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    福建平和矾山地区花岗岩地球化学、年代学、Hf同位素特征及地质意义

    王森 张达 赵红松 潘天望 吕良冀 冯海滨 狄永军

    王森, 张达, 赵红松, 潘天望, 吕良冀, 冯海滨, 狄永军, 2016. 福建平和矾山地区花岗岩地球化学、年代学、Hf同位素特征及地质意义. 地球科学, 41(1): 67-83. doi: 10.3799/dqkx.2016.005
    引用本文: 王森, 张达, 赵红松, 潘天望, 吕良冀, 冯海滨, 狄永军, 2016. 福建平和矾山地区花岗岩地球化学、年代学、Hf同位素特征及地质意义. 地球科学, 41(1): 67-83. doi: 10.3799/dqkx.2016.005
    Wang Sen, Zhang Da, Zhao Hongsong, Pan Tianwang, Lü Liangji, Feng Haibin, Di Yongjun, 2016. Geochemistry, Zircon U-Pb Dating and Hf Isotope Composition of Granite in Fanshan Area, Pinghe County, Fujian Province, and Its Geological Significance. Earth Science, 41(1): 67-83. doi: 10.3799/dqkx.2016.005
    Citation: Wang Sen, Zhang Da, Zhao Hongsong, Pan Tianwang, Lü Liangji, Feng Haibin, Di Yongjun, 2016. Geochemistry, Zircon U-Pb Dating and Hf Isotope Composition of Granite in Fanshan Area, Pinghe County, Fujian Province, and Its Geological Significance. Earth Science, 41(1): 67-83. doi: 10.3799/dqkx.2016.005

    福建平和矾山地区花岗岩地球化学、年代学、Hf同位素特征及地质意义

    doi: 10.3799/dqkx.2016.005
    基金项目: 

    “武夷山植被覆盖区成矿地质背景研究与成矿要素综合推断”项目 1212011085472

    中国地质调查局“武夷山植被覆盖区勘查模型研究与控矿要素探查”项目 12120113089600

    福建龙岩马坑-大田汤泉铁矿整装勘查区专项填图与技术应用示范”项目 12120114028701

    详细信息
      作者简介:

      王森(1986-),男,博士,主要从事构造地质学及成矿地质背景研究.E-mail: wangsen_cug@163.com

      通讯作者:

      张达, E-mail: zhangda@cugb.edu.cn

    • 中图分类号: P597; P595

    Geochemistry, Zircon U-Pb Dating and Hf Isotope Composition of Granite in Fanshan Area, Pinghe County, Fujian Province, and Its Geological Significance

    • 摘要: 为了揭示矾山地区中生代花岗岩的成因、侵位时间及其与成矿的关系,在岩石地球化学研究基础上,进行锆石U-Pb-Hf同位素测试,并与紫金山矿田进行对比,为本区找矿预测提供依据.矾山地区花岗岩具有高钾、高碱、富硅、低钛等特征,富集轻稀土元素,具弱-中等负铕异常.富集大离子亲石元素(K、Rb、Th等),亏损高场强元素(Nb、Ta、Ti等),具有板块俯冲后伸展环境特征.对花岗岩岩体进行锆石U-Pb测年,获得了110 Ma的年龄.花岗岩与花岗闪长岩Hf同位素特征相似,εHf(t)为-3.1~1.6,TDM2为1 066~1 366 Ma,说明花岗岩主要来源于中元古代地壳物质的重融,同时显示出壳幔混合作用的特征.矾山地区与紫金山矿区构造、成岩、成矿特征相似,具有“紫金山式”铜金矿找矿潜力.

       

    • 图  1  矾山地区地质简图(a)及区域位置图(b)

      1.第四纪;2.下白垩统黄坑组;3.上侏罗统南园组上段;4.上侏罗统南园组中段;5.上侏罗统南园组下段;6.下侏罗统梨山组;7.花岗岩;8.花岗闪长岩;9.二长花岗岩;10.地质界线;11.断层;12.采样点;a.据福建省地质调查研究院,2011.福建平和大小矾山地区矿产远景调查地质矿产图;b.据韦德光等(1997)

      Fig.  1.  Geological sketch map (a) and regional location (b) of the Fanshan area

      图  2  矾山地区花岗岩(a)和花岗闪长岩(b)显微镜下特征

      Qtz.石英;Pl.斜长石;Kf.钾长石;Bt.黑云母;Hb.普通角闪石

      Fig.  2.  Microscope images of granites (a) and granodiorites (b) from the Fanshan area

      图  3  样品X01-b2(a)和F02-b1(b)锆石阴极发光图像及测试点位置

      Fig.  3.  Cathodoluminescence images and the test location of zircons from samples of X01-b2 (a) and F02-b1 (b)

      图  4  样品X01-b2(a,b)和F02-b1(c,d)锆石U-Pb年龄谐和图

      Fig.  4.  Zircon U-Pb concordia diagram of samples of X01-b2(a, b) and F02-b1(c, d)

