Hydrochemical Characteristics and Formation Causes of Karst Water in Jinan Spring Catchment
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摘要: 济南泉域水质逐年变差，查明其污染来源和影响因素，对岩溶水资源开发利用及生态环境保护具有十分重要的意义，而对包含补给径流区的全区岩溶水系统分析尚未见报道.综合运用水化学(Piper三线图、离子比例系数、相关分析)和多元统计(因子分析、聚类分析)方法分析地下水水化学特征，探讨了不同区域水质影响因素及影响强度.因子分析反映了灰岩水岩作用、工业和生活污染、白云岩水岩作用、农牧业和生活污染对水化学组分的影响，贡献率依次为33.1%、28.4%、12.0%和11.8%.分析结果表明：研究区岩溶水水质受水岩作用和人类活动的双重影响；南部补给区、西郊及其以西排泄区水质优良，主要受碳酸盐岩溶解的影响；直接补给径流区部分岩溶水受农牧业和农村生活污染的影响，NO3-含量较高；东郊排泄区、城区及近郊开采区受工业及城镇生活污染的影响，水质较差，少数地段SO42-、NO3-、TDS和总硬度超标.Abstract: Water quality of Jinan spring catchment is getting worse year by year. It is of great significance to find out the pollution sources and influence factors for exploitation of the karst water and ecological environment protection. However, analysis of the whole karst water system including the recharge and runoff area has not been reported yet. Hydrochemical method (piper diagram, ion ratio, correlation analysis) and multivariate statistical method (factor analysis and cluster analysis) were comprehensively used to analyze the hydrochemical characteristics of groundwater, as well as the factors affecting water quality and relevant impact strength in different areas in this study. Factor analysis indicates the effects of water-rock interaction between limestone and groundwater, industrial and domestic pollution, water-rock interaction between dolomite and groundwater, and agriculture, husbandry and domestic pollution. Their contribution rates to groundwater quality are 33.1%, 28.4%, 12.0%, and 11.8%, respectively. Combined with hydrochemical and cluster analyses, the results indicate that groundwater quality in the study area is controlled by both water-rock interaction and anthropogenic activities. Groundwater with high quality in the southern recharge area and western discharge area is mainly affected by the dissolution of carbonate minerals. Some parts of the recharge-runoff area are influenced by agriculture, husbandry and rural domestic pollution with higher content of nitrate in the groundwater. Industrial and urban domestic pollution severely impacts the eastern suburb, urban and suburban exploitation area with poor groundwater quality and excessive levels of SO42-, NO3-, TDS and total hardness in a few sections.
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Key words:
- Jinan spring catchment /
- karst water /
- hydrochemistry /
- multivariate statistics /
- cluster analysis /
- formation cause /
- hydrogeology
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图 3 济南岩溶地下水水化学类型分布
Fig. 3. The spatial distribution of hydrochemical types of karst groundwater in Jinan
图 4 TDS与矿物饱和指数关系
Sic.方解石饱和指数；Sid.白云石饱和指数；Sig.石膏饱和指数；SIh.岩盐饱和指数
Fig. 4. Relationships between TDS and the saturation indexes of minerals
图 5 离子比值关系
图a, b中，mEq/L=mmol/L×原子价
Fig. 5. Relationships between the ratios of the selected ions
图 6 研究区地下水水化学样品聚类树状图
Fig. 6. Cluster dendrogram of groundwater hydrochemical samples in the study area
图 7 水化学样品系统聚类空间分布
Fig. 7. Spatial distribution of the hydrochemical sample clusters from HCA
表 1 济南岩溶水水化学分析结果统计
Table 1. Results of the hydrochemical analysis of karst water in Jinan
参数 单位 极小值 极大值 均值 标准差 变异系数 T ℃ 10.3 17.0 16.6 1.22 0.07 pH / 7.7 8.5 8.1 0.17 0.02 K++Na+ mg/L 3.0 170.6 18.9 24.15 1.28 Ca2+ mg/L 66.3 197.0 105.4 26.54 0.25 Mg2+ mg/L 10.4 36.6 20.5 5.48 0.27 Cl- mg/L 7.6 247.7 35.7 38.12 1.07 SO42- mg/L 30.6 287.5 91.2 43.42 0.48 HCO3- mg/L 144.3 348.3 251.6 41.51 0.17 NO3- mg/L 5.6 100.3 37.8 22.92 0.61 F- mg/L 0.1 0.4 0.2 0.07 0.35 TDS mg/L 270.3 1125 449.9 134.67 0.30 总硬度 mg/L 228.4 607.4 347.7 75.57 0.22 COD mg/L 0.2 1.8 0.6 0.33 0.54 注：变异系数无量纲. 
