铊同位素分析技术及其在地学中的应用

邱啸飞; 卢山松; 谭娟娟; 杨红梅; 段瑞春

doi:10.3799/dqkx.2014.066

铊同位素分析技术及其在地学中的应用

doi: 10.3799/dqkx.2014.066

中国地质调查局武汉地质调查中心同位素地球化学研究室，湖北武汉 430205

基金项目:

国家自然科学基金项目 41303026

中国地质调查局地质大调查项目 1212011121102

中国地质调查局地质大调查项目 1212011220512

详细信息

作者简介:
邱啸飞(1985-)，男，助理研究员，博士，主要从事同位素地球化学和岩石地球化学研究.E-mail: qiuxiaofei@geochemist.cn

中图分类号: P597
计量
- 文章访问数: 3960
- HTML全文浏览量: 753
- PDF下载量: 442
- 被引次数: 0
出版历程
- 收稿日期: 2013-08-25
- 刊出日期: 2014-06-15

Advances in Tl Isotopic Analysis and Its Geological Applications

Isotope Geochemistry Laboratory, Wuhan Center of Geological Survey, Wuhan 430205, China

摘要

摘要: 应用多接收电感耦合等离子质谱(MC-ICP-MS)等分析技术进行铊(Tl)同位素分析已成为非传统稳定同位素地球化学研究的重要内容之一.对近年来Tl同位素的实验测试方法及其地质应用的有关研究进展做了详细论述，包括Tl的地球化学行为、Tl同位素分析测试技术、同位素分馏机理、在各地质储库中的组成特征以及Tl同位素的地质应用等多个方面.这些研究表明该分析技术为行星科学、古海洋学、地幔地球化学、岩石成因以及矿床学等领域的研究提供了其他同位素分析方法难以获得的重要信息，充分展示了该分析技术在地球科学和环境科学领域的应用前景.
- 同位素 /
- 地质应用 /
- 研究进展 /
- 地球化学
Abstract: The utilization of MC-ICP-MS on thallium isotope is an important development in nontraditional stable isotopic geochemistry. This paper presents the advances in analytical methods and geological applications of Tl isotope in recent years, including element geochemical behavior, analytical techniques of Tl isotope, isotopic fractionation mechanism, the variability in various geological reservoirs, and its applications. Tl isotopes, compared to other isotopes, offer distinctive implications in the fields of planetary science, paleoceanography, mantle geochemistry, petrology, and mineral deposits. Therefore, Tl isotopes can have a great prospect in the further applications in geological and environmental sciences.
- isotope /
- geological application /
- advance /
- geochemistry

HTML全文

图 1 自然界中Tl同位素的ε²⁰⁵Tl变化

数据引自Rehkämper and Halliday, 1999; Rehkämper et al., 2002, 2004; Nielsen et al., 2004, 2005, 2006a, 2006b, 2006c, 2007, 2009a, 2009b, 2011; Rehkämper and Nielsen, 2004; Baker et al., 2009, 2010; Prytulak et al., 2013

Fig. 1. Variation of ε²⁰⁵Tl values in nature

下载: 全尺寸图片幻灯片

图 2 Tl的大洋循环示意

源汇通量的最佳估计值来自Rehkämper et al., 2002, 2004; Nielsen et al., 2005, 2006c; Baker et al., 2009, 2010

Fig. 2. The ocean cycle of dissolved Tl

下载: 全尺寸图片幻灯片

参考文献(54)

