单个油包裹体组分预测及其在油气成藏研究中的应用

平宏伟; 陈红汉; 宋国奇; ThiéryRégis

doi:10.3799/dqkx.2012.090

单个油包裹体组分预测及其在油气成藏研究中的应用

doi: 10.3799/dqkx.2012.090

1.
中国地质大学构造与油气资源教育部重点实验室，湖北武汉 430074
2.
中国科学院地质与地球物理研究所兰州油气资源研究中心，甘肃兰州 730000
3.
中国石化胜利油田分公司，山东东营 257015
4.
帕斯卡大学岩浆与火山实验室，法国克莱蒙费朗 63000

基金项目:

国家重点基础研究发展计划 2012CB214804

详细信息

作者简介:
平宏伟(1982-)，男，讲师，博士，主要从事含烃流体地质研究.E-mail: howping@yahoo.cn

中图分类号: TE122
计量
- 文章访问数: 752
- HTML全文浏览量: 1275
- PDF下载量: 19
- 被引次数: 0
出版历程
- 收稿日期: 2012-03-22
- 网络出版日期: 2021-10-13
- 刊出日期: 2012-07-15

Individual Oil Inclusion Composition Prediction and Its Application in Oil and Gas Accumulation Studies

1.
Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education, China University of Geosciences, Wuhan 430074, China
2.
Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou 730000, China
3.
Shengli Oilfield Company, SINOPEC, Dongying 257015, China
4.
Clermont Université, Université Blaise Pascal, Laboratoire Magmas et Volcans, Clermont-Ferrand 63000, France

摘要

摘要: 了解单个石油包裹体详细的组分信息不仅有助于微观上定量认识油气充注过程中其成熟度的演化，还对精细刻画油气成藏过程中动力演化具有重要意义.根据石油包裹体热动力学原理，利用10个成熟度依次增大的已知组分的原油在匹配其饱和压力和改进气、液相摩尔体积计算前提下，建立了捕获不同组分原油的包裹体均一温度(Th_oil)与其在室温下(20 ℃)气泡充填度(F_v)关系的标准图版，从而通过对比实测的Th_oil和其室温下F_v与标准Th_oil-F_v图版，反推出油包裹体近似等效流体组分.对东营凹陷北带民丰深层油包裹体进行系统荧光分析、显微测温和包裹体体积3D重构等一系列的测定.结果表明丰8井和丰深1井各发生过两幕油气充注，其中丰8井第一幕油气充注(甲烷摩尔含量位于31%~35%之间)对其油气成藏贡献最大；而丰深1井第二幕充注的油气(甲烷摩尔含量大于60%)控制丰深1井凝析油藏成藏.从而为进一步厘定北带深层油气充注PVTxt史奠定基础.
- 包裹体 /
- 均一温度 /
- 热动力学 /
- 东营凹陷 /
- 石油地质
Abstract: The composition information of individual oil inclusion is not only important for quantitatively understanding the maturity evolution of petroleum during the petroleum charging, but also significant for the precise depiction of the dynamic evolution during petroleum accumulation. However, it is very difficult to obtain the detailed composition of individual petroleum inclusion directly by experimental methods. Petroleum inclusions thermodynamics method is an easy and fast indirect method for obtaining the individual petroleum inclusion composition which has been well developed in last ten years. Ten oil composition data with different maturity are used to build the standard relation diagram of oil inclusions homogenization temperature (Th_oil) and the degree of gaseous filling (F_v) at room temperature (20 ℃) using petroleum inclusions thermodynamics method on condition that firstly, match the saturation pressure and improvement of the gas and liquid mole volume calculations, then the equivalent composition can be determined by comparing the measured homogenization temperature and the degree of gaseous filling at room temperature (20 ℃) with the standard Th_oil-F_v diagram. The compositions of petroleum inclusions with different maturity are quantified by a series of measurements on oil inclusions in the deeply buried reservoir in Minfeng area in North Dongying depression including fluorescence analysis, microthermometry and 3D reconstruction of the oil inclusions volume. The results show that both of the well Feng 8 and well Fengshen 1 happened two episodes of petroleum charging events. The first episode oil charging whose methane mole percent content is between 31%-35% contributed to the petroleum accumulation of well Feng 8, and the second episode oil whose methane mole percent content is more than 60% controlled the gas condensate accumulation of well Fengshen 1. The composition prediction results facilitates further establishing the oil and gas charging PVTxt history in the deeply buried reservoir in Minfeng area in North Dongying depression.
- inclusions /
- homogenization temperature /
- thermodynamics /
- Dongying depression /
- petroleum geology