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表 2 岩溶水各水化学组分间的相关系数
Table 2. Correlation coefficient of hydrochemical composition of karst groundwater
项目 K++Na+ Ca2+ Mg2+ Cl- SO42- HCO3- NO3- F- pH TDS 总硬度 COD K++Na+ 1.00 0.55* 0.28* 0.94* 0.68* 0.31* -0.11 0.14 -0.37* 0.82* 0.57* 0.55* Ca2+ 1.00 0.27* 0.65* 0.69* 0.70* 0.47* 0.11 -0.62* 0.91* 0.96* 0.10 Mg2+ 1.00 0.26 0.44* 0.51* 0.11 0.06 -0.23 0.46* 0.54* 0.05 Cl- 1.00 0.61* 0.35* -0.01 0.14 -0.46* 0.84* 0.65* 0.46* SO42- 1.00 0.30* -0.01 0.06 -0.29* 0.82* 0.74* 0.40* HCO3- 1.00 0.40* -0.01 -0.68* 0.63* 0.77* -0.16 NO3- 1.00 0.35* -0.21 0.31* 0.44* -0.25 F- 1.00 0.10 0.18 0.12 0.11 pH 1.00 -0.55* -0.61* 0.03 TDS 1.00 0.93* 0.31* 总硬度 1.00 0.10 COD 1.00 注：*表示通过α=0.05显著性检验.
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表 3 旋转因子载荷矩阵
Table 3. Matrix of rotated factor loadings
水化学指标 F1 F2 F3 F4 K++Na+ 0.313 0.885* 0.103 -0.007 Ca2+ 0.844* 0.385 0.116 0.217 Mg2+ 0.201 0.111 0.941* 0.021 Cl- 0.438 0.824* 0.030 0.031 SO42- 0.337 0.688* 0.409 0.017 HCO3- 0.832* -0.033 0.367 0.029 NO3- 0.510 -0.292 0.008 0.691* F- -0.120 0.174 0.031 0.885* pH- 0.831* -0.128 0.027 0.180 TDS 0.677* 0.642* 0.283 0.191 总硬度 0.800* 0.371 0.382 0.197 COD -0.238 0.798* -0.029 0.009 贡献率(%) 33.067 28.440 12.007 11.820 累积贡献率(%) 33.067 61.507 73.514 85.334 注：*表示较高的因子载荷.
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表 4 系统聚类水化学参数平均含量
Table 4. Average contents of hydrochemical parameters in the clusters determined from HCA
Cluster n K++Na+ Ca2+ Mg2+ Cl- SO42- HCO3- NO3- F- pH TDS 总硬度 COD 1 16 10.9 86.6 18.9 21.4 65.8 239.3 24.9 0.2 8.1 361.0 294.3 0.4 2 11 14.6 84.9 17.3 22.5 87.6 200.2 23.3 0.3 8.3 366.0 283.2 0.9 3 18 15.4 114.3 20.2 31.7 85.2 268.8 53.0 0.2 8.1 468.8 368.6 0.5 4 9 28.4 135.9 27.1 61.6 130.9 293.5 50.7 0.2 8.0 597.8 451.0 0.6 5 1 170.6 197.0 28.0 247.7 287.5 326.3 12.5 0.2 7.7 1125 607.4 1.8 注：n表示各类所包含的样品数量，各指标(除pH)单位均为mg/L.
