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    新疆西天山松湖铁矿床磁铁矿成分特征及其成因

    朱维娜 王义天 王春龙 张兵 张立成 任毅 肖燕红 袁彦超 胡相波

    朱维娜, 王义天, 王春龙, 张兵, 张立成, 任毅, 肖燕红, 袁彦超, 胡相波, 2015. 新疆西天山松湖铁矿床磁铁矿成分特征及其成因. 地球科学, 40(10): 1723-1740. doi: 10.3799/dqkx.2015.155
    引用本文: 朱维娜, 王义天, 王春龙, 张兵, 张立成, 任毅, 肖燕红, 袁彦超, 胡相波, 2015. 新疆西天山松湖铁矿床磁铁矿成分特征及其成因. 地球科学, 40(10): 1723-1740. doi: 10.3799/dqkx.2015.155
    Zhu Weina, Wang Yitian, Wang Chunlong, Zhang Bing, Zhang Licheng, Ren Yi, Xiao Yanhong, Yuan Yanchao, Hu Xiangbo, 2015. Magnetite Composition and Its Genetic Significance of the Songhu Iron Deposit in the Western Tianshan, Xinjiang, NW China. Earth Science, 40(10): 1723-1740. doi: 10.3799/dqkx.2015.155
    Citation: Zhu Weina, Wang Yitian, Wang Chunlong, Zhang Bing, Zhang Licheng, Ren Yi, Xiao Yanhong, Yuan Yanchao, Hu Xiangbo, 2015. Magnetite Composition and Its Genetic Significance of the Songhu Iron Deposit in the Western Tianshan, Xinjiang, NW China. Earth Science, 40(10): 1723-1740. doi: 10.3799/dqkx.2015.155

    新疆西天山松湖铁矿床磁铁矿成分特征及其成因

    doi: 10.3799/dqkx.2015.155
    基金项目: 

    中国地质调查局地质大调查工作项目"新疆天山古生代构造岩浆成矿系统与勘查模型研究" 1212011085527

    详细信息
      作者简介:

      朱维娜(1989- ) , 女, 硕士研究生, 主要研究矿物学、 岩石学、 矿床学专业.E-mail:weina_zhu@126.com

      通讯作者:

      王义天, E-mail: wyt69@263.com

    • 中图分类号: P318.4

    Magnetite Composition and Its Genetic Significance of the Songhu Iron Deposit in the Western Tianshan, Xinjiang, NW China

    • 摘要: 松湖铁矿位于新疆阿吾拉勒成矿带中段, 其成矿作用经历了2期6个阶段: 硫化物-钾长石阶段、赤铁矿-方解石-绿泥石阶段、磁铁矿-绿泥石-钾长石阶段(称为早阶段铁矿化)、磁铁矿-硫化物阶段(称为晚阶段铁矿化)、方解石-黄铜矿阶段及表生期.为了分析其成分特征及其成因, 使用磁铁矿电子探针分析, 结果显示: 早阶段磁铁矿FeOT含量高, TiO2、Al2O3、MgO、MnO等含量均较低, 与接触交代矿床成分特征相似, 加之SiO2含量较高, 暗示其形成与酸性岩浆热液密切相关; 晚阶段为主成矿阶段, 广泛作用于早阶段矿石之上, 磁铁矿FeOT含量相对较低, TiO2、MnO、V2O3、MgO、Al2O3等含量高于早阶段磁铁矿, 显示为热液成因.综合矿床地质特征, 认为晚阶段磁铁矿形成于岩浆活动晚期或间歇期, 含矿热液中有海水的加入.

