辽宁后仙峪硼矿区古元古代电气石岩: 锆石特征及SHRIMP定年

张艳飞; 刘敬党; 肖荣阁; 王生志; 王瑾; 包德军

doi:10.3799/dqkx.2010.112

辽宁后仙峪硼矿区古元古代电气石岩: 锆石特征及SHRIMP定年

doi: 10.3799/dqkx.2010.112

张艳飞^{1, 2,},
刘敬党^{1, 2},
肖荣阁³,
王生志²,
王瑾²,
包德军²

1.
辽宁工程技术大学, 辽宁阜新 123000
2.
辽宁省化工地质勘查院, 辽宁锦州 121000
3.
中国地质大学地球科学与资源学院, 北京 100083

基金项目:

国家自然科学基金项目 40073013

辽宁省国土资源厅基金项目 20050142

详细信息

作者简介:
张艳飞(1982-), 男, 在读博士生, 主要从事矿床地球化学研究.E-mail: zhangyanfei1234@163.com

中图分类号: P597
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出版历程
- 收稿日期: 2010-05-15
- 刊出日期: 2010-11-01

The Hyalotourmalites of Houxianyu Borate Deposit in Eastern Liaoning: Zircon Features and SHRIMP Dating

1.
Liaoning Technical University, Fuxin 123000, China
2.
Liaoning Geological Survey for Chemical Industry, Jinzhou 121000, China
3.
School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China

摘要

摘要: 为了确定辽东硼矿含硼岩系中电气石岩的形成时代, 对后仙峪硼矿区电气石岩首次进行了锆石SHRIMP U-Pb年龄测定.阴极发光图像显示, 锆石具核-边结构, 锆石核部多具振荡环带, 为高Th/U值的岩浆碎屑锆石; 锆石边部无明显结构变化, 为变质成因.岩浆碎屑锆石和变质锆石的年龄分别为2 171~2 175 Ma和1 894~1 906 Ma.结合野外地质和岩相学研究, 认为后仙峪硼矿区电气石岩原岩为古元古代克拉通裂谷环境中源于地壳再循环组分混染的亏损地幔的中酸性岩浆活动引发海底喷流作用的产物, 其原岩形成时代为古元古代中期(2 171~2 175 Ma), 并在稍后(1 894~1 906 Ma)遭受变质作用叠加改造.
- 电气石岩 /
- SHRIMP /
- 后仙峪硼矿区 /
- 古元古代 /
- 地质年代
Abstract: SHRIMP zircon U-Pb dating results are firstly reported for the hyalotourmalites in Houxianyu borate deposit in order to determine its formation time. The zircons commonly have core-rim structures. Most cores show oscillatory zoning in CL and plane polarized light images, suggesting a magmatic detrital origin. The zircon without distinct structural change may represent a metamorphic origin. Magmatic detrital zircons and metamorphic zircons from three samples yield ages of 2 171-2 175 Ma and 1 894-1 906 Ma, respectively. Combined with geology and lithology, the protolith of hyalotourmalite is concluded to be the product of exhalation of submarine hot water caused by the magmatic activity with the magma derived from the depleted mantle source with crustal contamination in the cratonic rift environment, which occurred in the middle Palaeoproterozoic (2 171-2 175 Ma) and underwent the late metamorphism during a period of 1 894-1 906 Ma.
- hyalotourmalite /
- SHRIMP dating /
- Houxianyu boron deposit /
- Palaeoproterozoic /
- geochronology

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图 1 后仙峪硼矿床地质略图(据黄作良等(1996)修改)

1.古元古界电气石变粒岩夹黑云变粒岩；2.古元古界黑云变粒岩；3.古元古界蛇纹石化镁橄榄岩及镁质大理岩；4.古元古界电英岩；5.硼矿体；6.片麻状花岗岩；7.伟晶岩；8.闪长玢岩；9.斜长煌斑岩；10.闪长岩；11.推测断层；12.地层产状；13.第四系；14.太古宙古陆；15.裂谷斜坡区；16.裂谷中央凹陷区；17.控制裂谷的深大断裂；18.古断裂；19.地质界线；20.取样位置

Fig. 1. Geological map of the Houxianyu boron deposit

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图 2 电气石岩的宏观和微观构造特点

a.条带(纹)状电气石岩；b.厚层状电气石岩被石英细脉切割；c.电气石岩中较自形的电气石颗粒；d.电气石岩中电气石的筛状结构；Tou.电气石；Q.石英

Fig. 2. Tectonites in the hyalotourmalites at different scales

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图 3 后仙峪硼矿区电气石岩(N13、N14、N02)的锆石阴极发光照片