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An, L.S., Zhao, Q.S., Ye, S.Y., et al., 2012.Hydrochemical Characteristics and Formation Mechanism of Shallow Groundwater in the Yellow River Delta.Environmental Science, 33(2):370-378(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-HJKZ201202007.htm Bo, K.T., Cai, Y.X., 2016.Evaluation on Groundwater Pollution Degree in Jinan Karst Area.Shandong Land and Resources, 32(3):51-55(in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTotal-SDDI201603014.htm Cao, Y., Teng, Y.G., Liu, Y.Z., 2013.Multivariate Statistical Approach to Identify Influencing Factors of Groundwater Quality in Jinji Water Source of Wuzhong City.Journal of Jilin University(Earth Science Edition), 43(1):235-244 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-CCDZ201301031.htm Cloutier, V., Lefebvre, R., Therrien, R., et al., 2008.Multivariate Statistical Analysis of Geochemical Data as Indicative of the Hydrogeochemical Evolution of Groundwater in a Sedimentary Rock Aquifer System.Journal of Hydrology, 353(3-4):294-313.doi: 10.1016/j.jhydrol.2008.02.015 Gao, Z.J., Xu, J.X., Wang, S.C., et al., 2014.The Distribution Characteristics and Hydrogeological Significance of Trace Elements in Karst Water, Jinan, China.Earth Science Frontiers, 21(4):135-146(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DXQY201404020.htm Güler, C., Kurt, M.A., Alpaslan, M., et al., 2012.Assessment of the Impact of Anthropogenic Activities on the Groundwater Hydrology and Chemistry in Tarsus Coastal Plain (Mersin, SE Turkey) Using Fuzzy Clustering, Multivariate Statistics and GIS Techniques.Journal of Hydrology, 414-415:435-451.doi: 10.1016/j.jhydrol.2011.11.021 Güler, C., Thyne, G.D., McCray, J.E., et al., 2002.Evaluation of Graphical and Multivariate Statistical Methods for Classification of Water Chemistry Data.Hydrogeology Journal, 10(4):455-474.doi: 10.1007/s10040-002-0196-6 Han, Y., Bian, J.M., Gu, T.X., et al., 2016.Hydrochemical Parameter Characteristics and Evolution Laws of Groundwater in Songyuan City.Journal of Jilin Agricultural University, 38(2):175-181(in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTotal-JLNY201602010.htm Hong, T., Xie, Y.Q., Yu, Q.W., et al., 2016.Hydrochemical Characteristics Study and Genetic Analysis of Groundwater in a Key Region of the Wumeng Mountain, Southwestern China.Earth and Environment, 44(1):11-18(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-DZDQ201601002.htm Huang, G.X., Sun, J.C., Zhang, Y., et al., 2013.Impact of Anthropogenic and Natural Processes on the Evolution of Groundwater Chemistry in a Rapidly Urbanized Coastal Area, South China.Science of the Total Environment, 463-464:209-221.doi: 10.1016/j.scitotenv.2013.05.078 Jiang, Y.J., Wu, Y.X., Groves, C., et al., 2009.Identification of Influencing Factors of Groundwater Quality Variation Using Factor Analysis.Hydrogeology & Engineering Geology, 36(4):1-7(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SWDG200904003.htm Kang, F.X., Jin, M.G., Qin, P.R., 2011.Sustainable Yield of a Karst Aquifer System:A Case Study of Jinan Springs in Northern China.Hydrogeology Journal, 19(4):851-863.doi: 10.1007/s10040-011-0725-2 Lang, X.J., Lin, W.J., Liu, Z.M., et al., 2016.Hydrochemical Characteristics of Geothermal Water in Guide Basin.Earth Science, 41(10):1723-1734(in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTotal-DQKX201610008.htm Li, Y.Z., Jia, X.F., Xu, C.Y., et al., 2013.A Study on the Source Tracing of Groundwater Nitrate in Shandong Province.Ecology and Environmental Sciences, 