HTML全文

图 1 石油包裹体组分预测原理示意(据Bourdet et al., 2008修改)

a.黑油的P-T相图及5个不同的等容路径(Th₁、Th₂、Th₃、Th₄和Th₅)和所对应的室温下(20 ℃)气/液相体积比(F_v1、F_v2、F_v3、F_v4和F_v5)；b.虚拟的黑油包裹体不同均一温度与室温下(20 ℃)气泡充填度(F_v)关系

Fig. 1. The schematic diagram of petroleum inclusion composition prediction

下载: 全尺寸图片幻灯片

图 2 东营凹陷北带民丰地区丰8井和丰深1井石油包裹体荧光照片

a，a'和e'为透射光，其他为荧光.丰8井，3 943.0 m，泥岩裂缝充填方解石脉中见大量淡黄-白色荧光油包裹体(a~d)；丰8井，4 195.12 m，石英颗粒加大边中见大量淡黄-白色荧光油包裹体(e~f)；丰深1井，4 321.7 m，在穿石英颗粒裂纹中见大量淡黄色荧光油包裹体(a'~b')、蓝白色荧光油包裹体(c'~d')及富气相蓝色荧光凝析油包裹体(e'~f')

Fig. 2. Photomicrographs of petroleum inclusions from well Feng 8 and well Fengshen 1 in Minfeng area in North Dongying depression

下载: 全尺寸图片幻灯片

图 3 东营凹陷北带民丰深层油包裹体均一温度与室温(20 ℃)下气泡充填度(F_v)关系

Fig. 3. The relational graph of homogenization temperature and the degree of gaseous filling (F_v) under room temperature (20 ℃) of petroleum inclusions in the deep reservoir in Minfeng area in North Dongying depression

下载: 全尺寸图片幻灯片

表 1 用于石油包裹体热动力学计算的最初流体组分

Table 1. The untuned crude oil composition using for petroleum inclusions thermodynamics

No.	F1	F2	F3	F4	F5	F6	F7	F8	F9	F10
N₂	0.24	0.29	0.25	0.53	0.00	0.00	0.41	0.32	0.74	1.67
CO₂	0.39	0.46	2.19	0.12	2.13	0.77	0.44	2.80	2.01	2.18
H₂S	0.00	0.49	1.16	0.00	0.00	0.00	0.00	1.49	0.00	0.00
C₁	5.82	10.75	16.33	22.80	31.28	36.20	40.48	45.29	51.30	60.51
C₂	0.84	1.11	6.29	6.45	7.51	9.74	7.74	9.11	10.67	7.52
C₃	0.43	1.58	7.48	8.51	6.93	6.75	8.20	5.50	7.12	4.74
C₄	1.14	3.68	6.09	6.60	6.26	4.96	5.45	4.13	3.61	4.12
C₅	3.01	4.03	4.36	4.71	4.74	3.89	3.64	3.06	2.20	2.97
C₆	4.92	4.75	3.58	4.24	4.37	3.29	2.83	2.38	1.83	0.00
C₇₊	83.20	72.86	52.27	46.04	36.78	34.40	31.42	25.92	20.52	16.29
GR.C₇₊	942.00	861.00	880.00	864.00	851.05	849.18	845.00	838.06	805.00	789.00
MW.C₇₊	304.00	261.00	249.00	242.00	232.88	216.89	210.00	215.89	192.35	181.00
注：F1据Elsharkawy(2003)；F2和F4据Wu and Rosenegger(1999)；F3据Moharam and Fahim(1995)；F5、F6和F8据Jaubert et al.(2002)；F7据Pedersen et al.(1988)；F9据Neau et al.(1993)；F10据Jacopy and Berry(1958).GR.C₇₊为C₇₊组分比重；MW.C₇₊为C₇₊组分分子量(kg/mol).