       

    • 图  1  阿吾拉勒成矿带区域地质及矿产分布

      1.中-新生界;2.二叠系;3.石炭系;4.泥盆系;5.志留系;6.奥陶系;7.寒武系;8.前寒武系;9.二叠纪花岗岩;10.石炭系花岗岩;11.泥盆纪花岗岩;12.志留纪花岗岩;13.铁镁-超铁镁岩;14.主要断裂;15.国界线;16.阿吾拉勒成矿带范围;17.主要铁矿床;18.松湖铁矿;①.式可布台;②.松湖;③.穹库尔;④.尼新塔格-阿克萨依;⑤.查岗诺尔;⑥.智博;⑦.敦德;⑧.备战;修改自李凤鸣等(2011)张作衡等(2012)

      Fig.  1.  Geological map of Awulale metallogenic belt and iron deposits

      图  2  松湖铁矿地质

      1.第四系;2.下石炭统大哈拉军山组浅紫色凝灰岩;3.浅灰绿色中细粒凝灰岩;4.紫色-紫红色晶屑岩屑中细粒凝灰岩;5.灰白-灰黑色灰岩;6.灰黑色碳质凝灰岩;7.矿体位置及编号;8.实测地质界线;9.推测断层及编号;10.实测逆断层、编号及产状;修改自新疆地矿局第七地质大队报告(2011)

      Fig.  2.  Geological map of the Songhu iron deposit

      图  3  松湖铁矿床2号勘探线剖面

      修改自新疆地矿局第七地质大队报告(2011)

      Fig.  3.  Section along No.2 exploration line of the Songhu iron deposit

      图  4  松湖铁矿围岩蚀变

      a.矿体剖面(图中标注了b~g的位置);b.矿体与底板围岩接触部位发育高岭土化,矿体边部见不连续脉状钾长石化、绿泥石化;c.后期方解石脉切穿团块状绿泥石,方解石脉外侧发育钾长石化;d.磁铁矿石内黄铜矿-方解石脉;e.角砾状褐铁矿化;f.方解石脉内见绿帘石;g.矿体内绿泥石-钾长石脉;Chl.绿泥石;Kf.钾长石;Py.黄铁矿;Lm.褐铁矿;Mt.磁铁矿;Cal.方解石;Kln.高岭石;Hm.赤铁矿;Ccp.黄铜矿;Ep.绿帘石

      Fig.  4.  Wall rock alteration of the Songhu iron deposit

      图  5  松湖铁矿矿石照片

      a.早阶段叶片状磁铁矿;b.交代残余结构;c.交代残余结构;d.块状磁铁矿;e.磁铁矿及黄铁矿组成的条带状矿石;f.早阶段脉状磁铁矿,伴随钾长石化;g.晚阶段粒状磁铁矿,穿切叶片状磁铁矿;h.胶状磁特矿;i.磁铁矿与赤铁矿呈环带状结构;j.晚阶段脉状磁铁矿;k.团块状磁铁矿;l.角砾状磁铁矿;Mt.磁铁矿;Mt1.早阶段磁铁矿;Mt2.晚阶段磁铁矿;Hm.赤铁矿;Py.黄铁矿;Kf.钾长石;Chl.绿泥石;Cal.方解石

      Fig.  5.  Texture and structure of ores from the Songhu iron deposit

      图  6  松湖铁矿磁铁矿电子探针成分蛛网图

      底图据Céline and Georges(2011)

      Fig.  6.  Spider diagram of magnetite from the Songhuiron deposit

      图  7  松湖铁矿磁铁矿氧化物成分相关性

      Fig.  7.  The correlation diagram of oxides in magnetite from the Songhu iron deposit

      图  8  磁铁矿Ca+Al+Mn vs.Ti+V成因分类

      底图据Céline and Georges(2011)

      Fig.  8.  The Ca+Al+Mn vs.Ti+V discriminant diagram of magnetite

      图  9  松湖铁矿床磁铁矿TiO2-Al2O3-MgO三角图解

      Ⅰ.花岗岩区;Ⅱ.玄武岩区;Ⅲ.辉长岩区;Ⅳ.橄榄岩区;Ⅴ1.角闪石岩区;Ⅴ2.闪长岩区;Ⅵ.金伯利岩区;Ⅶ.热液型及钙矽卡岩型(虚线以上主要为深成热液型,以下为热液型及钙矽卡岩型);Ⅷ.热液型及镁矽卡岩型(深成热液型,部分为热液交代型,镁矽卡岩型);Ⅸ.沉积变质,热液叠加型;Ⅹ.碳酸盐岩区(靠上部者与超基性岩有关,靠下部者与围岩交代有关);XI.过渡区;底图据王顺金等(1984)