22(8):1401-1407(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-TRYJ201308021.htm Liu, B., Wang, Q.B., 2012.Pollution Evaluation and Analysis on and Prevention and Control Countermeasures to the Groundwater of Jinan Oil Refinery.China Population, Resources and Environment, 22(5):335-338(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZGDH201201027.htm Liu, J.H., Zheng, X.Q., 2012.Research on Dynamic Change of Landscape Pattern and Characteristics Based on GIS and RS in Jinan City.In:Liu, Y.S., Xiong, K.N., Dan, W.H., eds., Research on Rural Land Consolidation and Rural-Urban Harmonies Development in China.Guizhou Science and Technology Publishing House, Guiyang, 497-503(in Chinese with English abstract). Liu, L., 2010.Study on Hydrochemical Character of Karst Water and Its Indication in Jinan Spring(Dissertation).Jinan University, Jinan(in Chinese with English abstract). Lu, H.H., Zhang, C., 2007.The Variations of Groundwater Quality and Its Relationship with Human Activity.Research of Soil and Water Conservation, 14(6):238-240(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-STBY200706071.htm Machiwal, D., Jha, M.K., 2015.Identifying Sources of Groundwater Contamination in a Hard-Rock Aquifer System Using Multivariate Statistical Analyses and GIS-Based Geostatistical Modeling Techniques.Journal of Hydrology:Regional Studies, 4:80-110.doi: 10.1016/j.ejrh.2014.11.005 Ning, L.B., Feng, Q.Z., Xu, H.L., et al., 2015.The Distribution and Formation Mechanism of Fluorine in Groundwater of Henan Province.Geological Publishing House, Beijing, 22-39(in Chinese). Qi, X.F., Li, W.P., Li, H.T., et al., 2015.Teleconnections between Groundwater Levels, Precipitation, Air Temperature of the Jinan Karst Springs Watershed and Large Scale Climatic Patterns.Hydrogeology & Engineering Geology, 42(6):18-28(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-SWDG201506005.htm Reis, A.P., Sousa, A.J., Ferreira da Silva, E., et al., 2004.Combining Multiple Correspondence Analysis with Factorial Kriging Analysis for Geochemical Mapping of the Gold-Silver Deposit at Marrancos (Portugal).Applied Geochemistry, 19(4):623-631.doi: 10.1016/j.apgeochem.2003.09.003 Shi, J., Lu, G.M., Jiang, S., et al., 2012.Study on Present Condition and Countermeasures of Groundwater Pollution in Jinan Spring Areas.Shandong Land and Resources, 28(9):21-24(in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTOTAL-SDDI201209007.htm Sun, B., Xing, L.T., 2010.Research on Groundwater Chemical Characteristics in Urban Areas in Jinan.China Rural Water and Hydropower, (11):33-37, 40 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZNSD201011008.htm Valdes, D., Dupont, J.P., Laignel, B., et al., 2007.A Spatial Analysis of Structural Controls on Karst Groundwater Geochemistry at a Regional Scale.Journal of Hydrology, 340(3-4):244-255.doi: 10.1016/j.jhydrol.2007.04.014 Wan, L.Q., Xu, H.Z., Yin, X.L., et al., 2008.Formation of Hydrochemistry Components of Karst Groundwater in Jinan.Hydrogeology & Engineering Geology, 35(3):61-64(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SWDG200803014.htm Wang, D.H., Li, C., Gao, Y., et al., 2003.Effect on Groundwater Quality of Jinan Spring Region by Human Activity.Environmental Monitoring in China, 19(5):18-21(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-IAOB200305005.htm Wang, J.L., Jin, M.G., Lu, G.P., et al., 2016.Investigation of Discharge-Area Groundwaters for Recharge Source Characterization on Different Scales:The Case of Jinan in Northern China.Hydrogeology Journal, 24(7):1723-1737.doi: 