Anders, E., Stevens, C.M., 1960. Search for Extinct Lead 205 in Meteorites. Journal of Geophysical Research, 65(10): 3043-3048. doi: 10.1029/JZ065i010p03043
Baker, R.G.A., Rehkämper, M., Hinkley, T., et al., 2009. Investigation of Thallium Fluxes from Subaerial Volcanism—Implications for the Present and Past Mass Balance of Thallium in the Oceans. Geochimica et Cosmochimica Acta, 73(20): 6340-6359. doi: 10.1016/j.gca.2009.07.014
Baker, R.G.A., Rehkämper, M., Ihlenfeld, C., et al., 2010. Thallium Isotope Variations in an Ore-Bearing Continental Igneous Setting: Collahuasi Formation, Northern Chile. Geochimica et Cosmochimica Acta, 74(15): 4405-4416. doi: 10.1016/j.gca.2010.04.068
Bidoglio, G., Gibson, P., O'Gorman, M., et al., 1993. X-Ray Absorption Spectroscopy Investigation of Surface Redox Transformations of Thallium and Chromium on Colloidal Mineral Oxides. Geochimica et Cosmochimica Acta, 57(10): 2389-2394. doi: 10.1016/0016-7037(93)90576-I
Bopp, C.J., Lundstrom, C.C., Johnson, T.M., et al., 2009. Variations in ²³⁸U/²³⁵U in Uranium Ore Deposits: Isotopic Signatures of the U Reduction Process?Geology, 37(7): 611-614. doi: 10.1130/G25550A.1
Burton, K.W., Ling, H.F., O'Nions, R.K., 1997. Closure of the Central American Isthmus and Its Effect on Deep-Water Formation in the North Atlantic. Nature, 386(6623): 382-385. doi: 10.1038/386382a0
Chen, J.H., Wasserburg, G.J., 1987. A Search for Evidence of Extinct Lead 205 in Iron Meteorites. Abstracts of the Lunar and Planetary Science Conference, 18: 165-166. http://adsabs.harvard.edu/abs/1987lpi....18..165c
Cloquet, C., Carignan, J., Libourel, G., et al., 2006. Tracing Source Pollution in Soils Using Cadmium and Lead Isotopes. Environmental Science & Technology, 40(8): 2525-2530. doi: 10.1021/es052232+
Coggon, R., Rehkämper, M., Atteck, C., et al., 2009. Constraints on Hydrothermal Fluid Fluxes from Tl Geochemistry. Geochimica et Cosmochimica Acta, 73(13): A234 http://adsabs.harvard.edu/abs/2009GeCAS..73Q.234C
Dunstan, L., Gramlich, J., Barnes, I., et al., 1980. Absolute Isotopic Abundance and the Atomic Weight of a Reference Sample of Thallium. Journal of Research of the National Bureau of Standards, 85(1): 1-10. doi: 10.6028/jres.085.001
Hofmann, A.W., 1997. Mantle Geochemistry: The Message from Oceanic Volcanism. Nature, 385(6613): 219-229. doi: 10.1038/385219a0
Huey, J.M., Kohman, T.P., 1972. Search for Extinct Natural Radioactivity of ²⁰⁵Pb via Thallium-Isotope Anomalies in Chondrites and Lunar Soil. Earth and Planetary Science Letters, 16(3): 401-412. doi: 10.1016/0012-821X(72)90159-8
Kazantzis, G., 2000. Thallium in the Environment and Health Effects. Environmental Geochemistry and Health, 22(4): 275-280. doi: 10.1023/A:1006791514080
Lee, D.C., Halliday, A.N., Hein, J.R., et al., 1999. Hafnium Isotope Stratigraphy of Ferromanganese Crusts. Science, 285(5430): 1052-1054. doi: 10.1126/science.285.5430.1052
McDonough, W., Sun, S.S., 1995. The Composition of the Earth. Chemical Geology, 120(3-4): 223-253. doi: 10.1016/0009-2541(94)00140-4
Metz, S., Trefry, J.H., 2000. Chemical and Mineralogical Influences on Concentrations of Trace Metals in Hydrothermal Fluids. Geochimica et Cosmochimica Acta, 64(13): 2267-2279. doi: 10.1016/S0016-7037(00)00354-9
Nielsen, S.G., Goff, M., Hesselbo, S.P., et al., 2011. Thallium Isotopes in Early Diagenetic Pyrite—A Paleo Redox Proxy?Geochimica et Cosmochimica Acta, 75(21): 6690-6704. doi: 10.1016/j.gca.2011.07.047
Nielsen, S.G., Mar-Gerrison, S., Gannoun, A., et al., 2009a. Thallium Isotope Evidence for a Permanent Increase in Marine Organic Carbon Export in the Early Eocene. Earth and Planetary Science Letters, 278(3-4): 297-307. doi: 10.1016/j.epsl.2008.12.010
Nielsen, S.G., Rehkämper, M., 2012. Thallium Isotopes and Their Application to Problems in Earth and Environmental Science. In: Baskaran, M., ed., Handbook of Environmental Isotope Geochemistry. Springer, Berlin, 247-269. doi: 10.1007/978-3-642-10637-8_13
