Zircon U-Pb Age of Mafic-Ultramafic Rock from Pingchuan Region in Southern Sichuan and Its Geological Implications
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摘要: 为探讨镁铁质-超镁铁质岩的岩石学特征及成岩成矿作用时间序列, 完善区域成岩成矿年代学格架, 对平川地区的镁铁质-超镁铁质岩进行了元素地球化学分析和LA-ICP-MS锆石U-Pb定年.测试结果显示, 黄草坪辉长岩成岩年龄为259.7±1.2 Ma, 其捕获锆石结晶年龄为269.8±2.4 Ma, 辉绿(玢)岩等次火山岩参考成岩年龄为248± Ma, 其变质锆石年龄为67± Ma.研究结果表明, 平川地区的镁铁质-超镁铁质岩产出于大陆裂谷环境, 岩浆源区来自上地幔尖晶石相二辉橄榄岩, 为一套同源异相有利于铁矿化形成的富钠质拉斑玄武质岩石系列.岩浆活动开始孕育时间不晚于269.8±2.4 Ma, 大规模岩浆活动发生于259.7±1.2 Ma, 其约束了岩浆分异型和火山喷发(溢)沉积型矿化的成矿时间, 次火山岩的成岩年龄约束了次火山热液型矿化的成矿时间上限, 变质锆石U-Pb年龄记录了平川地区经历了喜马拉雅期陆内造山作用.平川地区构造岩浆活动具有爆发性、阶段性和成矿专属性等特点, 镁铁质-超镁铁质岩的形成可能与岩石圈的大规模减薄作用有关, 攀西地区海西-印支期的成岩-成矿作用为同源岩浆受区域统一深部地球动力学背景约束演化的异相产物.Abstract: LA-ICP-MS zircon U-Pb dating and elements geochemical analysis has been carried out for mafic-ultramafic rock from Pingchuan to discuss the petrology characteristics and the time series of diagenesis-mineralization in Pingchuan region and further improve the geochronological framework of diagenesis-mineralization of the Panxi area. The test results show that Huangcaoping gabbro formed in 259.7±1.2 Ma and its capture zircon's crystallization age is 269.8±2.4 Ma, and the subvolcanic's reference diagenetic age is 248± Ma and its metamorphic zircon age is 67± Ma. The results indicate that mafic-ultramafic rock in Pingchuan region is a set of homologous phase sodium-rich tholeiitic rock series, conduciving to the formation of iron-mineralization, outputting in the continental rift environment, magma source coming from the upper mantle spinel lherzolite. The magmatic activity started no later than 269.8±2.4 Ma, and the large-scale magmatic activity occurred at 259.7±1.2 Ma, which constrained the mineralization time of magmatic profiled and volcanic eruptions (underflow) sedimentary, and the subvolcanic diagenetic age limited the upper mineralization time of sub-volcanic hydrothermal, and the metamorphic zircon U-Pb age recorded that Pingchuan region experienced Himalayan intracontinental orogeny. The tectonic-magmatic activity of Pingchuan region is featured with being explosive, phased and metallogenic; the formation of mafic-ultramafic rock in Pingchuan region is probably related to the large-scaled lithospheric thinning; diagenesis-mineralization in Hercynian-Indosinian in Panxi area is the comagmatic product of different phases evolution, controlled by regional uniform deep geodynamics.
