with English abstract). https://www.researchgate.net/publication/316648096_Space-time_distribution_of_manganese_ore_deposits_along_the_southern_margin_of_the_South_China_Block_in_the_context_of_Palaeo-Tethyan_evolution
Zhou, Q., Du, Y.S., Wang, J.S., et al., 2007a.Characteristics and Significance of the Cold Seep Carbonates from the Datangpo Formation of the Nanhua Series in the Northeast of Guizhou.Earth Science, 32(3):339-346 (in Chinese with English abstract). https://www.researchgate.net/publication/286286214_Origin_and_petroleum_geological_significance_of_carbonate_rock_concretes_in_Linxi_Formation_northeast_of_Inner_Mongolia_China
Zhou, Q., Du, Y.S., Yan, J.X., et al., 2007b.Geological and Geochemical Characteristics of the Cold Seep Carbonates in the Early Nanhua System in Datangpo, Songtao, Guizhou Province.Earth Science, 32(6):845-852 (in Chinese with English abstract). https://www.researchgate.net/publication/289986514_Geological_and_geochemical_characteristics_of_the_cold_seep_carbonates_in_the_early_Nanhua_system_in_Datangpo_Songtao_Guizhou_Province
Zhou, Q., Qin, Y., Zhang, S., et al., 2002.Progress of Looking for the Manganese Ores of Good Quality in the Area of Northeast Guizhou.Geology of Guizhou, 19(4):228-230 (in Chinese with English abstract). https://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=91013LD4.TXT
贵州省地质矿产局, 1987.贵州省区域地质志.北京:地质出版社.
蔡学林, 曹家敏, 朱介寿, 等, 2008.中国大陆岩石圈壳幔韧性剪切带系统.地学前缘, 15(3):36-54. http://www.cnki.com.cn/Article/CJFDTOTAL-DXQY200803002.htm
何卫红, 唐婷婷, 乐明亮, 等, 2014.华南南华纪-二叠纪沉积大地构造演化.地球科学, 39(8):929-953. http://earth-science.net/WebPage/qk.aspx?id=128#
何志威, 杨瑞东, 高军波, 等, 2014.贵州松桃道坨锰矿含锰岩系地球化学特征和沉积环境分析.地质论评, 60(5):1061-1075. http://www.cnki.com.cn/Article/CJFDTOTAL-DZLP201405012.htm
李献华, 李武显, 何斌, 2012.华南陆块的形成与Rodinia超大陆聚合-裂解——观察、解释与检验.矿物岩石地球化学通报, 31(6):543-559. http://www.cnki.com.cn/Article/CJFDTOTAL-KYDH201206001.htm
覃永军, 杜远生, 牟军, 等, 2015.黔东南地区新元古代下江群的地层年代及其地质意义.地球科学, 40(7):1107-1121. http://earth-science.net/WebPage/qk.aspx?id=139#
饶家荣, 王纪恒, 曹一中, 1993.湖南深部构造.湖南地质, (增刊7):1-103. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKX200203010.htm
王剑, 2005.华南"南华系"研究新进展——论南华系地层划分与对比.地质通报, 24(6):491-495. http://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD200506001.htm
王剑, 潘桂棠, 2009.中国南方古大陆研究进展与问题评述.沉积学报, 27(5):818-825. http://www.cnki.com.cn/Article/CJFDTOTAL-CJXB200905007.htm
汪正江, 许效松, 杜秋定, 等, 2013.南华冰期的底界讨论:来自沉积学与同位素年代学证据.地球科学进展, 28(4):477-489. doi: 10.11867/j.issn.1001-8166.2013.04.0477
王自强, 高林志, 丁孝忠, 等, 2012."江南造山带"变质基底形成的构造环境及演化特征.地质论评, 58(3):401-413. http://www.cnki.com.cn/Article/CJFDTOTAL-DZLP201203002.htm
尹崇玉, 高林志, 2013.中国南华系的范畴、时限及地层划分.地层学杂志, 37(4):534-541. http://www.cnki.com.cn/Article/CJFDTOTAL-DCXZ201304017.htm
尹崇玉, 王砚耕, 唐烽, 等, 2006.贵州松桃南华系大塘坡组凝灰岩锆石SHRIMPⅡ U-Pb年龄.地质学报, 80(2):273-278. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE200602019.htm
袁学诚, 华九如, 2011.华南岩石圈三维结构.中国地质, 38(1):1-19. http://www.cnki.com.cn/Article/CJFDTOTAL-DGYK200304001.htm
翟裕生, 张湖, 宋鸿林, 等, 1997.大型构造与超大型矿床.北京:地质出版社.
张飞飞, 闫斌, 郭跃玲, 等, 2013.湖北古城锰矿的沉淀形式及其古环境意义.地质学报, 87(2):245-258. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201302011.htm
张景廉, 2001.论石油的无机成因.北京:石油工业出版社.
张景廉, 2014.二论石油的无机成因.北京:油工业出版社.
张遂, 周琦, 张平壹, 等, 2015.黔东松桃西溪堡超大型锰矿床地质特征与找矿预测.地质科技情报, 34(6):8-16. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201506002.htm
周琦, 1989.松桃大塘坡菱锰矿床矿枕形成机理初探.贵州地质, 6(1):1-7. http://www.cnki.com.cn/Article/CJFDTOTAL-GZDZ198901000.htm
周琦, 2008.黔东新元古代南华纪早期冷泉碳酸盐岩地质地球化学特征及其对锰矿的控矿意义 (博士学位论文).武汉:中国地质大学.
周琦, 杜远生, 2012.古天然气渗漏与锰矿成矿.北京:地质出版社.
周琦, 杜远生, 覃英, 2013.古天然气渗漏沉积型锰矿床成矿系统与成矿模式——以黔湘渝毗邻区南华纪"大塘坡式"锰矿为例.矿床地质, 32(3):457-466. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ201303001.htm
周琦, 杜远生, 王家生, 等, 2007a.黔东北地区南华系大塘坡组冷泉碳酸盐岩及其意义.地球科学, 32(3):339-346. http://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200703005.htm
周琦, 杜远生, 颜佳新, 等, 2007b.贵州松桃大塘坡地区南华纪早期冷泉碳酸盐岩地质地球化学特征.地球科学, 32(6):845-852. http://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200706016.htm
周琦, 覃英, 张遂, 等, 2002.黔东北地区优质锰矿找矿进展与前景展望.贵州地质, 19(4):228-230. http://www.cnki.com.cn/Article/CJFDTOTAL-GZDZ200204002.htm