10.1007/s10040-016-1428-5 Wang, S.C., 2014.Effect on Groundwater Environment in Urbanization of Jinan City(Dissertation).Shandong University of Science and Technology, Qingdao(in Chinese with English abstract). Wang, Y.X., Guo, Q.H., Su, C.L., et al., 2006.Strontium Isotope Characterization and Major Ion Geochemistry of Karst Water Flow, Shentou, Northern China.Journal of Hydrology, 328(3-4):592-603.doi: 10.1016/j.jhydrol.2006.01.006 Wang, Z.L., Gao, Z.J., Xu, Y., et al., 2013.Hydrochemical Characteristics of Karst Water in Jinan Spring Region.Shandong Land and Resources, (2):27-29(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SDDI201302009.htm Xiang, D.J., Li, H.W., Liu, X.Y., 2005.Applied Multivariate Statistical Analysis.China University of Geosciences Press, Wuhan, 100-180(in Chinese). Xu, H.Z., Duan, X.M., Gao, Z.D., et al., 2007.Hydrochemical Study of Karst Groundwater in the Jinan Spring Catchment.Hydrogeology & Engineering Geology, 34(3):15-19(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SWDG200703005.htm Xu, J.X., Xing, L.T., Wei, L.F., et al., 2012.Research on Karst Water System in Jinan.Metallurgical Industry Press, Beijing, 31-137(in Chinese). Xu, L.H., 2007.Study on the Capacity & Total Quantity Control of SO2 in Jinan City(Dissertation).Shandong Normal University, Jinan(in Chinese with English abstract). Yang, L.Z., Liu, C.H., Qi, X.F., 2016.Study on Characteristic Variation of Hydro-Chemistry of Jinan Spring.Journal of Water Resources & Water Engineering, 27(1):59-64(in Chinese with English abstract). http://kns.cnki.net/KCMS/detail/detail.aspx?filename=mevr201606008&dbname=CJFD&dbcode=CJFQ Yang, L.Z., Liu, C.H., Zhu, H.H., 2015.Studies on Hydro-Chemistry Characteristics and the Causation of Variation of Karst Water in the Jinan Wellspring District.In:Hu, X., ed., New Advancement of Geoscience in 2015:Proceedings of the 13th Science and Technology Forum in East China of Six Provinces and One City.Jiangxi Science and Technology Press, Nanchang, 323-327(in Chinese with English abstract). Yu, D.L., Zheng, L.S., Yu, S.L., 2015.Influence Analysis of Waste Landfill in Southern Jinan to Groundwater Quality.Shandong Land and Resources, 31(8):54-57(in Chinese with English abstract). Yuan, J.F., Deng, G.S., Xu, F., et al., 2016.The Multivariate Statistical Analysis of Chemical Characteristics and Influencing Factors of Karst Groundwater in the Northern Part of Bijie City, Guizhou Province.Geology in China, 43(4):1446-1456(in Chinese with English abstract). https://www.researchgate.net/publication/271951033_Identifying_the_hydrochemical_characteristics_of_rivers_and_groundwater_by_multivariate_statistical_analysis_in_the_Sanjiang_Plain_China Zhang, B., Song, X.F., Zhang, Y.H., et al., 2012.Hydrochemical Characteristics and Water Quality Assessment of Surface Water and Groundwater in Songnen Plain, Northeast China.Water Research, 46(8):2737-2748.doi: 10.1016/j.watres.2012.02.033 Zhang, P.F., 2012.A Study on Causes and Prevention Countermeasures of River Basin Water Pollution(Dissertation).Shandong University, Jinan(in Chinese with English abstract). Zhao, Z.F., Ou, L., Qin, D.J., et al., 2012.Factors Controlling Hydrochemical Characteristics of Karstic Water in Jinan.China Rural Water and Hydropower, (7):32-37(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZNSD201207010.htm Zhuang, Y.Q., Guo, Q.H., Liu, M.L., et al., 2016.Geochemical Simulation of Thioarsenic Speciation in High-Temperature, Sulfide-Rich Hot Springs:A Case Study in the Rehai Hydrothermal Area, Tengchong, Yunnan.Earth Science, 41(9):1499-1510(in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTotal-DQKX201609006.htm 安乐生, 赵全升, 叶思源, 等, 2012.