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Key words:
- zircon /
- mafic-ultramafic rock /
- diagenesis-mineralization /
- pingchuan region /
- geochemistry
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图 10 (Tb/Yb)PM和(Yb/Sm)PM图解(底图据张招崇等, 2006)
Fig. 10. Relation of (Tb/Yb)PM and (Yb/Sm)PM
图 11 (Th/Ta)PM和(La/Nb)PM图解(底图据Neal et al., 2002)
Fig. 11. Relation of (Th/Ta)PM and (La/Nb)PM
表 1 平川地区镁铁质-超镁铁质岩常量元素含量及特征值
Table 1. Table of eigenvalue and content of major elements of mafic-ultramafic rock in Pingchuan region
样号 岩石类型 化学成分(%) 特征值 SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2O P2O5 FeO′ ZK21101-2 细粒玄武岩 51.57 2.19 14.47 3.30 7.21 0.20 6.94 10.90 2.15 0.84 0.24 10.18 ZK21201-9 块状玄武岩 50.31 1.97 14.03 2.87 8.30 0.19 8.63 9.71 3.02 0.73 0.24 10.88 ZK21503-1 含杏仁体玄武岩 53.56 1.77 14.62 3.10 7.21 0.18 6.70 8.79 2.68 1.17 0.21 10.00 ZK22001-1 灰绿色玄武岩 50.14 2.30 14.28 5.81 5.98 0.21 6.26 11.83 1.90 1.04 0.25 11.21 ZK22001-3 杏仁体玄武岩 53.96 2.06 14.52 2.09 7.19 0.18 5.65 9.94 4.10 0.06 0.24 9.07 ZK22101-2 含杏仁体玄武岩 52.32 2.15 14.88 3.34 7.22 0.18 6.88 8.42 4.29 0.07 0.26 10.22 ZK22101-10 块状玄武岩 50.74 2.21 14.61 3.64 7.76 0.25 7.52 8.34 3.12 1.58 0.24 11.03 ZK22101-14 铁质凝灰岩 44.79 1.15 11.75 11.81 7.95 0.36 8.50 11.31 1.88 0.07 0.42 18.58 LZC-3 斑状玄武岩 49.62 1.99 13.97 5.01 7.05 0.21 7.57 11.76 2.03 0.52 0.26 11.56 CK10201-1 粗粒辉长岩 51.44 2.93 14.91 5.53 5.27 0.14 4.93 9.07 5.01 0.58 0.18 10.25 CK10201-4 细粒辉长岩 50.41 1.95 14.75 2.56 8.25 0.19 6.85 9.57 4.73 0.54 0.20 10.56 CK10201-6 中粗粒辉长岩 50.46 1.70 15.59 3.85 5.68 0.22 7.87 9.69 3.89 0.91 0.15 9.15 CK10201-7 中-细粒矿化辉长岩 47.19 1.52 14.56 3.00 11.23 0.13 7.35 11.28 3.15 0.46 0.14 13.93 CK10201-8 中-细粒辉长岩 49.94 1.59 15.36 3.94 5.63 0.13 7.77 11.53 3.39 0.58 0.14 9.17 DPZ-1 中-粗粒辉长岩 49.90 0.95 15.84 2.50 7.00 0.19 9.06 10.30 2.92 1.25 0.09 9.24 DPZ-3 粗粒辉长岩 49.93 1.98 12.95 5.81 7.23 0.22 7.15 10.29 3.81 0.36 0.28 12.46 DPZ-71-2 辉绿辉长岩 49.07 2.73 15.53 2.92 10.19 0.20 5.92 8.49 3.86 0.86 0.24 12.81 DPZ-74 中细粒辉长岩 50.55 1.72 12.85 4.36 5.26 0.16 9.14 11.12 4.38 0.30 0.16 9.19 ZK3002-5-1 细粒辉长岩 52.48 0.89 16.31 3.12 5.99 0.17 6.68 11.30 2.63 0.36 0.07 8.79 ZK3002-14 中-粗粒矿化辉长岩 46.07 2.71 13.05 9.24 9.34 0.19 5.97 10.13 2.69 0.55 0.05 17.65 ZK3002-18 矿化粗粒辉长岩 44.55 2.26 