图中椭圆(~30 μm)为锆石SHRIMP U-Pb测年位置，其编号与表 1中一致

Fig. 3. Cathodoluminescence images of zircons from hyalotourmalite(N13, N14, N02) in Houxianyu borate deposit

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图 4 后仙峪硼矿区电气石岩锆石SHRIMP U-Pb年龄谐和图

Fig. 4. Concordia diagrams of SHRIMP U-Pb data for zircons from hyalotourmalites in Houxianyu borate deposit

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表 1 后仙峪硼矿区电气石岩锆石SHRIMP U-Pb年龄测定结果

Table 1. SHRIMP U-Pb isotope data for zircons from hyalotourmalite in Houxianyu borate deposit

样点	206Pb_c(%)	U(10^-6)	Th(10^-6)	²³²Th/²³⁸U	²⁰⁶Pb^* (10^-6)	²⁰⁶Pb/²³⁸U 年龄(Ma)	²⁰⁷Pb/²⁰⁶Pb 年龄(Ma)	不和谐度 (%)	²⁰⁷Pb^/²⁰⁶Pb^	±%	²⁰⁷Pb^*/²³⁵U	±%	²⁰⁶Pb^*/²³⁸U	±%	相关误差
中粗粒电气石岩(N13)
1.1C	0.08	138	77	0.57	47.1	2 152±28	2 154±13	0	0.134 25	0.73	7.340	1.7	0.396 3	1.5	0.899
2.1C	0.05	814	274	0.35	241.0	1 906±23	2 055± 5.7	7	0.126 88	0.32	6.017	1.4	0.343 9	1.4	0.974
2.2R	0.03	587	14	0.02	168.0	1 859±24	1 910±7.2	3	0.116 99	0.40	5.391	1.6	0.334 2	1.5	0.967
2.3R	0.01	496	25	0.05	148.0	1 921±25	1 902±12	-1	0.116 42	0.65	5.572	1.6	0.347 1	1.5	0.916
3.1C	0.17	167	84	0.52	57.8	2 177±28	2 163±13	-1	0.134 88	0.72	7.470	1.7	0.401 7	1.5	0.901
3.2R	0.01	492	18	0.04	132.0	1 756±22	1 902±8.2	8	0.116 45	0.45	5.028	1.5	0.313 1	1.4	0.953
4.1C	0.03	306	182	0.61	101.0	2 094±26	2 177±8.5	4	0.136 07	0.49	7.200	1.5	0.383 7	1.4	0.947
4.2R	0.05	474	23	0.05	139.0	1 895±23	1 893±8.3	0	0.115 86	0.46	5.460	1.5	0.341 8	1.4	0.951
5.1C	0.01	180	90	0.51	61.3	2 150±28	2 179±11	1	0.136 13	0.64	7.430	1.6	0.396 0	1.5	0.920
6.1C	0.07	944	123	0.13	145.0	1 060±21	1 541±10	31	0.095 65	0.54	2.357	2.2	0.178 7	2.2	0.970
7.1C	0.04	298	148	0.51	103.0	2 178±27	2 179±8.2	0	0.136 20	0.47	7.550	1.5	0.402 0	1.4	0.950
7.2R	0.04	602	17	0.03	185.0	1 973±24	1 918±7.0	-3	0.117 49	0.39	5.800	1.5	0.358 0	1.4	0.964
8.1C	0.06	129	86	0.69	45.9	2 230±29	2 173±13	-3	0.135 73	0.72	7.740	1.7	0.413 4	1.6	0.907
8.2R	0.01	537	29	0.06	155.0	1 873±23	1 897±7.5	1	0.116 13	0.42	5.400	1.5	0.337 2	1.4	0.959
9.1C	0.03	346	270	0.81	122.0	2 213±28	2 169±7.6	-2	0.135 43	0.43	7.650	1.6	0.409 5	1.5	0.960
9.2R	0.03	562	30	0.06	171.0	1 954±24	1 912±7.4	-2	0.117 08	0.41	5.717	1.5	0.354 1	1.4	0.960
10.1C	0.04	159	88	0.57	58.8	2 302±31	2 199±11	-5	0.137 76	0.63	8.150	1.7	0.429 3	1.6	0.929
10.2R	0.03	649	27	0.04	197.0	1 951±47	1 911±6.7	-2	0.117 01	0.37	5.700	2.8	0.353 3	2.8	0.991
