13X沸石对Ni<sup>2+</sup>吸附性能的实验研究

肖万; 马鸿文; 杨静; 王英滨

13X沸石对Ni²⁺吸附性能的实验研究

中国地质大学矿物材料国家专业实验室, 北京 100083

基金项目:

教育部博士学科点基金 1999049114

矿物材料国家专业实验室开放基金 98015

详细信息

作者简介:
肖万(1975-), 男, 硕士, 2002年毕业于中国地质大学(北京), 现从事矿物材料学研究

中图分类号: P578
计量
- 文章访问数: 3893
- HTML全文浏览量: 317
- PDF下载量: 10
- 被引次数: 0
出版历程
- 收稿日期: 2002-05-15
- 刊出日期: 2003-01-25

Adsorption of 13X Zeolite on Ni²⁺ in Wastewater: An Experimental Study

National Laboratory ofMineral Materials, China University ofGeosciences, Beijing 100083, China

摘要

摘要: 在静态条件下, 实验研究了13X沸石的用量、温度、时间、溶液pH值、初始Ni²⁺质量浓度对Ni²⁺+ 吸附性能的影响.结果表明: 在室温下, 13X沸石对Ni²⁺+ 的吸附平衡时间为15min, 对Ni²⁺+ 的最大吸附量为4 9.7mg/ g沸石; 静态等温吸附过程符合Langmiur吸附等温方程式; 13X沸石对Ni²⁺+ 的吸附机理为离子交换吸附和表面络合吸附
- 13X沸石 /
- 含Ni2+废水 /
- 吸附机理
Abstract: The absorbability of 13X zeolite on Ni²⁺ in wastewater was experimentally studied. The absorption rate, isotherms, capacity and effects of such factors on the absorbability as pH value, Ni²⁺ concentration in the wastewater, temperature, time and dosage of wastewater were characterized separately. The mechanism for adsorption of 13X zeolite on Ni²⁺ was also studied. The results show that at ambient temperature, the adsorption capacity of 13X zeolite on Ni²⁺ in wastewater was 49.7 mg/g zeolite in 15 minutes. The adsorption isotherm for the process exhibits Langmiur behavior, and the ion exchange and surface complex were suggested to be the major adsorption mechanisms in the experiments.
- 13X zeolite /
- wastewater bearing Ni²⁺ /
- mechanism of adsorption

HTML全文

图 1 13X沸石吸附Ni²⁺的lnρ-lnQ (a) 和1/Q-1/ρ (b) 图

Fig. 1. lnρ-lnQ and 1/Q-1/ρ plots on absorption of 13X zeolite for Ni²⁺

下载: 全尺寸图片幻灯片

表 1 13X沸石分子筛的化学分析结果

Table 1. Chemical analysis of the synthesized 13X zoelite molecular sieve w_B/%

表 2 pH值对13X沸石吸附Ni²⁺离子效率的影响

Table 2. Effects of pH value on adsorption efficiency of the 13X zeolite

表 3 初始质量浓度对13X沸石吸附Ni²⁺离子效率的影响

Table 3. Effects of initial Ni²⁺ concentration on adsorption efficiency of the 13X zeolite

表 4 沸石用量对13X沸石吸附Ni²⁺离子效率的影响

Table 4. Effects of zeolite dosage on adsorption efficiency of the 13X zeolite

表 5 吸附时间对13X沸石吸附Ni²⁺离子效率的影响

Table 5. Effects of time on adsorption efficiency of the 13X zeolite

表 6 温度对13X沸石吸附Ni²⁺离子效率的影响

Table 6. Effects of temperature on adsorption efficiency of the 13X zeolite

表 7 剩余质量浓度与吸附量的关系

Table 7. Relation of remaining Ni²⁺ concentration in the solution and adsorptive quantities

表 8 某电镀厂废水的静态吸附实验结果

Table 8. Results of static adsorption of Ni²⁺ in electroplating wastewater

参考文献(12)