Nielsen, S.G., Rehkämper, M., Baker, J., et al., 2004. The Precise and Accurate Determination of Thallium Isotope Compositions and Concentrations for Water Samples by MC-ICPMS. Chemical Geology, 204(1-2): 109-124. doi: 10.1016/j.chemgeo.2003.11.006
Nielsen, S.G., Rehkämper, M., Brandon, A.D., et al., 2007. Thallium Isotopes in Iceland and Azores Lavas—Implications for the Role of Altered Crust and Mantle Geochemistry. Earth and Planetary Science Letters, 264(1-2): 332-345. doi: 10.1016/j.epsl.2007.10.008
Nielsen, S.G., Rehkämper, M., Halliday, A.N., 2006a. Large Thallium Isotopic Variations in Iron Meteorites and Evidence for Lead-205 in the Early Solar System. Geochimica et Cosmochimica Acta, 70(10): 2643-2657. doi: 10.1016/j.gca.2006.02.012
Nielsen, S.G., Rehkämper, M., Norman, M.D., et al., 2006b. Thallium Isotopic Evidence for Ferromanganese Sediments in the Mantle Source of Hawaiian Basalts. Nature, 439(7074): 314-317. doi: 10.1038/nature04450
Nielsen, S.G., Rehkämper, M., Porcelli, D., et al., 2005. Thallium Isotope Composition of the Upper Continental Crust and Rivers—An Investigation of the Continental Sources of Dissolved Marine Thallium. Geochimica et Cosmochimica Acta, 69(8): 2007-2019. doi: 10.1016/j.gca.2004.10.025
Nielsen, S.G., Rehkämper, M., Teagle, D.A., et al., 2006c. Hydrothermal Fluid Fluxes Calculated from the Isotopic Mass Balance of Thallium in the Ocean Crust. Earth and Planetary Science Letters, 251(1-2): 120-133. doi: 10.1016/j.epsl.2006.09.002
Nielsen, S.G., Williams, H.M., Griffin, W.L., et al., 2009b. Thallium Isotopes as a Potential Tracer for the Origin of Cratonic Eclogites. Geochimica et Cosmochimica Acta, 73(24): 7387-7398. doi: 10.1016/j.gca.2009.09.001
Nriagu, J.O., 1998. Thallium in the Environment. Advances in Environmental Science and Technology, 29: 289.
Ostic, R., El-Badry, H., Kohman, T., 1969. Isotopic Composition of Meteoritic Thallium. Earth and Planetary Science Letters, 7(1): 72-76. doi: 10.1016/0012-821X(69)90015-6
Peacock, C.L., Moon, E.M., Nielsen, S.G., et al., 2009. Oxidative Scavenging of Tl by Mn Oxide Birnessite: Sorption and Stable Isotope Fractionation. Geochimica et Cosmochimica Acta, 73(Suppl. ): A1003.
Pengra, J.G., Genz, H., Fink, R.W., 1978. Orbital Electron Capture Ratios in the Decay of ²⁰⁵Pb. Nuclear Physics A, 302(1): 1-11. doi: 10.1016/0375-9474(78)90283-X
Poirier, A., Doucelance, R., 2009. Effective Correction of Mass Bias for Rhenium Measurements by MC-ICP-MS. Geostandards and Geoanalytical Research, 33(2): 195-204. doi: 10.1111/j.1751-908X.2009.00017.x
Prytulak, J., Nielsen, S., Plank, T., et al., 2013. Assessing the Utility of Thallium and Thallium Isotopes for Tracing Subduction Zone Inputs to the Mariana Arc. Chemical Geology, 345: 139-149. doi: 10.1016/j.chemgeo.2013.03.003
Qiu, X.F., Ling, W.L., 2009. Progress in In-Situ Common Pb Isotopic Analysis and Its Geological Applications. Geological Science and Technology Information, 28(5): 118-124 (in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTOTAL-DZKQ200905017.htm
Rehkämper, M., Frank, M., Hein, J., et al., 2002. Thallium Isotope Variations in Seawater and Hydrogenetic, Diagenetic, and Hydrothermal Ferromanganese Deposits. Earth and Planetary Science Letters, 197(1-2): 65-81. doi: 10.1016/S0012-821X(02)00462-4
Rehkämper, M., Frank, M., Hein, J., et al., 2004. Cenozoic Marine Geochemistry of Thallium Deduced from Isotopic Studies of Ferromanganese Crusts and Pelagic Sediments. Earth and Planetary Science Letters, 219(1-2): 77-91. doi: 10.1016/S0012-821X(03)00703-9
Rehkämper, M., Halliday, A.N., 1999. The Precise Measurement of Tl Isotopic Compositions by MC-ICPMS: Application to the Analysis of Geological Materials and Meteorites. Geochimica et Cosmochimica Acta, 63(6): 935-944. doi: 10.1016/S0016-7037(98)00312-3