黄河三角洲浅层地下水化学特征及形成作用.环境科学, 33(2):370-378. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKZ201202007.htm 薄克庭, 蔡有兄, 2016.济南地区岩溶地下水污染程度评价.山东国土资源, 32(3):51-55. http://www.cnki.com.cn/Article/CJFDTOTAL-SDDI201603014.htm 曹阳, 滕彦国, 刘昀竺, 2013.宁夏吴忠市金积水源地地下水水质影响因素的多元统计分析.吉林大学学报(地球科学版), 43(1):235-244. http://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ201301031.htm 高宗军, 徐军祥, 王世臣, 等, 2014.济南岩溶水微量元素分布特征及其水文地质意义.地学前缘, 21(4) :135-146. http://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201404020.htm 韩宇, 卞建民, 谷天雪, 等, 2016.松原市地下水水化学参数特征及变化规律.吉林农业大学学报, 38(2):175-181. http://www.cnki.com.cn/Article/CJFDTOTAL-JLNY201602010.htm 洪涛, 谢运球, 喻崎雯, 等, 2016.乌蒙山重点地区地下水水化学特征及成因分析.地球与环境, 44(1):11-18. http://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ201601002.htm 蒋勇军, 吴月霞, Groves, C., 等, 2009.利用因子分析确定岩溶地下河系统水质的影响因素.水文地质工程地质, 36(4):1-7. http://www.cnki.com.cn/Article/CJFDTOTAL-SWDG200904003.htm 郎旭娟, 蔺文静, 刘志明, 等, 2016.贵德盆地地下热水水文地球化学特征.地球科学, 41(10):1723-1734. http://www.earth-science.net/WebPage/Article.aspx?id=3374 李玉中, 贾小妨, 徐春英, 等, 2013.山东省地下水硝酸盐溯源研究.生态环境学报, 22(8):1401-1407. http://cdmd.cnki.com.cn/Article/CDMD-82101-2010171089.htm 刘斌, 王庆兵, 2012.济南炼油厂对地下水污染评价及防治对策分析.中国人口:资源与环境, 22(5):335-338. http://www.cnki.com.cn/Article/CJFDTOTAL-ZGRZ2012S1080.htm 刘金花, 郑新奇, 2012. 基于GIS和RS的山东济南近10年土地利用景观格局动态变化研究. 见: 刘彦随, 熊康宁, 但文红, 编, 中国农村土地整治与城乡协调发展研究. 贵阳: 贵州科技出版社, 497-503. 刘莉, 2010. 济南泉域岩溶水水化学特征及其指示作用研究(硕士学位论文). 济南: 济南大学. 路洪海, 章程, 2007.济南泉域岩溶水质演变及其对人类活动的响应.水土保持研究, 14(6):238-240. http://www.cnki.com.cn/Article/CJFDTOTAL-STBY200706071.htm 宁立波, 冯全洲, 徐恒力, 等, 2015.河南省地下水中氟的分布及其形成机理研究.北京:地质出版社, 22-39. 祁晓凡, 李文鹏, 李海涛, 等, 2015.济南岩溶泉域地下水位、降水、气温与大尺度气象模式的遥相关.水文地质工程地质, 42(6):18-28. http://www.cnki.com.cn/Article/CJFDTOTAL-SWDG201506005.htm 石建, 逯光明, 姜山, 等, 2012.济南泉域地下水污染现状及对策研究.山东国土资源, 28(9):21-24. http://www.cnki.com.cn/Article/CJFDTOTAL-SDDI201209007.htm 孙斌, 邢立亭, 2010.济南市区附近地下水化学特征研究.中国农村水利水电, (11):33-37, 40. http://www.cnki.com.cn/Article/CJFDTOTAL-ZNSD201011008.htm 万利勤, 徐慧珍, 殷秀兰, 等, 2008.济南岩溶地下水化学成分的形成.水文地质工程地质, 35(3):61-64. http://www.cnki.com.cn/Article/CJFDTOTAL-SWDG200803014.htm 王东海, 李春, 高焰, 等, 2003.人类活动对济南泉域地下水水质的影响.中国环境监测, 19(5):18-21. http://www.cnki.com.cn/Article/CJFDTOTAL-IAOB200305005.htm 王世臣, 2014. 济南市城市化对地下水环境的影响(硕士学位论文). 青岛: 山东科技大学. 王兆林, 高宗军, 徐源, 等, 2013.济南泉域岩溶水水化学特征.山东国土资源, (2):27-29. http://cdmd.cnki.com.cn/Article/CDMD-10427-2010214842.htm 向东进, 李宏伟, 刘小雅, 2005.实用多元统计分析.武汉:中国地质大学出版社. 徐慧珍, 段秀铭, 高赞东, 等, 2007.济南泉域排泄区岩溶地下水水化学特征.水文地质工程地质, 34(3):15-19. http://www.cnki.com.cn/Article/CJFDTOTAL-SWDG200703005.htm 徐军祥, 邢立亭, 魏鲁峰, 等, 2012.济南岩溶水系统研究.北京:冶金工业出版社, 31-137. 徐丽华, 2007. 济南市SO2容量及总量控制研究(硕士学位论文). 济南: 山东师范大学. 杨丽芝, 刘春华, 祁晓凡, 2016.济南泉水水化学特征变异研究.水资源与水工程学报, 27(1):59-64. http://www.cnki.com.cn/Article/CJFDTOTAL-XBSZ201601010.htm 杨丽芝, 刘春华, 朱恒华, 2015. 济南泉域岩溶水水化学变异特征与成因探讨. 见: 胡宪, 编, 地学新进展——第十三届华东六省一市地学科技论坛文集. 江西科学技术出版社, 南昌, 323-327. 于大潞, 郑丽爽, 于世林, 2015.济南南部垃圾填埋场对地下水质量的影响分析.山东国土资源, 31(8):54-57. http://www.cnki.com.cn/Article/CJFDTOTAL-SDDI201508020.htm 袁建飞, 邓国仕, 徐芬, 2016.毕节市北部岩溶地下水水化学特征及影响因素的多元统计分析.中国地质, 43(4):1446-1456. http://www.cnki.com.cn/Article/CJFDTOTAL-DIZI201604029.htm 张彭飞, 2012. 流域水污染的成因及防治对策研究(硕士学位论文). 济南: 山东大学. 赵占锋, 欧璐, 秦大军, 等, 2012.济南岩溶水水化学特征及影响因素.中国农村水利水电, (7):32-37. http://www.cnki.com.cn/Article/CJFDTOTAL-ZNSD201207010.htm 庄亚芹, 郭清海, 刘明亮, 等, 2016.高温富硫化物热泉中硫代砷化物存在形态的地球化学模拟:以云南腾冲热海水热区为例.地球科学, 41(9):1499-1510. http://www.earth-science.net/WebPage/Article.aspx?id=3356 -
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