13.00 2.73 18.10 0.19 5.50 10.01 2.92 0.68 0.07 20.56 ZK3002-19 中粗粒辉长岩 52.08 1.03 15.11 3.89 4.97 0.18 6.69 11.85 3.25 0.88 0.07 8.47 ZK3002-20 矿化细粒辉长岩 43.43 2.57 13.36 9.63 10.81 0.20 6.90 10.50 2.15 0.40 0.05 19.48 K-8 辉绿岩 44.74 1.39 8.73 2.70 9.35 0.30 24.25 7.92 0.41 0.09 0.12 11.78 K-10 辉绿岩 46.42 0.01 9.08 1.58 12.06 0.17 23.44 7.01 0.01 0.12 0.10 13.48 K-14 辉绿岩 44.14 1.09 8.21 3.92 7.91 0.20 25.41 8.77 0.20 0.04 0.10 11.44 K-41 辉绿岩 44.88 1.20 9.05 3.01 8.43 0.17 23.78 8.56 0.52 0.30 0.10 11.14 K-244 辉绿岩 45.78 1.22 8.84 3.68 9.47 0.26 22.57 7.73 0.31 0.03 0.10 12.78 K-13 苦橄岩 44.93 1.22 9.41 3.84 7.61 0.20 22.20 9.07 1.12 0.31 0.09 11.06 K-15 苦橄岩 45.20 1.23 9.65 3.66 7.69 0.19 21.66 9.11 1.23 0.27 0.09 10.99 K-18 苦橄岩 44.19 1.04 8.27 2.92 8.78 0.20 25.22 7.88 1.19 0.22 0.09 11.41 K-246-2 苦橄岩 45.31 1.16 8.55 2.65 9.21 0.19 23.17 8.20 1.32 0.14 0.09 11.59 K-246-3 苦橄岩 46.05 1.13 8.86 3.04 9.09 0.20 21.65 8.32 1.31 0.21 0.12 11.83 K-171 苦橄岩 45.37 1.20 8.36 4.30 7.75 0.19 23.80 7.82 0.88 0.23 0.10 11.62 注:氧化物含量已换算成100%,分析数据由澳实分析检测(广州)有限公司测定. 表 2 平川地区镁铁质-超镁铁质岩微量元素含量及特征值
Table 2. Eigenvalues and contents of Trace elements of mafic-ultramafic rock in Pingchuan region
样号 岩石名称 元素(10-6) 特征值 Rb Ba Th U Ta Nb La Ce Pb Pr Sr Nd Zr Hf Sm Eu Dy Y Ho Yb Lu Gd Tb Er Tm ∑REE LREE/HREE δEu δCe ZK21101-2 细粒玄武岩 20.1 1140 2.2 0.5 1.06 17.4 18.2 37.7 4.5 5.15 503 22.7 136.0 3.7 5.40 1.97 4.90 23.9 0.91 2.14 0.32 5.45 0.89 2.52 0.35 108.60 5.21 1.10 0.94 ZK21201-9 块状玄武岩 23.3 660 2.4 0.6 1.26 20.9 21.0 44.5 3.3 5.42 487 22.6 142.5 3.8 5.33 1.72 4.88 27.3 1.02 2.30 0.31 5.95 0.95 2.78 0.39 119.15 5.41 0.93 1.00 ZK21503-1 含杏仁体玄武岩 43.1 280 2.0 0.5 0.98 15.0 21.8 43.5 5.7 5.57 397 22.9 123.0 3.4 5.09 1.73 4.27 21.6 0.78 1.81 0.26 5.33 0.76 2.21 0.29 116.30 6.40 1.01 0.94 ZK22001-1 灰绿色玄武岩 32.9 450 2.3 0.6 1.23 17.9 21.8 47.7 7.6 6.17 718 26.7 91.5 3.2 6.18 2.11 4.97 24.6 0.94 2.13 0.33 6.00 0.96 2.54 0.37 128.90 6.07 1.05 0.99 ZK22001-3 杏仁体玄武岩 2.8 110 1.9 0.5 1.11 17.3 18.8 42.1 5.0 5.74 426 25.5 115.5 3.3 5.88 2.24 4.83 23.4 0.93 2.19 0.31 5.84 0.92 2.51 0.35 118.14 5.61 1.16 0.98 ZK22101-2 含杏仁体玄武岩 2.2 90 2.5 0.7 1.18 18.5 24.3 50.5 4.9 6.21 376 26.0 177.5 4.7 6.00 2.05 4.93 26.4 1.04 2.21 0.30 6.21 1.02 2.67 0.36 133.80 6.14 1.02 0.98 