Rehkämper, M., Nielsen, S.G., 2004. The Mass Balance of Dissolved Thallium in the Oceans. Marine Chemistry, 85(3-4): 125-139. doi: 10.1016/j.marchem.2003.09.006
Rudge, J.F., Reynolds, B.C., Bourdon, B., 2009. The Double Spike Toolbox. Chemical Geology, 265(3-4): 420-431. doi: 10.1016/j.chemgeo.2009.05.010
Sager, M., 1993. Determination of Arsenic, Cadmium, Mercury, Stibium, Thallium and Zinc in Coal and Coal Fly-ash. Fuel, 72(9): 1327-1330. doi: 10.1016/0016-2361(93)90132-L
Sasmaz, A., Sen, O., Kaya, G., et al., 2007. Distribution of Thallium in Soil and Plants Growing in the Keban Mining District of Turkey and Determined by ICP-MS. Atomic Spectroscopy-Norwalk Connecticut, 28(5): 157-194. http://www.researchgate.net/publication/344466030_Distribution_of_Thallium_in_Soil_and_Plants_Growing_in_the_Keban_Mining_District_of_Turkey_and_Determined_by_ICP-MS
Schauble, E.A., 2007. Role of Nuclear Volume in Driving Equilibrium Stable Isotope Fractionation of Mercury, Thallium, and Other Very Heavy Elements. Geochimica et Cosmochimica Acta, 71(9): 2170-2189. doi: 10.1016/j.gca.2007.02.004
Schedlbauer, O.F., Heumann, K.G., 2000. Biomethylation of Thallium by Bacteria and First Determination of Biogenic Dimethyl Thallium in the Ocean. Applied Organometallic Chemistry, 14(6): 330-340. doi: 10.1002/(SICI)1099-0739(200006)14:6<330::AID-AOC994>3.0.CO;2-Y
Shaw, D.M., 1952. The Geochemistry of Thallium. Geochimica et Cosmochimica Acta, 2(2): 118-154. doi: 10.1016/0016-7037(52)90003-3
Shiel, A.E., Barling, J., Orians, K.J., et al., 2009. Matrix Effects on the Multi-Collector Inductively Coupled Plasma Mass Spectrometric Analysis of High-Precision Cadmium and Zinc Isotope Ratios. Analytica Chimica Acta, 633(1): 29-37. doi: 10.1016/j.aca.2008.11.026
Stirling, C.H., Andersen, M.B., Potter, E.K., et al., 2007. Low-Temperature Isotopic Fractionation of Uranium. Earth and Planetary Science Letters, 264(1): 208-225. doi: 10.1016/j.epsl.2007.09.019
Thirlwall, M.F., Gee, M., Taylor, R.N., et al., 2004. Mantle Components in Iceland and Adjacent Ridges Investigated Using Double-Spike Pb Isotope Ratios. Geochimica et Cosmochimica Acta, 68(2): 361-386. doi: 10.1016/S0016-7037(03)00424-1
Tribovillard, N., Algeo, T.J., Lyons, T., et al., 2006. Trace Metals as Paleoredox and Paleoproductivity Proxies: An Update. Chemical Geology, 232(1): 12-32. doi: 10.1016/j.chemgeo.2006.02.012
Urey, H.C., 1947. The Thermodynamic Properties of Isotopic Substances. Journal of the Chemical Society (Resumed), 562-581. doi: 10.1039/JR9470000562
van de Flierdt, T., Frank, M., Halliday, A.N., et al., 2004. Tracing the History of Submarine Hydrothermal Inputs and the Significance of Hydrothermal Hafnium for the Seawater Budget—A Combined Pb-Hf-Nd Isotope Approach. Earth and Planetary Science Letters, 222(1): 259-273. doi: 10.1016/j.epsl.2004.02.025
Walder, A.J., Freedman, P.A., 1992. Isotopic Ratio Measurement Using a Double Focusing Magnetic Sector Mass Analyser with an Inductively Coupled Plasma as an Ion Source. Journal of Analytical Atomic Spectrometry, 7(3): 571-575. doi: 10.1039/JA9920700571
Williams, H.M., Nielsen, S.G., Renac, C., et al., 2009. Fractionation of Oxygen and Iron Isotopes in the Mantle: Implications for Crustal Recycling and the Source Regions of Oceanic Basalts. Earth and Planetary Science Letters, 283: 156-166. doi: 10.1016/j.epsl.2009.04.011
Xie, S.C., Pancost, R.D., Yin, H.F., et al., 2005. Two Episodes of Microbial Change Coupled with Permo/Triassic Faunal Mass Extinction. Nature, 434(7032): 494-497. doi: 10.1038/nature03396
Zindler, A., Hart, S., 1986. Chemical Geodynamics. Annual Review of Earth and Planetary Sciences, 14: 493-571. doi: 10.1146/annurev.ea.14.050186.002425
邱啸飞, 凌文黎, 2009. 微区原位普通铅同位素分析技术及其地质应用进展. 地质科技情报, 28(5): 118-124. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ200905017.htm