下载: 导出CSV

表 2 用于石油包裹体热动力学计算的调整后的流体组分

Table 2. The tuned crude oil composition using for petroleum inclusions thermodynamics

No.	F1	F2	F3	F4	F5	F6	F7	F8	F9	F10
N₂	0.23	0.29	0.25	0.53	0.00	0.00	0.41	0.32	0.74	1.66
CO₂	0.37	0.46	2.21	0.12	2.12	0.77	0.44	2.83	2.02	2.17
H₂S	0.00	0.49	1.17	0.00	0.00	0.00	0.00	1.51	0.00	0.00
C₁	5.55	10.74	16.46	22.76	31.14	35.84	40.33	45.80	51.53	60.13
C₂	0.80	1.11	6.34	6.44	7.48	9.64	7.71	9.21	10.72	7.47
C₃	0.41	1.58	7.54	8.49	6.90	6.68	8.17	5.56	7.15	4.71
C₄	1.09	3.68	6.14	6.59	6.23	4.91	5.43	4.18	3.63	4.09
C₅	2.87	4.03	4.40	4.70	4.72	3.86	3.63	3.09	2.21	2.95
C₆	4.69	4.75	3.61	4.23	4.35	3.26	2.82	2.41	1.84	0.00
C₇₊	83.99	72.89	51.89	46.14	37.06	35.05	31.07	25.08	20.16	16.81
GR.C₇₊	898.06	860.15	887.08	862.36	847.33	840.70	846.96	847.55	808.64	784.09
MW.C₇₊	287.12	260.65	252.86	241.01	230.14	210.71	211.57	225.64	196.66	174.30

下载: 导出CSV

表 3 表 1中流体匹配饱和压力后的组分变化

Table 3. The composition change of petroleum fluids in table 1 after match of the saturation pressure

	F1	F2	F3	F4	F5	F6	F7	F8	F9	F10	AAD%
	AD%										AAD%
N₂	4.17	-	0.00	-	-	-	-	-	-	0.60	1.59
CO₂	5.13	-	0.91	-	0.47	-	-	1.07	0.50	0.46	1.42
H₂S	-	-	0.86	-	-	-	-	1.34	-	-	-
C₁	4.64	0.09	0.80	0.18	0.45	0.99	0.37	1.13	0.45	0.63	0.97
C₂	4.76	0.00	0.79	0.16	0.40	1.03	0.39	1.10	0.47	0.66	0.98
C₃	4.65	0.00	0.80	0.24	0.43	1.04	0.37	1.09	0.42	0.63	0.97
C₄	4.39	0.00	0.82	0.15	0.48	1.01	0.37	1.21	0.55	0.73	0.97
C₅	4.65	0.00	0.92	0.21	0.42	0.77	0.27	0.98	0.45	0.67	0.94
C₆	4.67	0.00	0.84	0.24	0.46	0.91	0.35	1.26	0.55	-	1.03
C₇₊	0.95	0.04	0.73	0.22	0.76	1.89	1.11	3.24	1.75	3.19	1.39
GR.C₇₊	4.66	0.10	0.80	0.19	0.44	1.00	0.23	1.13	0.45	0.62	0.96
MW.C₇₊	5.55	0.13	1.55	0.41	1.18	2.85	0.75	4.52	2.24	3.70	2.29
注：$ AD = \left\| {\frac{{{x^{{\rm{tun}}}} - {x^{{\rm{exp}}}}}}{{{x^{\exp }}}}} \right\|;AAD = \frac{1}{N}\sum\limits_{i = 1}^N {\left\| {\frac{{{x^{{\rm{tun}}}} - {x^{{\rm{exp}}}}}}{{{x^{\exp }}}}} \right\|} $，其中x^exp和x^tun分为调整前和调整后的组分或者分子量和密度，N为个数.