[1]	宋和付, 夏畅斌, 何湘柱, 等. 天然沸石对Pb (Ⅱ) 和Ni (Ⅱ) 离子的吸附作用研究[J]. 矿产地质, 2000, (4): 276-278. https://www.cnki.com.cn/Article/CJFDTOTAL-KCYD200004016.htm SONG H F, XIA C B, HE X Z, et al. Study on adsorption of natural zeolite for Pb(Ⅱ)and Ni(Ⅱ)[J]. Mineral Resources and Geology, 2000, (4): 276- 278. https://www.cnki.com.cn/Article/CJFDTOTAL-KCYD200004016.htm
[2]	高效江, 戎秋涛. 麦饭石对重金属离子的吸附作用研究[J]. 环境污染与防治, 1997, 19 (4): 4-7. https://www.cnki.com.cn/Article/CJFDTOTAL-HJWR199704001.htm GAO X J, RONG Q T. Study on adsorption of medicinal tone"Maifanshi" for heavy-metal ions metalions[ J]. Environmental Pollution and Prevention, 1997, 19(4): 4- 7. https://www.cnki.com.cn/Article/CJFDTOTAL-HJWR199704001.htm
[3]	胡艳海, 王继库, 邵淑华. 活性沸石对重金属离子的吸附及再生性研究[J]. 无机盐工业, 1997, (2): 5-6. https://www.cnki.com.cn/Article/CJFDTOTAL-WJYG702.001.htm HU Y H, WANG J K, SHAO S H. Study on regeneration and adsorption of activated zeolite for heavy metals[ J]. Inorganic Chemicals Industry, 1997, (2): 5- 6. https://www.cnki.com.cn/Article/CJFDTOTAL-WJYG702.001.htm
[4]	霍爱群, 姜华. 改性天然沸石用于饮用水体除铅机理探讨[J]. 无机盐工业, 1998, 30 (2): 14-15. https://www.cnki.com.cn/Article/CJFDTOTAL-WJYG802.004.htm HUO A Q, JIANG H. Mechanism on adsorption of lead in drinking water with natural zeolite[J]. Inorganic Chemicals Industry, 1998, 30(2): 14- 15. https://www.cnki.com.cn/Article/CJFDTOTAL-WJYG802.004.htm
[5]	夏畅斌. 麦饭石对Pb²+离子吸附的动力学研究[J]. 环境化学, 2000, 19 (5): 436-440. doi: 10.3321/j.issn:0254-6108.2000.05.009 XIA C B. Kinetics of the adsorption of Pb²⁺ ion with medicinal stone"Maifanshi" in aqueous solutions[J]. Enviromental Chemistry, 2000, 19(5): 436- 440. doi: 10.3321/j.issn:0254-6108.2000.05.009
[6]	张兆春, 刘兴沛, 管清佩, 等. 活性矸吸附剂处理含磷废水的研究[J]. 山东煤炭科技, 1995, (1): 51-53. https://www.cnki.com.cn/Article/CJFDTOTAL-MTSD501.016.htm ZHANG Z C, LIU X P, GUAN Q P, et al. Study on purifying phosphate in drinking water with activated coal waste adsorbent[ J]. Coal Science and Technology of Shandong, 1995, (1): 51- 53. https://www.cnki.com.cn/Article/CJFDTOTAL-MTSD501.016.htm
[7]	王鲁敏, 邓昌亮, 殷军港, 等. 硝化褐煤对铬离子溶液的吸附研究[J]. 环境化学, 2001, 20 (1): 54-58. https://www.cnki.com.cn/Article/CJFDTOTAL-HJHX200101010.htm WANG L M, DENG C L, YIN J G, et al. Study on adsorption of nitrify lignite for chromium ion in solution[ J]. Environmental Chemistry, 2001, 20(1): 54- 58. https://www.cnki.com.cn/Article/CJFDTOTAL-HJHX200101010.htm
[8]	王万金, 白志民, 马鸿文. 利用不溶性钾矿提钾的研究现状及展望[J]. 地质科技情报, 1996, (3): 59-63. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ603.009.htm WANG W J, BAI Z M, MA H W. Preparation of potassium compounds from insoluble potassium ores: developments and prospects[J]. Geological Science and Technology Information, 1996, (3): 59- 63. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ603.009.htm
[9]	马鸿文, 白志民, 王万金, 等. 用钾长石制取沸石分子筛的工艺[P]. 中国专利: ZL96120734.5. 2000-03-17. MA H W, BAI Z M, WANG W J, et al, A technique for synthesizing zeolite molecular sieve from potassium feldspar powder[P]. Chinese Patent, ZL 96 1 20734.5. 2000- 03- 17.
[10]	杨静, 马鸿文, 王英滨, 等. 皖西霞石正长岩合成沸石分子筛及提钾的实验研究[J]. 现代地质, 2000, (2): 153-157. https://www.cnki.com.cn/Article/CJFDTOTAL-XDDZ200002007.htm YANG J, MA H W, WANG Y B, et al. Synthesizing zeolite molecular sieve and preparing potassium carbonate from nepheline syenite of western Anhui Province[ J]. Geoscience, 2000, (2): 153- 157. https://www.cnki.com.cn/Article/CJFDTOTAL-XDDZ200002007.htm
[11]	马鸿文, 陶红, 杨静, 等. 13X沸石用于处理含重金属废水并回收金属的技术[P]. 中华人民共和国专利公告, No. 39, 公开号: CN1267641A. 2000-09-27. MA H W, TAO H, YANG J, et al. A technique for purifying wastewater with heavy metal ions using 13X zeolite molecular sieve and recovering the metals[P]. Bull of Chinese Patent, No. 39, Public No. CN1267641A. 2000-09-27.
[12]	张铨昌. 天然沸石离子交换性能及其应用[M ]. 北京: 科学出版社, 1978. ZHANG Q C. Ion exchange capabilities of natural zeolite, with practical applications[ M]. Beijing: Science Press, 1978.