      Fig.  9.  The triangular figure of TiO2-Al2O3-MgO of magnetite from the Songhu iron deposit

      图  10  磁铁矿元素含量相关点阵

      A.缓倾斜区;B.过渡区;C.陡倾斜区;底图据林师整(1982)

      Fig.  10.  The related dot matrix of elements in magnetite

      表  1  松湖铁矿矿物生成顺序

      Table  1.   Genetic sequences of mineral assemblages in Songhu iron deposit

      下载: 导出CSV

      表  2  松湖铁矿电子探针测试样品描述

      Table  2.   The samples for electron microprobe analyses from Songhu iron deposit

      样品号 采样位置 Mt化阶段 描述
      SH1-11 2738m平台,靠近底板围岩 黑色富磁铁矿石,块状构造
      SH1-13 2738m平台,靠近底板围岩 早、晚 黑色富磁铁矿石,块状构造,主要由磁铁矿、黄铁矿组成
      SH1-20 2738m平台,靠近底板围岩 早、晚 黑色磁铁矿,角砾状构造,胶结物为钾长石、绿泥石
      SH1-21 2738m平台,靠近底板围岩 钢灰色磁铁矿,块状-蜂窝状构造
      SH1-22 2738m平台,靠近底板围岩 早、晚 灰黑色磁铁矿,角砾状构造,磁铁矿周围发育赤铁矿化
      SH1-31 2738m平台,靠近底板围岩 黑色磁铁矿,脉状构造,磁铁矿结晶颗粒粗大
      SH1-32 2738m平台,磁铁矿脉 黑色磁铁矿,脉状构造,约5cm,磁铁矿结晶颗粒粗大
      SH1-33 2738m平台,磁铁矿脉 黑色磁铁矿,脉状构造,约5cm,磁铁矿结晶颗粒粗大
      SH1-38 2738m平台,矿体中部 灰黑色,磁铁矿呈不连续脉状,脉石矿物主要为钾长石及绿泥石
      SH2-17 2749m平台,矿体中部 黑色磁铁矿,块状构造,发育钾长石化脉
      SH2-21 2749m平台,矿体中部 黑色磁铁矿,块状构造,发育脉状钾长石及黄铁矿
      SH2-31 2749m平台,靠近顶板围岩 早、晚 灰黑色磁铁矿,角砾状构造,,磁铁矿角砾中含黄铁矿
      SH2-32 2749m平台,靠近顶板围岩 早、晚 灰黑色磁铁矿,块状构造,发育条带状黄铁矿
      SH3-8 2765m平台,矿体中部 锖色磁铁矿,块状构造,发育不连续蚀变热液脉
      SH3-16 2765m平台,矿体中部 黑色磁铁矿,脉状构造,含脉状黄铁矿
      SH5-6 2813m平台,浅部矿体 灰黑色磁铁矿,脉状构造
      SH6-3 2729m平台,深部矿体 灰黑色磁铁矿,块状构造,蚀变强烈
      SH6-7 2729m平台,深部矿体 黑色磁铁矿,脉状构造,磁铁矿结晶颗粒粗大
      SH7-3 矿体中部 橘红色贫铁矿石,团块状构造,局部见钾长石脉
      SH7-7 矿体中部 钢灰色磁铁矿,脉状构造,发育黄钾铁矾
      SH8-1 矿体中部 早、晚 肉红色钾长石化磁铁矿,角砾状构造
      SH9-1 矿体中部 蚀变岩,钾长石化、绿泥石化强烈,磁铁矿呈角砾状分布
      SH12-1 矿体中部 褐红色磁铁矿,团块状-蜂窝状构造
      SH13-1 2888m平台,浅部矿体 条带状构造,磁铁矿与钾长石条带相间分布
      ZK217-12 217钻孔,矿体深部尖灭处 黑色磁铁矿,块状构造,含少量浸染状黄铁矿
      ZK217-14 217钻孔,矿体深部尖灭处 黑色磁铁矿,块状构造,含少量浸染状黄铁矿
      I-7 矿体上部 钢灰色磁铁矿,条带状构造,局部发育褐铁矿化
      I-13 矿体上部 条带状构造,磁铁矿与钾长石条带相间分布,接触线平直
      1003-31 1003钻孔,矿体上部 灰绿色中细粒凝灰岩,见浸染状黄铁矿化及脉状磁铁矿
      1003-32 1003钻孔,矿体上部 灰绿色中细粒凝灰岩,蚀变强烈,磁铁矿呈脉状
      1003-33 1003钻孔,矿体上部 矿体顶板蚀变岩,磁铁矿呈脉状
      1003-34 1003钻孔,矿体下部 灰紫色中细粒凝灰岩,磁铁矿呈粗脉状
      1003-37 1003钻孔,矿体下部 灰绿色中细粒凝灰岩,磁铁矿呈条带状
      1003-40 1003钻孔,矿体下部 钢灰色磁铁矿,脉状构造
      1003-43 1003钻孔,矿体下部 灰绿色角砾凝灰岩,磁铁矿含量较低,呈条带状
      VII-6 矿体上部 黑色富磁铁矿石,块状构造,见脉状及纹层状黄铁矿
      VII-10 矿体上部 黑色富磁铁矿石,块状构造,见脉状及浸染状黄铁矿
      下载: 导出CSV