下载: 导出CSV

表 4 根据表 2中调整后组分计算的石油包裹体不同均一温度对应室温下(20 ℃)气泡充填度值(F_v)

Table 4. The degree of gaseous filling (F_v) under room temperature (20 ℃) calculated according to the tuned fluid composition shown in table 2 under different homogenization temperatures of petroleum inclusion

No.	F1	F2	F3	F4	F5	F6	F7	F8	F9	F10
Th_oil(℃)	F_v (20 ℃) (%)
20	0.00	0.00	0.00	0.00	0.00	0.00	0.00	0.00	0.00	0.00
30	0.21	0.38	0.58	0.68	0.96	1.20	1.42	1.93	3.15	6.05
40	0.63	0.85	1.21	1.45	1.98	2.40	2.80	3.75	5.96	10.39
50	0.97	1.25	1.84	2.23	2.95	3.61	4.22	5.47	8.47	13.97
60	1.29	1.77	2.49	3.03	4.02	4.85	5.65	7.09	10.82	16.95
70	1.79	2.30	3.16	3.78	5.03	6.06	7.01	8.66	12.97	19.71
80	2.13	2.71	3.84	4.64	6.13	7.37	8.43	10.20	14.97	22.19
90	2.49	3.27	4.65	5.51	7.18	8.64	9.83	11.67	16.91	24.61
100	3.24	3.85	5.37	6.42	8.33	9.93	11.22	13.08	18.74	26.95
110	3.43	4.44	6.11	7.26	9.43	11.26	12.60	14.48	20.56	29.01
120	3.82	5.05	6.87	8.24	10.63	12.54	14.01	15.82	22.35	31.13
130	4.43	5.68	7.78	9.14	11.78	13.93	15.41	17.18	24.04	33.39
140	4.85	6.36	8.58	10.15	12.94	15.27	16.84	18.57	25.76	35.67
150	5.35	7.03	9.40	11.19	14.22	16.64	18.26	19.95	27.50	37.89
160	5.81	7.72	10.37	12.17	15.45	18.06	19.70	21.27	29.25	40.11
170	6.52	8.43	11.23	13.27	16.69	19.48	21.12	22.66	30.98	42.33
180	7.05	9.16	12.25	14.40	17.96	20.94	22.56	24.05	32.71	44.55
190	7.56	9.91	13.15	15.45	19.25	22.34	23.98	25.41	34.44	46.77
200	8.35	10.68	14.22	16.64	20.56	23.85	25.42	26.78	36.17	48.99

下载: 导出CSV

表 5 东营凹陷北带深层油包裹体均一温度(Th_oil)与室温下(20 ℃)气泡充填度(F_v)数据

Table 5. The data of homogenization temperature (Th_oil) and the degree of gaseous filling (F_v) under room temperature (20 ℃) of petroleum inclusions in the deep reservoir in North Dongying depression

包裹体编号	井号	深度(m)	产状	成因	荧光颜色	API°	Th_oil	F_v(%)	Th_aqu	幕次	包裹体类型
1	丰8	3 943.0	方解石脉	原生	淡黄-白色	33.8	47.5	3.1	134.3	第一幕	油
2	丰8	3 943.0	方解石脉	原生	淡黄-白色	36.1	76.0	6.2	145.9	第一幕	油
3	丰8	4 195.1	石英加大边	原生	淡黄-白色	37.3	102.5	10.5	156.7	第一幕	油
4	丰深1	4 321.7	穿石英颗粒裂纹	次生	淡黄色	38.7	128.6	16.9	151.6	第一幕	油
5	丰深1	4 321.7	穿石英颗粒裂纹	次生	蓝白色	42.4	139.3	25.6	156.7	第一幕	油
6	丰深1	4 321.7	穿石英颗粒裂纹	次生	蓝色	49.0	150.3	72.5	178.7	第二幕	凝析油
7	丰深1	4 321.7	穿石英颗粒裂纹	次生	不发荧光				161.0~176.0	第三幕	天然气

下载: 导出CSV

参考文献(47)