ZK22101-10 块状玄武岩 44.6 1310 2.5 0.6 1.12 17.8 24.4 48.6 10.8 5.54 335 24.0 159.0 4.2 5.25 2.00 4.33 23.0 0.84 1.82 0.26 5.32 0.83 2.33 0.29 125.81 6.85 1.15 0.98 ZK22101-14 铁质凝灰岩 3.8 10000 3.9 4.2 0.63 11.4 51.1 72.6 160.5 6.40 807 22.9 100.5 2.7 4.46 4.46 4.19 25.0 0.87 2.22 0.34 4.84 0.77 2.54 0.35 178.04 10.04 2.92 0.84 LZC-3 斑状玄武岩 11.8 190 1.3 0.3 0.84 12.9 13.8 30.4 3.8 4.59 355 21.1 87.3 2.7 5.31 1.89 5.23 25.7 0.97 2.30 0.32 5.72 0.94 2.69 0.38 95.64 4.16 1.04 0.93 CK10201-1 中粗粒辉长岩 15.2 540 3.1 0.3 1.53 22.9 15.2 33.1 2.3 3.98 450 19.8 51.5 2.0 4.81 1.85 5.10 29.5 1.06 2.61 0.41 5.32 0.91 3.08 0.43 97.66 4.16 1.11 1.02 CK10201-4 细粒辉长岩 14.5 360 3.1 0.5 1.22 19.0 20.4 46.1 14.4 5.23 398 21.0 113.5 3.4 4.99 1.49 4.75 25.6 0.88 2.26 0.33 5.42 0.86 2.54 0.36 116.61 5.70 0.87 1.07 CK10201-6 中粗粒辉长岩 17.8 470 1.4 0.3 0.70 11.0 13.2 26.2 1.1 3.44 362 15.5 57.1 2.0 3.92 1.28 4.21 21.0 0.83 2.11 0.31 4.30 0.72 2.35 0.35 78.72 4.19 0.95 0.93 CK10201-7 中-细粒矿化辉长岩 11.5 210 1.8 0.3 0.62 9.9 10.5 25.8 4.8 3.11 429 13.7 60.6 1.9 3.79 1.18 3.60 21.0 0.73 1.81 0.26 3.98 0.67 2.03 0.28 71.44 4.35 0.92 1.09 DPZ-1 中-粗粒辉长岩 29.3 420 1.4 0.2 0.39 6.4 7.1 17.3 4.5 2.08 260 9.0 27.4 0.9 2.43 0.99 3.04 17.2 0.62 1.65 0.22 2.98 0.52 1.72 0.27 49.92 3.53 1.12 1.09 DPZ-71-2 辉绿辉长岩 22.2 280 1.8 0.4 1.07 16.6 16.1 37.2 2.1 5.54 542 25.6 120.0 3.4 6.61 2.47 6.63 31.8 1.26 2.96 0.43 7.22 1.18 3.49 0.49 117.18 3.95 1.09 0.96 DPZ-74 中细粒辉长岩 10.6 320 2.7 0.3 1.02 15.1 15.6 34.5 3.2 4.77 223 19.8 75.4 2.5 4.70 1.40 4.45 22.6 0.86 2.24 0.32 5.13 0.79 2.56 0.35 97.47 4.84 0.87 0.97 ZK3002-4 中-细粒辉长岩 13.7 180 1.7 0.3 0.30 4.8 8.1 17.2 2.7 1.99 253 8.7 48.6 1.6 2.60 0.85 3.49 20.6 0.72 1.86 0.28 3.17 0.59 2.06 0.30 51.91 3.16 0.90 1.02 ZK3002-5 细粒辉长岩 9.4 170 1.5 0.3 0.24 3.8 6.4 13.5 4.1 1.68 276 7.4 47.9 1.4 2.10 0.85 2.82 16.6 0.58 1.52 0.22 2.50 0.45 1.73 0.25 42.00 3.17 1.13 0.99 ZK3002-18 矿化粗粒辉长岩 23.1 190 1.6 0.3 0.32 5.0 7.8 17.9 4.5 2.09 261 9.3 39.6 1.4 2.69 1.01 3.67 21.2 0.73 1.98 0.28 3.21 0.62 2.15 0.33 53.76 3.14 1.05 1.07 ZK3002-20 矿化细粒辉长岩 11.1 140 1.3 0.2 0.25 4.1 6.2 13.4 5.3 1.59 205 7.3 46.3 1.5 2.10 0.72 2.95 16.6 0.58 1.62 0.23 2.54 0.47 1.72 0.26 41.68 3.02 0.95 1.02 ZK21301-1 辉绿岩 13.3 420 2.1 0.5 1.04 17.1 18.0 38.6 7.5 5.28 429 