      表  3  磁铁矿电子探针测试分析结果(单位: %)

      Table  3.   Electron microprobe analyses of magnetites from the Songhu iron deposit(%)

      样号 SiO2 Al2O3 MnO MgO TiO2 V2O3 Cr2O3 NiO CaO K2O Na2O P2O5 Fe2O3 FeO Total Fe3+/Fe2+
      SH1-11-1 0.56 0.16 0.04 0.05 0.05 0.00 0.00 0.03 0.00 0.00 0.07 0.01 68.92 32.05 101.94 1.94
      SH1-11-2 3.84 1.40 0.07 0.22 0.01 0.02 0.04 0.03 0.99 0.08 0.18 0.01 59.00 33.68 99.56 1.58
      SH1-11-3 1.25 0.19 0.07 0.00 0.03 0.04 0.01 0.04 0.05 0.01 0.04 0.00 67.16 33.03 101.92 1.83
      SH1-11-4 3.44 0.92 0.12 0.16 0.29 0.01 0.02 0.00 0.67 0.04 0.17 0.00 60.88 34.43 101.16 1.59
      SH1-11-5 2.39 0.55 0.07 0.14 0.13 0.04 0.00 0.03 0.37 0.04 0.07 0.00 63.51 33.53 100.85 1.70
      SH1-11-6 2.40 0.72 0.06 0.11 0.16 0.09 0.00 0.00 0.49 0.03 0.10 0.00 62.64 33.22 100.03 1.70
      SH1-11-7 1.60 0.26 0.01 0.05 0.14 0.03 0.05 0.01 0.30 0.01 0.07 0.04 65.52 32.99 101.07 1.79
      SH1-11-8 2.90 0.92 0.01 0.14 0.49 0.07 0.13 0.07 0.80 0.08 0.16 0.00 60.73 33.30 99.80 1.64
      SH1-11-9 0.52 0.16 0.00 0.00 0.01 0.00 0.00 0.00 0.00 0.02 0.05 0.00 68.60 31.87 101.23 1.94
      SH1-11-10 1.61 0.43 0.01 0.17 0.13 0.04 0.05 0.01 0.22 0.11 0.12 0.03 65.52 32.27 100.73 1.83
      SH1-11-11 0.64 0.11 0.04 0.10 0.05 0.03 0.02 0.03 0.00 0.00 0.00 0.03 67.75 32.02 100.81 1.90
      SH1-11-12 1.49 0.27 0.02 0.12 0.11 0.05 0.00 0.01 0.16 0.02 0.04 0.02 65.64 32.85 100.81 1.80
      SH1-11-13 2.30 0.58 0.14 0.16 0.02 0.02 0.00 0.01 0.35 0.01 0.12 0.00 63.73 33.01 100.45 1.74
      SH1-11-14 5.06 1.80 0.08 0.19 0.06 0.00 0.04 0.02 1.41 0.15 0.25 0.02 56.14 34.57 99.79 1.46
      SH1-11-15 0.89 0.09 0.01 0.04 0.01 0.04 0.00 0.00 0.05 0.00 0.01 0.00 67.58 32.42 101.13 1.88
      SH1-11-16 3.49 1.05 0.09 0.19 0.23 0.07 0.03 0.01 0.71 0.06 0.18 0.00 60.29 34.08 100.49 1.59
      SH1-11-17 2.38 0.60 0.02 0.12 0.14 0.07 0.02 0.00 0.41 0.03 0.12 0.00 63.40 33.39 100.69 1.71
      SH1-11-18 1.83 0.34 0.07 0.07 0.12 0.06 0.05 0.02 0.24 0.00 0.04 0.00 64.56 33.21 100.59 1.75
      SH1-11-19 3.04 0.87 0.13 0.14 0.37 0.06 0.00 0.00 0.90 0.07 0.14 0.04 61.32 33.73 100.81 1.64