11.1C	0.02	446	223	0.52	158.0	2 229±29	2 178±6.9	-2	0.136 11	0.40	7.750	1.6	0.413 1	1.5	0.968
11.2R	0.02	467	18	0.04	134.0	1 854±24	1 916±9.4	3	0.117 38	0.53	5.395	1.6	0.333 3	1.5	0.944
12.1C	0.07	216	125	0.60	73.2	2 142±27	2 163±9.4	1	0.134 95	0.54	7.330	1.6	0.394 1	1.5	0.939
12.2R	0.01	547	20	0.04	161.0	1 903±23	1 889±7.2	-1	0.115 58	0.40	5.472	1.5	0.343 4	1.4	0.963
13.1C	0.01	172	99	0.59	58.8	2 156±27	2 182±11	1	0.136 38	0.65	7.470	1.6	0.397 2	1.5	0.916
13.2R	0.03	475	22	0.05	136.0	1 857±23	1 899±8.2	2	0.116 26	0.46	5.353	1.5	0.333 9	1.4	0.951
14.1C	0.15	123	67	0.56	42.4	2 165±29	2 164±14	0	0.135 00	0.82	7.430	1.8	0.399 1	1.6	0.887
14.2R	0.02	534	23	0.04	145.0	1 766±22	1 904±7.6	7	0.116 57	0.42	5.065	1.5	0.315 1	1.4	0.958
15.1C	0.02	386	154	0.41	135.0	2 201±27	2 172±8.6	-1	0.135 66	0.50	7.610	1.5	0.407 0	1.4	0.944
16.1C	0.04	198	137	0.72	67.6	2 161±27	2 183±10	1	0.136 51	0.58	7.500	1.6	0.398 3	1.5	0.930
16.2R	0.01	714	27	0.04	213.0	1 922±23	1 919±6.3	0	0.117 59	0.35	5.633	1.5	0.347 4	1.4	0.971
17.1C	0.09	138	68	0.51	48.0	2 187±32	2 180±13	0	0.136 27	0.73	7.590	1.9	0.403 8	1.7	0.920
17.2R	-	484	21	0.05	146.0	1 938±24	1 905±7.6	-2	0.116 63	0.42	5.638	1.5	0.350 6	1.4	0.958
18.1C	0.00	149	134	0.93	49.6	2 111±30	2 197±13	4	0.137 60	0.74	7.350	1.8	0.387 5	1.7	0.912
18.2R	0.02	562	30	0.06	156.0	1 801±22	1 900±9.8	5	0.116 34	0.55	5.171	1.5	0.322 3	1.4	0.933
19.1C	0.06	135	147	1.13	44.1	2 084±28	2 142±13	3	0.133 33	0.73	7.020	1.7	0.381 6	1.6	0.905
19.2R	0.02	541	18	0.03	147.0	1 776±22	1 897±8.1	6	0.116 10	0.45	5.076	1.5	0.317 1	1.4	0.953
细粒电气石岩(N14)
1.1	0.01	397	295	0.77	138.0	2 190±27	2 183±8.1	0	0.136 50	0.46	7.61	1.5	0.404 5	1.4	0.952
2.1	--	387	217	0.58	135.0	2 194±27	2 142±8.5	-2	0.133 32	0.48	7.45	1.5	0.405 3	1.4	0.947
3.1	0.04	132	81	0.64	45.6	2 175±31	2 182±13	0	0.136 38	0.73	7.55	1.8	0.401 4	1.7	0.916
4.1	0.01	314	176	0.58	110.0	2 198±27	2 167±8.2	-1	0.135 24	0.47	7.58	1.5	0.406 4	1.4	0.950
5.1	0.09	257	174	0.70	83.0	2 054±27	2 153±10	5	0.134 12	0.58	6.94	1.7	0.375 3	1.6	0.937
6.1	0.01	133	65	0.51	45.2	2 147±28	2 166±13	1	0.135 14	0.73	7.36	1.7	0.395 2	1.5	0.901
中细粒电气石岩(N02)
1.1C	0.08	200	81	0.42	65.7	2 081±26	2 166±11	4	0.135 14	0.62	7.10	1.6	0.381 0	1.5	0.921
2.1C	0.13	151	71	0.49	48.7	2 058±26	2 137±12	4	0.132 93	0.69	6.89	1.6	0.376 0	1.5	0.906