Ahmed, T.H., Cady, G.V., Story, A.L., 1985. A generalized correlation for characterizing the hydrocarbon heavy fractions. In: SPE 60th annual technical conference. SPE, Las Vegas, 14266. doi: 10.2118/14266-MS
Al-Meshari, A.A., Aramco, S., MaCain, W.D., 2007. Validation of splitting the hydrocarbon plus fraction: first step in tuning equation of state. In: Middle east oil and gas show and conference. SPE, Kingdom of Bahrain, 104631. doi: 10.2118/104631-MS
Aplin, A.C., Macleod, G., Larter, S.R., et al., 1999. Combined use of confocal laser scanning microscopy and PVT simulation for estimating the composition and physical properties of petroleum in fluid inclusions. Marine and Petroleum Geology, 16(2): 97-110. doi: 10.1016/S0264-8172(98)00079-8
Bourdet, J., Pironon, J., Levresse, G., et al., 2008. Petroleum type determination through homogenization temperature and vapour volume fraction measurements in fluid inclusions. Geofluids, 8(1): 46-59. doi: 10.1111/j.1468-8123.2007.00204.x
Bourdet, J., Pironon, J., Levresse, G., et al., 2010. Petroleum accumulation and leakage in a deeply buried carbonate reservoir, Níspero field (Mexico). Marine and Petroleum Geology, 27(1): 126-142. doi: 10.1016/j.marpetgeo.2009.07.003
Cavett, R., 1962. Physical data for distillation calculations: vapor-liquid equilibria. In: Proc. 27th Annual Meeting. American Petroleum Institute, Dallas, 351-366.
Elsharkawy, A.M., 2003. An empirical model for estimating the saturation pressures of crude oils. Journal of Petroleum Science and Engineering, 38(1): 57-77. doi: 10.1016/S0920-4105(03)00035-4
George, S.C., Krieger, F.W., Eadington, P.J., et al., 1997. Geochemical comparison of oil-bearing fluid inclusions and produced oil from the Toro sandstone, Papua New Guinea. Organic Geochemistry, 26(3): 155-173. doi: 10.1016/S0146-6380(97)00004-1
Grimmer, J.O.W., Pironon, J., Teinturier, S., et al., 2003. Recognition and differentiation of gas condensates and other oil types using microthermometry of petroleum inclusions. Journal of Geochemical Exploration, 78-79: 367-371. doi: 10.1016/S0375-6742(03)00137-7
Guilhaumou, N., Szydlowskii, N., Pradier, B., 1990. Characterization of hydrocarbon fluid inclusions by infra-red and fluorescence microspectrometry. Mineralogical Magazine, 54(375): 311-324. doi: 10.1180/minmag.1990.054.375.17
Horsfield, B., McLimans, R.K., 1984. Geothermometry and geochemistry of aqueous and oil-bearing fluid inclusions from Fateh field, Dubai. Organic Geochemistry, 6: 733-740. doi: 10.1016/0146-6380(84)90094-9
Jacopy, R.H., Berry, Jr. V.J., 1958. A method for predicting pressure maintenance for reservoirs producing volatile oil. Petrol. Trans. AIME, 213: 59-65. doi: 10.2118/921-G
Jaubert, J.N., Avaullee, L., Souvay, J.F., 2002. A crude oil data bank containing more than 5 000 PVT and gas injection data. Journal of Petroleum Science and Engineering, 34(1-4): 65-107. doi: 10.1016/S0920-4105(02)00153-5
Jhaveri, B.S., Youngren, G.K., 1988. Three-parameter modification of the Peng-Robinson equation of state to improve volumetric predictions. SPE Reservoir Engineering, 3(3): 1033-1040. doi: 10.2118/13118-PA
Katz, D.L., Firoozabadi, A., 1978. Predicting phase behavior of condensate/crude-oil systems using methane interaction coefficients. Journal of Petroleum Technology, 30(11): 1649-1655. doi: 10.2118/6721-PA