      SH1-13-1 0.25 0.03 0.00 0.00 0.04 0.00 0.01 0.00 0.00 0.02 0.00 0.05 68.60 31.67 100.67 1.95
      SH1-13-2 5.47 0.43 0.00 1.06 0.15 0.02 0.00 0.00 1.92 0.05 0.15 0.01 55.75 33.37 98.39 1.50
      SH1-13-7 4.68 0.63 0.00 0.71 0.36 0.00 0.00 0.00 1.70 0.03 0.17 0.05 57.47 33.77 99.56 1.53
      SH1-13-9 0.09 0.13 0.01 0.00 0.04 0.01 0.00 0.00 0.00 0.00 0.04 0.00 66.85 30.23 97.39 1.99
      SH1-13-10 4.75 0.27 0.00 0.57 0.00 0.00 0.01 0.02 1.24 0.02 0.12 0.00 58.02 34.29 99.31 1.52
      SH1-13-14 0.04 0.04 0.00 0.02 0.01 0.01 0.00 0.00 0.00 0.00 0.01 0.00 69.95 31.55 101.63 1.99
      SH1-13-15 0.16 0.06 0.01 0.00 0.04 0.00 0.00 0.00 0.00 0.00 0.09 0.01 68.50 30.81 99.67 2.00
      SH1-13-17 1.04 0.17 0.03 0.03 0.07 0.00 0.00 0.02 0.09 0.01 0.11 0.00 66.23 31.66 99.45 1.88
      SH1-20-1 7.45 0.58 0.05 0.68 0.11 0.01 0.05 0.00 1.45 0.24 0.18 0.00 52.00 36.78 99.58 1.27
      SH1-20-3 12.14 0.46 0.01 0.63 0.11 0.01 0.00 0.00 1.49 0.15 0.14 0.00 41.82 43.95 100.92 0.86
      SH1-20-5 5.58 0.46 0.01 0.79 0.09 0.00 0.02 0.00 1.73 0.15 0.15 0.00 56.85 34.34 100.18 1.49
      SH1-20-6 4.72 0.35 0.00 0.59 0.07 0.00 0.00 0.00 1.55 0.03 0.10 0.01 58.37 34.23 100.01 1.53
      SH1-20-7 0.10 0.10 0.02 0.00 0.09 0.05 0.00 0.04 0.15 0.00 0.02 0.00 67.23 30.34 98.13 1.99
      SH1-20-9 1.23 0.15 0.00 0.01 0.22 0.03 0.04 0.00 0.06 0.02 0.07 0.00 66.29 32.75 100.85 1.82
      SH1-21-1 1.41 0.14 0.00 0.02 0.04 0.00 0.02 0.00 0.12 0.02 0.00 0.03 65.48 32.82 100.10 1.80
      SH1-22-2 5.73 0.31 0.00 0.88 0.05 0.04 0.04 0.01 1.87 0.10 0.16 0.00 56.34 34.12 99.66 1.49
      SH1-22-3 0.12 0.05 0.01 0.00 0.04 0.07 0.00 0.00 0.12 0.00 0.06 0.00 69.57 31.24 101.27 2.00
      SH1-22-4 0.50 0.17 0.00 0.02 0.11 0.04 0.01 0.00 0.00 0.00 0.00 0.02 68.16 32.21 101.22 1.90
      SH1-31-2 0.01 0.06 0.07 0.00 0.11 0.02 0.04 0.00 0.00 0.00 0.05 0.01 69.63 31.32 101.32 2.00
      SH1-31-4 1.29 0.38 0.03 0.06 0.48 0.09 0.05 0.07 0.16 0.07 0.05 0.00 65.43 32.73 100.89 1.80
      SH1-32-1 1.61 0.53 0.00 0.03 0.06 0.05 0.00 0.00 0.12 0.07 0.07 0.02 65.29 32.88 100.74 1.79