3.1C	0.04	354	199	0.58	124.0	2 204±27	2 168±7.5	-2	0.135 32	0.43	7.61	1.5	0.407 6	1.4	0.957
3.2R	0.03	1 002	70	0.07	265.0	1 732±23	1 855±13	7	0.113 44	0.70	4.821	1.7	0.308 2	1.5	0.909
4.1C	0.02	2 211	683	0.32	755.0	2 158±26	2 162±3.2	0	0.134 89	0.18	7.39	1.4	0.397 5	1.4	0.992
5.1C	0.01	533	306	0.59	185.0	2 189±26	2 177±6.1	-1	0.136 05	0.35	7.59	1.4	0.404 4	1.4	0.970
6.1C	0.00	166	77	0.48	55.7	2 121±27	2 123±12	0	0.131 87	0.66	7.08	1.6	0.389 6	1.5	0.914
7.1C	0.04	407	108	0.27	115.0	1 838±23	1 970±8.9	7	0.120 95	0.50	5.503	1.5	0.330 0	1.4	0.944
6.2R	0.08	667	76	0.12	189.0	1 834±22	1 888±7.2	3	0.115 54	0.40	5.242	1.5	0.329 0	1.4	0.961
7.2R	0.01	1 191	61	0.05	349.0	1 891±28	1 846±13	-2	0.112 84	0.73	5.303	1.9	0.340 9	1.7	0.921
8.1C	0.09	166	74	0.46	56.7	2 158±35	2 184±12	1	0.136 53	0.68	7.49	2.0	0.397 7	1.9	0.940
9.1C	0.01	4 028	1 543	0.40	1 280.0	2 035±29	2 112±2.3	4	0.131 10	0.13	6.71	1.7	0.371 1	1.7	0.997
10.1C	0.01	335	242	0.75	120.0	2 249±27	2 181±7.6	-3	0.136 38	0.44	7.85	1.5	0.417 5	1.4	0.956
11.1C	0.02	359	159	0.46	112.0	1 997±26	2 077±8.1	4	0.128 50	0.46	6.43	1.6	0.363 0	1.5	0.956
12.1C	0.02	514	366	0.74	178.0	2 181±27	2 165±6.3	-1	0.135 11	0.36	7.50	1.5	0.402 5	1.5	0.971
13.1C	0.06	268	136	0.52	86.2	2 049±26	2 062±9.6	1	0.127 37	0.54	6.57	1.6	0.374 2	1.5	0.937
14.1C	0.01	911	926	1.05	329.0	2 261±27	2 185±4.7	-3	0.136 67	0.27	7.92	1.5	0.420 1	1.4	0.982
15.1C	0.07	369	197	0.55	127.0	2 178±27	2 172±7.7	0	0.135 67	0.44	7.52	1.5	0.402 0	1.5	0.958
16.1C	0.02	418	203	0.50	126.0	1 942±26	2 157±10	10	0.134 43	0.59	6.51	1.6	0.351 5	1.5	0.933
17.1C	0.08	249	136	0.56	84.3	2 142±30	2 177±9.5	2	0.136 06	0.55	7.39	1.7	0.394 1	1.7	0.950
18.1C	0.02	744	374	0.52	253.0	2 153±26	2 171±5.4	1	0.135 54	0.31	7.41	1.4	0.396 5	1.4	0.976
19.1C	0.12	221	77	0.36	60.8	1 791±23	2 049±12	13	0.126 44	0.68	5.583	1.6	0.320 2	1.5	0.905
19.2R	0.01	525	31	0.06	159.0	1 945±24	1 901±7.8	-2	0.116 36	0.43	5.649	1.5	0.352 1	1.4	0.956
20.1C	0.07	200	93	0.48	62.0	1 986±25	2 098±11	5	0.129 97	0.62	6.47	1.6	0.360 8	1.5	0.920
20.2R	0.08	796	297	0.39	179.0	1 500±21	1 889±7.6	21	0.115 63	0.42	4.175	1.6	0.261 9	1.6	0.966
21.1C	0.03	215	118	0.57	68.2	2 028±29	2 188±11	7	0.136 86	0.62	6.98	1.8	0.369 8	1.7	0.937
注：Pb^*代表放射性成因铅，对样品N13和N02；C和R分别代表锆石的核部和边部.

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