Kay, W.B., 1936. Gases and vapors at high temperature and pressure-density of hydrocarbon. Ind. Eng. Chem. Res. , 28(8): 1014-1019. doi: 10.1021/ie50321a008
Kihle, J., 1995. Adaptation of fluorescence excitation-emission micro-spectroscopy for characterization of single hydrocarbon fluid inclusions. Organic Geochemistry, 23(11-12): 1029-1042. doi: 10.1016/0146-6380(95)00091-7
Liu, D.H., Xiao, X.M., Mi, J.K., et al., 2003. Determination of trapping pressure and temperature of petroleum inclusions using PVT simulation software: a case study of Lower Ordovician carbonates from the Lunnan low uplift, Tarim basin. Marine and Petroleum Geology, 20(1): 29-43. doi: 10.1016/S0264-8172(03)00047-3
Moharam, H.M., Fahim, M.A., 1995. Prediction of viscosity of heavy petroleum fractions and crude oils using a corresponding states method. Ind. Eng. Chem. Res. , 34(11): 4140-4144. doi: 10.1021/ie00038a061
Munz, I., Johansen, H., Johanse, I., 1999. Characterisation of composition and PVT properties of petroleum inclusions: implications of reservoir filling and compartmentalisation. Society of Petroleum Engineers, 56519: 1-7. doi: 10.2118/56519-MS
Neau, E., Jaubert, J.N., Rogalski, M., 1993. Characterization of heavy oils. Industrial & Engineering Chemistry Research, 32(6): 1196-1203. doi: 10.1021/ie00018a027
Pang, L.S.K., George, S.C., Quezada, R.A., 1998. A study of the gross compositions of oil-bearing fluid inclusions using high performance liquid chromatography. Organic Geochemistry, 29(5-7): 1149-1161. doi: 10.1016/S0146-6380(98)00135-1
Pedersen, K.S., Thomassen, P., Fredenslund, A., 1988. On the dangers of "tuning" equation of sate parameters. Chem. Eng. Sci. , 43(2): 269-278. doi: 10.1016/0009-2509(88)85039-5
Peng, D.R., Robinson, D.B., 1976. A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals, 15(1): 59-64. doi: 10.1021/i160057a011
Ping, H.W., Chen, H.H., 2011. Main controlling factors on oil inclusion homogenization temperatures and their geological significance. Earth Science—Journal of China University of Geosciences, 36(1): 131-138 (in Chinese with English abstract).
Ping, H.W., Chen, H.H., Song, G.Q., et al., 2012. Contributions degree of petroleum charging to oil and gas accumulation and its significance. Earth Science—Journal of China University of Geosciences, 37(1): 163-170 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DQKX201201020.htm
Ping, H.W., Thiéry, R., Chen, H.H., 2011. Thermodynamic modeling of petroleum inclusions: the prediction of the saturation pressure of crude oils. Geofluids, 11(3): 328-340. doi: 10.1111/j.1468-8123.2011.00343.x
Pironon, J., Barres, O., 1990a. FT-IR microanalysis of hydrocarbon fluid inclusions. Chemical Geology, 84(1-4): 224-226. doi: 10.1016/0009-2541(90)90220-2
Pironon, J., Barres, O., 1990b. Semi-quantitative FT-IR microanalysis limits: evidence from synthetic hydrocarbon fluid inclusions in sylvite. Geochimica et Cosmochimica Acta, 54(3): 509-518. doi: 10.1016/0016-7037(90)90348-O
Pironon, J., Canals, M., Dubessy, J., et al., 1998. Volumetric reconstruction of individual oil inclusions by confocal scanning laser microscopy. Eur. J. Mineral. , 10(6): 1143-1150. doi: 10.1127/ejm/10/6/1143
Przyjalgowski, M.A., Ryder, A.G., Feely, M., et al., 2005. Analysis of hydrocarbon-bearing fluid inclusions(HCFI) using time-resolved fluorescence spectroscopy. In: Proceedings of SPIE. International Society Optical Engineering, 5826: 173-184.