      SH1-32-3 0.65 0.03 0.06 0.04 0.14 0.04 0.00 0.00 0.00 0.00 0.03 0.00 68.03 32.15 101.16 1.90
      SH1-33-1 0.35 0.10 0.00 0.05 0.07 0.04 0.05 0.03 0.03 0.00 0.02 0.00 67.55 31.18 99.48 1.95
      SH1-33-2 1.09 0.10 0.05 0.04 0.00 0.00 0.01 0.02 0.01 0.00 0.00 0.06 66.33 32.60 100.30 1.83
      SH1-33-3 0.98 0.33 0.00 0.03 0.05 0.04 0.00 0.00 0.09 0.02 0.01 0.01 66.26 32.20 100.01 1.85
      SH1-38-1 0.78 0.07 0.01 0.10 0.05 0.00 0.00 0.00 0.05 0.02 0.06 0.02 66.75 31.41 99.31 1.91
      SH2-17-2 3.25 0.39 0.10 0.51 0.07 0.00 0.03 0.00 0.80 0.28 0.08 0.02 62.86 32.95 101.34 1.72
      SH2-21-1 3.00 0.18 0.03 0.65 0.05 0.00 0.00 0.00 0.84 0.15 0.14 0.00 62.80 32.05 99.88 1.76
      SH2-21-2 3.13 0.72 0.03 0.92 0.13 0.02 0.00 0.04 0.60 0.05 0.03 0.00 61.48 33.06 100.21 1.67
      SH2-21-3 4.72 0.49 0.07 0.87 0.07 0.04 0.00 0.00 1.19 0.20 0.09 0.03 57.30 33.27 98.33 1.55
      SH2-21-4 2.89 0.19 0.06 0.69 0.04 0.07 0.00 0.03 0.97 0.01 0.08 0.00 62.23 32.09 99.35 1.74
      SH2-31-1 0.23 0.18 0.00 0.12 0.11 0.12 0.00 0.01 0.00 0.00 0.01 0.00 65.88 30.28 96.95 1.96
      SH2-31-2 4.96 0.28 0.00 0.87 0.18 0.00 0.01 0.00 1.49 0.03 0.15 0.00 57.91 34.02 99.88 1.53
      SH2-32-1 0.24 0.10 0.00 0.00 0.07 0.04 0.02 0.00 0.00 0.00 0.00 0.00 68.72 31.72 100.91 1.95
      SH2-32-3 0.44 0.24 0.01 0.00 0.06 0.00 0.01 0.00 0.00 0.02 0.07 0.00 68.57 31.71 101.13 1.95
      SH2-32-5 3.68 0.10 0.00 0.25 0.01 0.01 0.01 0.00 0.71 0.01 0.08 0.04 61.66 34.93 101.49 1.59
      SH2-32-6 4.90 0.25 0.01 0.68 0.03 0.00 0.00 0.00 1.49 0.02 0.05 0.03 58.45 34.84 100.75 1.51
      SH3-8-1 4.99 0.79 0.05 0.98 0.12 0.16 0.06 0.00 1.01 0.25 0.06 0.03 57.26 34.27 100.03 1.50
      SH3-8-5 5.10 0.89 0.04 0.70 0.75 0.05 0.04 0.01 0.72 0.45 0.03 0.00 55.58 35.14 99.48 1.42
      SH3-16-1 1.12 0.13 0.01 0.15 0.15 0.02 0.05 0.04 0.08 0.02 0.01 0.00 65.89 32.15 99.81 1.84
      SH5-6-1 4.19 0.19 0.00 0.85 0.09 0.05 0.00 0.04 1.02 0.02 0.07 0.03 60.26 34.23 101.01 1.58
      SH5-6-3 5.54 0.51 0.06 0.66 0.14 0.02 0.00 0.00 0.98 0.22 0.06 0.04 55.16 35.15 98.53 1.41
      SH6-3-2 1.77 0.17 0.05 0.11 0.02 0.00 0.00 0.00 0.19 0.00 0.02 0.01 65.25 33.16 100.74 1.77