23.3 111.0 3.1 5.51 1.99 5.10 23.6 0.96 2.23 0.32 5.70 0.94 2.61 0.37 110.91 5.08 1.08 0.96 K-8 辉绿岩 2.9 30 0.6 0.2 0.46 7.0 6.1 15.5 1.9 1.94 106.5 8.5 69.1 2.0 2.42 0.95 2.95 16.7 0.57 1.49 0.19 2.91 0.54 1.64 0.24 45.94 3.36 1.09 1.10 K-14 辉绿岩 3.0 60 0.6 0.2 0.42 6.5 6.2 13.8 0.7 1.80 53.5 8.1 48.5 1.5 2.09 0.81 2.54 13.8 0.55 1.26 0.16 2.60 0.45 1.41 0.21 41.98 3.57 1.06 1.00 K-41 辉绿岩 17.3 20 0.7 0.2 0.49 7.6 6.6 15.3 1.9 1.82 89.1 7.6 50.3 1.6 2.12 0.86 2.61 14.4 0.53 1.24 0.19 2.41 0.49 1.50 0.19 43.46 3.74 1.16 1.06 K-244 辉绿岩 0.8 20 0.6 0.2 0.41 5.9 6.5 13.3 1.5 2.00 38.8 8.9 55.0 1.7 2.43 0.87 2.80 14.8 0.55 1.31 0.18 3.00 0.46 1.60 0.21 44.11 3.36 0.98 0.90 K-13 苦橄岩 10.5 230 0.7 0.2 0.48 7.2 7.5 17.7 9.0 2.02 183 8.7 71.0 1.9 2.37 0.89 2.81 16.1 0.57 1.29 0.19 2.71 0.51 1.48 0.23 48.97 4.00 1.07 1.09 K-15 苦橄岩 8.2 230 0.7 0.2 0.50 7.6 7.7 16.8 3.9 2.18 183 9.7 75.5 2.0 2.61 1.04 3.09 16.8 0.66 1.50 0.20 0.0 0.0 0.0 0.0 40.56 3.65 1.05 1.10 K-18 苦橄岩 5.8 190 0.6 0.2 0.38 5.7 5.7 14.2 2.6 1.72 188 7.4 66.9 1.8 2.05 0.77 2.38 13.7 0.50 1.17 0.17 2.43 0.44 1.43 0.20 47.29 3.68 1.06 0.95 K-246-2 苦橄岩 4.1 70 0.6 0.2 0.41 5.8 7.5 15.3 3.3 2.01 194 9.0 64.2 1.8 2.46 0.92 2.84 14.5 0.56 1.38 0.20 2.86 0.47 1.56 0.23 47.49 3.61 0.97 0.86 K-246-3 苦橄岩 5.1 140 0.6 0.2 0.43 6.2 7.7 14.5 4.4 2.14 257 9.4 62.1 1.9 2.55 0.89 2.90 14.7 0.55 1.32 0.19 3.06 0.48 1.59 0.22 44.29 3.47 1.08 0.88 K-171 苦橄岩 8.8 110 0.5 0.2 0.39 5.7 7.6 13.8 4.1 1.80 170 8.1 61.1 1.7 2.22 0.87 2.84 14.2 0.56 1.35 0.20 2.72 0.47 1.53 0.23 108.60 5.21 1.10 0.94 注:分析数据由澳实分析检测(广州)有限公司测定. 表 3 平川地区镁铁质-超镁铁质岩锆石U-Pb年代学分析结果
Table 3. The analysis results of zircon U-Pb dating of mafic-ultramafic rock in Pingchuan region
分析点 含量(10-6) Th/U U-Th-Pb同位素比值±1σ 同位素年龄±1σ(Ma) U Th 207Pb/206Pb 207Pb/235U 206Pb/238U 208Pb/232Th 206Pb/238U 207Pb/235U 208Pb/232Th DSS 01 764 946 1.24 0.051 4±0.001 5 0.291 3±0.008 6 0.041 0±0.000 4 0.011 3±0.000 2 258.91±2.50 259.55±6.76 227.08±3.46 02 649 1 076 1.66 0.054 2±0.001 7 0.307 8±0.009 3 0.041 1±0.000 4 0.011 1±0.000 2 259.84±2.41 272.44±7.26 222.77±4.09 03 623 856 1.37 0.050 9±0.001 6 0.288 8±0.008 9 0.041 0±0.000 4 0.011 3±0.000 2 259.25±2.45 257.59±7.02 227.56±4.45 04 470 862 1.83 0.053 7±0.001 8 0.305 4±0.010 4 0.041 1±0.000 