Rao, D., Qin, J.Z., Zhang, Z.R., et al., 2010. Composition analyses of individual hydrocarbon inclusion. Petroleum Geology & Experiment, 32(1): 67-70 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SYSD201001014.htm
Riazi, M.R., Al-Sahhaf, T.A., 1996. Physical properties of heavy petroleum fractions and crude oils. Fluid Phase Equilibria, 117(1): 217-224. doi: 10.1016/0378-3812(95)02956-7
Stasiuk, L.D., Snowdon, L.R., 1997. Fluorescence micro-spectrometry of synthetic and natural hydrocarbon fluid inclusions: crude oil chemistry, density and application to petroleum migration. Applied Geochemistry, 12(3): 229-241. doi: 10.1016/S0883-2927(96)00047-9
Thiéry, R., Pironon, J., Walgenwitz, F., et al., 2000. PIT (petroleum inclusion thermodynamic): a new modeling tool for the characterization of hydrocarbon fluid inclusions from volumetric and microthermometric measurements. Journal of Geochemical Exploration, 69-70: 701-704. doi: 10.1016/S0375-6742(00)00085-6
Thiéry, R., Pironon, J., Walgenwitz, F., et al., 2002. Individual characterization of petroleum fluid inclusions (composition and P-T trapping conditions) by microthermometry and confocal laser scanning microscopy: inferences from applied thermodynamics of oils. Marine and Petroleum Geology, 19(7): 847-859. doi: 10.1016/S0264-8172(02)00110-1
Thomassen, P., Pedersen, K.S., Fredenslund, A., 1987. Adjustment of C₇₊ molecular weights in the characterization of petroleum mixtures containing heavy hydrocarbons. SPE, 16036-MS. http://www.onepetro.org/general/SPE-16036-MS
Tseng, H.Y., Pottorf, R.J., 2002. Fluid inclusion constraints on petroleum PVT and compositional history of the greater Alwyn-South Brent petroleum system, northern North Sea. Marine and Petroleum Geology, 19(7): 797-809. doi: 10.1016/S0264-8172(02)00088-0
Volk, H., Fuentes, D., Fuerbach, A., et al., 2010. First on-line analysis of petroleum from single inclusion using ultrafast laser ablation. Organic Geochemistry, 41(2): 74-77. doi: 10.1016/j.orggeochem.2009.05.006
Whitson, C.H., 1984. Effect of C₇₊ properties on equation-of-state predictions. Soc. Pet. Eng. J. , 24(6): 685-696. doi: 10.2118/11200-PA
Wu, R., Rosenegger, L., 1999. Intergrated oil PVT data characterization-lessons from four case histories. J. Can. Petrol. Technol. , 38(Specl. 13): 97-105. http://www.researchgate.net/publication/240780849_Integrated_Oil_PVT_Characterization_-_Lessons_From_Four_Case_Histories
Zhang, Z.R., Zhang, Q., Xi, B.B., et al., 2011. On-line analysis of oil-bearing fluid inclusions with laser ablation GC-MS. Petroleum Geology & Experiment, 33(4): 437-440(in Chinese with English abstract).
Zurita, R.A.A., McCain, Jr. W.D., 2002. An efficient tuning strategy to calibrate cubic EOS for compositional simulation, SPE annual technical conference and exhibition. SPE, San Antonio, Texas, 77382. doi: 10.2118/77382-MS
平宏伟, 陈红汉, 2011. 影响油包裹体均一温度的主要控制因素及其地质涵义. 地球科学——中国地质大学学报, 36(1): 131-138. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201101015.htm
平宏伟, 陈红汉, 宋国奇, 等, 2012. 油气充注成藏贡献度及其意义. 地球科学——中国地质大学学报, 37(1): 163-170. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201201020.htm
饶丹, 秦建中, 张志荣, 等, 2010. 单体烃包裹体成分分析. 石油实验地质, 32(1): 67-70. doi: 10.3969/j.issn.1001-6112.2010.01.013
张志荣, 张渠, 席斌斌, 等, 2011. 含油包裹体在线激光剥蚀色谱-质谱分析. 石油实验地质, 33(4): 437-440. doi: 10.3969/j.issn.1001-6112.2011.04.020