      SH6-3-6 1.99 0.18 0.00 0.13 0.02 0.00 0.01 0.00 0.13 0.00 0.01 0.05 63.67 33.33 99.50 1.72
      SH6-3-8 1.86 0.13 0.01 0.06 0.00 0.03 0.03 0.00 0.04 0.00 0.02 0.01 64.43 33.32 99.93 1.74
      SH6-7-1 1.86 0.11 0.00 0.01 0.09 0.05 0.00 0.00 0.00 0.00 0.05 0.04 64.65 33.64 100.51 1.73
      ZK217-12-1 0.39 0.10 0.00 0.01 0.00 0.07 0.00 0.11 0.00 0.00 0.04 0.01 68.99 31.78 101.49 1.95
      ZK217-14-2 1.92 0.60 0.02 0.08 0.08 0.03 0.00 0.00 0.23 0.03 0.09 0.00 64.81 33.22 101.12 1.76
      SH7-3-2 0.80 0.05 0.00 0.03 0.01 0.00 0.03 0.00 0.00 0.00 0.00 0.00 67.62 32.35 100.89 1.88
      SH7-3-5 0.18 0.01 0.00 0.03 0.06 0.00 0.00 0.00 0.00 0.00 0.00 0.03 68.44 31.39 100.13 1.96
      SH7-7-1 1.91 0.49 0.05 0.16 0.12 0.00 0.04 0.00 0.35 0.04 0.03 0.02 65.07 33.39 101.67 1.75
      SH8-1-3 0.10 0.03 0.05 0.00 0.20 0.00 0.07 0.00 0.00 0.01 0.00 0.00 69.15 31.68 101.29 1.96
      SH8-1-4 3.14 0.58 0.00 0.00 0.65 0.00 0.06 0.01 0.32 0.00 0.02 0.05 59.15 35.37 99.34 1.50
      SH8-1-5 0.42 0.26 0.06 0.01 0.57 0.01 0.02 0.00 0.00 0.01 0.00 0.00 67.76 32.60 101.72 1.87
      SH9-1-1 0.00 0.10 0.05 0.01 0.61 0.29 0.03 0.05 0.00 0.00 0.01 0.00 65.60 30.66 97.41 1.93
      SH9-1-2 0.35 0.21 0.00 0.02 0.60 0.33 0.08 0.00 0.00 0.00 0.00 0.00 64.47 31.23 97.30 1.86
      SH9-1-4 0.00 0.01 0.01 0.00 0.15 0.06 0.03 0.02 0.00 0.00 0.00 0.01 66.70 30.33 97.32 1.98
      SH12-1-4 0.04 0.06 0.02 0.02 0.02 0.00 0.02 0.00 0.00 0.00 0.02 0.00 70.03 31.52 101.74 2.00
      SH12-1-5 0.00 0.00 0.02 0.00 0.05 0.00 0.03 0.00 0.00 0.07 0.03 0.00 70.57 31.40 102.17 2.02
      SH13-2-2 1.02 0.25 0.00 0.02 0.19 0.00 0.02 0.00 0.47 0.05 0.01 0.00 66.39 31.95 100.37 1.87
      I-7-1 2.89 0.25 0.02 0.40 0.05 0.00 0.01 0.02 0.62 0.17 0.04 0.00 61.15 32.27 97.89 1.71
      I-13-1 4.35 0.49 0.13 0.81 0.39 0.08 0.01 0.00 1.03 0.07 0.16 0.01 58.42 33.72 99.67 1.56
      1003-31-3 0.13 0.00 0.00 0.01 0.16 0.09 0.00 0.00 0.00 0.00 0.00 0.00 66.19 30.40 96.98 1.96
      1003-31-4 0.36 0.18 0.04 0.00 0.38 0.03 0.06 0.00 0.00 0.00 0.02 0.03 63.90 30.42 95.42 1.89
      1003-31-5 0.02 0.06 0.00 0.03 1.47 0.00 0.04 0.06 0.00 0.01 0.00 0.00 64.96 31.83 98.49 1.84