4 0.011 7±0.000 2 259.58±2.53 270.64±8.09 234.66±4.63 05 563 783 1.39 0.052 1±0.001 7 0.295 1±0.009 5 0.041 0±0.000 4 0.011 5±0.000 2 259.30±2.71 262.58±7.49 230.70±4.29 06 421 525 1.25 0.050 6±0.001 9 0.285 7±0.010 6 0.041 1±0.000 4 0.011 3±0.000 2 259.69±2.77 255.15±8.40 226.73±4.99 07 746 1 300 1.74 0.054 6±0.001 6 0.310 8±0.008 6 0.041 2±0.000 4 0.011 5±0.000 2 260.31±2.35 274.79±6.66 231.97±4.81 08 387 418 1.08 0.051 2±0.001 9 0.291 0±0.010 8 0.041 1±0.000 4 0.011 6±0.000 3 259.90±2.63 259.38±8.46 232.48±5.54 09 340 484 1.43 0.049 4±0.002 2 0.279 9±0.012 5 0.041 1±0.000 4 0.011 4±0.000 3 259.38±2.76 250.60±9.88 229.50±5.60 10 152 119 0.78 0.053 6±0.002 8 0.302 6±0.016 0 0.041 1±0.000 6 0.010 9±0.000 4 259.63±3.93 268.45±9.49 218.88±8.29 11 632 607 0.96 0.050 1±0.001 6 0.283 8±0.008 8 0.041 1±0.000 4 0.011 3±0.000 3 259.84±2.38 253.70±6.99 227.63±5.18 12 523 641 1.23 0.049 9±0.001 7 0.281 1±0.009 1 0.040 9±0.000 4 0.011 5±0.000 2 258.56±2.70 251.56±7.22 230.56±4.80 13 673 1 067 1.59 0.052 8±0.001 6 0.298 1±0.009 0 0.041 0±0.000 5 0.011 5±0.000 2 258.88±2.93 264.89±7.06 230.30±4.89 14 274 291 1.06 0.052 0±0.002 5 0.292 4±0.014 2 0.041 0±0.000 5 0.011 2±0.000 3 258.82±3.35 260.47±8.17 224.68±5.59 15 559 749 1.34 0.048 7±0.001 6 0.278 4±0.009 4 0.041 2±0.000 4 0.011 5±0.000 3 260.55±2.76 249.41±7.50 230.14±5.31 16 389 553 1.42 0.051 4±0.001 7 0.293 2±0.010 3 0.041 1±0.000 4 0.011 4±0.000 3 259.73±2.72 261.07±8.05 229.73±5.06 17 694 1 253 1.81 0.051 0±0.001 6 0.291 2±0.008 8 0.041 2±0.000 4 0.011 7±0.000 2 260.52±2.27 259.47±6.92 235.95±4.30 18 505 795 1.57 0.052 9±0.001 7 0.299 1±0.009 3 0.041 1±0.000 5 0.010 9±0.000 2 259.39±3.27 265.68±7.27 219.70±4.12 19 303 422 1.39 0.047 7±0.002 0 0.272 5±0.011 5 0.041 2±0.000 4 0.012 2±0.000 3 260.10±2.75 244.65±9.15 244.29±5.59 20 502 612 1.22 0.051 9±0.001 8 0.293 4±0.009 6 0.041 2±0.000 5 0.011 3±0.000 2 260.24±3.29 261.21±7.50 226.39±4.69 21 1 189 1 355 1.14 0.050 5±0.001 2 0.300 1±0.007 8 0.042 7±0.000 4 0.011 8±0.000 2 269.82±2.27 266.47±6.06 236.15±4.33 22 254 367 1.44 0.104 0±0.003 6 0.612 5±0.021 2 0.042 7±0.000 5 0.014 6±0.000 3 269.26±3.05 485.11±9.35 293.61±5.54 23 2 869 2 369 0.83 0.051 4±0.001 0 0.305 0±0.006 5 0.042 7±0.000 4 0.011 8±0.000 2 269.73±2.74 