      1003-32-1 0.00 0.04 0.09 0.00 0.12 0.00 0.01 0.04 0.00 0.00 0.04 0.00 70.08 31.42 101.84 2.01
      1003-32-3 1.02 0.40 0.03 0.14 0.11 0.29 0.22 0.02 0.00 0.00 0.01 0.00 65.83 32.42 100.49 1.83
      1003-32-2 0.01 0.01 0.01 0.00 0.55 0.67 0.05 0.00 0.00 0.00 0.00 0.00 67.82 31.87 100.99 1.91
      1003-33-4 0.03 0.08 0.00 0.00 0.17 0.32 0.06 0.00 0.00 0.00 0.01 0.00 68.66 31.45 100.78 1.96
      1003-33-6 0.83 0.17 0.08 0.07 0.04 0.41 0.05 0.00 0.01 0.16 0.00 0.00 67.16 31.79 100.77 1.90
      1003-34-2 0.00 0.06 0.05 0.01 0.31 0.00 0.03 0.00 0.00 0.00 0.00 0.00 70.24 32.15 102.84 1.97
      1003-37-3 0.63 0.03 0.01 0.00 0.26 0.20 0.00 0.00 0.00 0.01 0.03 0.00 68.13 32.52 101.82 1.88
      1003-40-2 2.19 0.26 0.01 0.49 0.75 0.13 0.02 0.00 0.46 0.09 0.01 0.00 62.86 33.25 100.52 1.70
      1003-43-3 0.43 0.27 0.00 0.01 0.08 0.25 0.03 0.00 0.03 0.03 0.01 0.00 68.48 32.08 101.70 1.92
      VII-6-1 2.53 0.07 0.00 0.24 0.00 0.03 0.02 0.01 0.60 0.00 0.00 0.00 63.04 33.28 99.81 1.70
      VII-6-2 2.92 0.08 0.00 0.20 0.00 0.01 0.02 0.00 0.41 0.00 0.00 0.02 62.00 34.14 99.80 1.63
      VII-6-3 2.05 0.04 0.04 0.13 0.05 0.02 0.00 0.00 0.35 0.01 0.00 0.00 64.00 33.06 99.75 1.74
      VII-10-1 1.29 0.20 0.02 0.19 0.03 0.00 0.00 0.03 0.10 0.03 0.00 0.00 66.59 32.61 101.09 1.84
      VII-10-2 4.42 0.35 0.10 0.72 0.06 0.00 0.01 0.00 0.81 0.21 0.03 0.00 59.42 34.26 100.39 1.56
      VII-10-3 4.04 0.32 0.02 0.91 0.00 0.01 0.01 0.00 1.18 0.00 0.03 0.00 60.63 33.85 101.00 1.61
      VII-10-4 4.11 0.86 0.10 0.64 0.05 0.03 0.04 0.04 1.12 0.19 0.03 0.00 59.70 33.80 100.71 1.59
      VII-10-5 5.42 1.49 0.09 0.76 0.13 0.00 0.01 0.00 1.08 0.27 0.15 0.01 56.29 34.88 100.58 1.45
      VII-10-6 0.00 0.09 0.12 0.00 0.00 0.03 0.01 0.00 0.00 0.00 0.02 0.01 69.64 31.21 101.13 2.01
      VII-10-7 4.85 0.31 0.05 1.14 0.09 0.00 0.04 0.00 1.46 0.11 0.11 0.01 58.76 33.46 100.38 1.58
      注:1.样品SH1-11-1~ZK217-14-2的测试工作完成于长安大学电子探针实验室,样品SH7-3-2~VII-10-7的测试工作完成于中国地质科学院矿产资源研究所电子探针实验室;2.Fe2O3、FeO含量为依据阴、阳离子电价平衡原理计算所得.
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