270.30±5.03 237.35±4.38 24 2 382 4 269 1.79 0.050 6±0.001 1 0.299 9±0.006 9 0.042 7±0.000 4 0.011 9±0.000 2 269.80±2.63 266.32±5.40 239.70±4.77 25 634 1 049 1.66 0.064 6±0.002 0 0.382 9±0.011 9 0.042 8±0.000 5 0.012 1±0.000 2 270.47±3.06 329.17±8.77 243.22±4.77 KI-8 01 1 329 688 0.52 0.047 3±0.002 2 0.070 3±0.003 1 0.010 8±0.000 1 0.003 6±0.000 1 69.6±0.8 69.0±3.0 72.4±2.1 04 778 466 0.60 0.051 1±0.001 7 0.277 9±0.009 4 0.039 2±0.000 4 0.012 3±0.000 4 248.1±2.8 249.0±7.5 247.2±7.2 05 734 415 0.57 0.051 7±0.002 1 0.279 6±0.011 2 0.039 0±0.000 4 0.013 2±0.000 4 246.6±2.3 250.4±8.9 265.0±8.3 KI-18 01 1 568 1 202 0.77 0.083 1±0.003 2 0.115 3±0.004 4 0.010 0±0.000 1 0.003 6±0.000 1 64.3±0.8 110.8±4.0 73.0±2.2 03 308 664 2.16 0.099 0±0.004 0 0.531 6±0.021 3 0.039 2±0.000 6 0.007 2±0.000 3 248.1±3.8 264.0±7.0 221.0±6.6 04 366 185 0.50 0.058 9±0.001 9 0.632 7±0.019 0 0.078 0±0.000 9 0.022 4±0.000 6 484.0±5.6 497.8±11.8 446.9±12.2 05 203 208 1.02 0.073 1±0.002 7 0.784 2±0.031 2 0.078 1±0.001 1 0.023 6±0.000 8 484.5±6.7 587.9±17.7 471.3±15.4 06 374 119 0.32 0.060 2±0.001 8 0.657 2±0.020 2 0.078 7±0.000 9 0.023 2±0.000 7 488.3±5.4 512.9±12.4 463.0±13.7 07 253 235 0.93 0.098 6±0.002 4 3.599 6±0.089 7 0.263 3±0.003 5 0.064 1±0.001 4 15 06.5±17.7 1 549.4±19.8 1 255.0±26.8 08 161 146 0.90 0.095 3±0.002 5 3.643 7±0.093 5 0.276 4±0.003 2 0.074 6±0.001 8 1 573.0±16.3 1 559.1±20.4 1 454.9±33.1 09 258 262 1.02 0.099 9±0.002 1 3.831 7±0.088 4 0.277 7±0.004 0 0.064 7±0.001 4 1 579.6±20.4 1 599.4±18.6 1 266.7±26.4 注:分析测试工作在中国地质大学(武汉)地质过程与矿产资源国家重点实验室测定. 表 4 平川地区大杉树辉长岩锆石稀土分析结果
Table 4. The analysis results of zircon REE of Dashanshu gabbro in Pingchuan region
分析点 元素(10-6) LREE/HREE δEu δCe La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 01 0.009 2 34.90 0.09 1.43 3.08 1.33 21.62 11.26 157.62 65.67 323.46 76.32 759.13 129.94 0.03 0.36 105.52 02 0.000 0 27.54 0.12 1.79 4.18 1.17 21.80 10.71 132.70 52.16 221.94 48.30 455.14 73.12 0.03 0.30 63.41 03 0.005 0 42.82 0.09 2.15 5.26 1.54 26.27 14.09 189.26 79.84 368.47 83.82 819.12 133.59 0.03 0.33 139.59 04 0.100 3 24.44 0.46 7.26 13.99 5.00 87.08 36.38 435.58 158.82 683.81 144.48 1364.94 215.60 0.02 0.33 13.94 05 0.016 3 44.48 0.16 2.60 5.73 1.48 31.42 15.81 209.74 82.38 379.41 83.80 804.10 131.03 0.03 0.27 78.12 06 0.000 0 27.92 0.09 1.38 3.92 1.17 19.61 10.12 143.30 58.62 287.90 67.06 681.36 115.61 0.02 0.33 93.24 07 0.097 8 34.97 0.53 8.07 18.09 5.36 90.56 39.55 470.83 173.93 750.13 165.51 1 557.64 249.51 0.02 0.33 17.65 08 0.063 5 29.49 0.21 2.91 5.90 1.51 32.22 15.35 194.75 79.12 358.21 80.99 790.04 124.81 0.02 0.27 36.52 09 0.000 0 18.84 0.19 4.44 9.89 2.20 45.90 19.90 228.14 84.08 360.77 77.76 733.30 113.78 0.02 0.26 28.47 10 0.013 9 12.31 0.05 0.86 2.71 0.55 13.32 6.72 84.84 34.95 164.51 38.34 386.28 66.08 0.02 0.23 61.98 11 0.052 9 29.64 0.05 1.83 3.60 1.19 20.14 10.66 149.18 61.29 290.88 66.07 661.86 107.02 0.03 0.34 115.23 12 0.046 4 42.45 0.16 2.23 6.73 1.48 35.03 16.54 223.37 90.59 414.22 92.97 895.55 142.99 0.03 0.24 67.51 13 0.054 5 40.63 0.39 6.42 13.35 3.60 69.48 29.53 361.78 129.67 557.11 118.41 1 072.94 168.56 0.03 0.29 28.14 14 0.014 5 15.82 0.10 1.79 3.05 1.00 17.67 7.92 107.12 44.55 210.12 49.19 484.44 85.38 0.02 0.33 43.36 15 0.046 0 22.48 0.36 6.88 12.12 2.68 58.28 25.39 294.42 108.22 460.19 99.14 930.72 142.63 0.02 0.25 17.16 16 0.000 0 20.36 0.18 4.79 7.25 2.41 38.89 17.20 210.42 77.92 350.77 78.58 767.70 122.09 0.02 0.35 32.20 17 0.133 3 42.41 0.52 9.42 24.11 6.30 120.51 49.27 575.26 204.58 850.92 180.25 1 654.82 245.62 0.02 0.29 21.38 18 0.019 2 22.06 0.37 4.91 11.44 2.60 59.31 28.29 350.92 132.60 577.49 122.86 1 134.99 178.77 0.02 0.25 16.59 19 0.019 4 15.38 0.29 4.77 8.52 2.14 46.19 20.50 245.44 89.35 382.46 83.29 778.75 120.58 0.02 0.26 14.58 20 0.039 6 20.02 0.21 4.04 7.42 1.87 40.21 16.97 217.08 86.48 384.21 84.26 799.30 132.11 0.02 0.26 24.97 21 0.013 6 3.41 0.07 1.42 3.46 1.57 15.93 7.80 99.53 41.14 197.15 49.38 549.88 100.54 0.01 0.54 12.28 22 0.047 7 14.43 0.19 3.55 9.10 2.67 45.89 19.72 229.23 84.99 363.72 78.35 727.83 117.92 0.02 0.32 19.89 23 0.025 4 19.92 0.12 1.84 4.83 1.77 26.31 12.18 163.87 67.30 321.23 76.78 812.31 146.50 0.02 0.38 42.60 24 0.041 0 50.80 0.17 1.13 3.75 1.78 25.77 13.19 182.01 77.44 386.06 94.43 988.67 172.94 0.03 0.41 77.19 25 0.014 9 42.62 0.19 2.95 4.95 1.26 28.76 13.72 161.79 63.03 283.36 61.02 580.10 92.22 0.04 0.25 62.42 注:分析测试工作在中国地质大学(武汉)地质过程与矿产资源国家重点实验室测定. -
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