      图  5  矾山地区花岗岩与花岗闪长岩的SiO2-(Na2O+K2O)及SiO2-K2O图

      a据Le Bas et al.(1986)及SiO2-K2O图解;b据Peccerillo and Taylor(1976)

      Fig.  5.  The SiO2-(Na2O+K2O) (a) and SiO2-K2O (b) diagrams of granite and granodiorite from the Fanshan area

      图  6  矾山地区花岗岩(a)及花岗闪长岩(b)稀土元素球粒陨石标准化配分模式

      标准值据Sun and McDonough(1989)

      Fig.  6.  Chondrite-normalized REE patterns of granite (a) and granodiorite (b) from the Fanshan area

      图  7  矾山地区花岗岩(a)及花岗闪长岩(b)微量元素原始地幔标准化蜘蛛图

      标准值据Sun and McDonough(1989)

      Fig.  7.  Primitive mantle normalized spider diagram of granite (a) and granodiorite (b) from the Fanshan area

      图  8  矾山地区花岗岩及花岗闪长岩εHf(t)-T关系

      Fig.  8.  εHf(t)-T diagram of granites and granodiorites from the Fanshan area

      图  9  矾山地区花岗岩及花岗闪长岩Y-Nb及(Rb/30)-Hf-Ta×3判别图解

      a据Foster et al.(1997);b据Harris et al.(1986)

      Fig.  9.  Y-Nb and (Rb/30)-Hf-Ta×3 discrimination diagrams of the granite and granodiorite from the Fanshan area

      表  1  矾山地区花岗岩及花岗闪长岩LA-MC-ICP MS锆石U-Pb定年测试结果

      Table  1.   LA-MC-ICP MS Zircon U-Pb dating results of granite and granodiorite from the Fanshan area

      测试点 Th/U 同位素比值 年龄(Ma)
      207Pb/206Pb±1σ 207Pb/235U±1σ 206Pb/238U±1σ 207Pb/206Pb±1σ 207Pb/235U±1σ 206Pb/238U±1σ
      X01-b2
      1 0.625 1 0.049 1±0.005 8 0.118 0±0.013 3 0.017 4±0.000 2 151±276 113±13 111±1
      2 0.594 7 0.049 1±0.001 8 0.118 4±0.004 3 0.017 5±0.000 1 154±84 114±4 112±1
      3 0.915 4 0.059 7±0.001 8 0.142 1±0.004 2 0.017 3±0.000 1 591±64 135±4 110±1
      4 0.645 2 0.054 6±0.001 1 0.152 6±0.003 3 0.020 3±0.000 1 396±43 144±3 129±1
      5 0.816 2 0.090 5±0.001 3 0.212 9±0.003 6 0.017 1±0.000 1 1436±28 196±3 109±1
      6 0.678 8 0.055 3±0.000 9 0.132 5±0.002 2 0.017 4±0.000 1 424±36 126±2 111±1
      7 0.489 3 0.049 4±0.001 7 0.120 7±0.004 2 0.017 7±0.000 1 165±80 116±4 113±1
      8 0.713 8 0.083 9±0.002 1 0.197 8±0.005 1 0.017 1±0.000 1 1 289±49 183±5 109±1
      9 0.849 2 0.212 6±0.001 5 0.502 8±0.007 4 0.017 2±0.000 2 2 925±11 414±6 110±1
      10 0.982 0 0.050 7±0.000 8 0.125 6±0.002 0 0.018 0±0.000 1 228±35 120±2 115±1
      11 0.832 3 0.048 4±0.001 1 0.118 7±0.002 7 0.017 8±0.000 1 117±52 114±3 114±1
      12 0.761 6 0.048 9±0.003 2 0.120 5±0.008 2 0.017 9±0.000 1 143±156 116±8 114±1
      13 0.529 6 0.055 2±0.001 3 0.153 5±0.003 7 0.020 2±0.000 1 419±54 145±3 129±1
      14 0.506 2 0.048 5±0.001 2 0.119 3±0.003 2 0.017 9±0.000 1 122±60 114±3 114±1
      15 0.494 8 0.087 0±0.001 6 0.204 0±0.003 9 0.017 0±0.000 1 1 361±36 189±4 109±1
      16 0.489 8 0.051 3±0.003 0 0.127 8±0.007 5 0.018 1±0.000 1 254±133 122±7 115±1
      17 0.945 9 0.051 9±0.001 9 0.123 0±0.005 5 0.017 2±0.000 1 283±82 118±5 110±1
      8 0.484 2 0.052 1±0.000 4 0.122 6±0.001 0 0.017 1±0.000 1 290±18 117±1 109±1
      19 0.550 2 0.049 0±0.002 6 0.118 5±0.006 4 0.017 6±0.000 1 146±126 114±6 112±1
      20 0.722 5 0.277 3±0.002 0 0.661 1±0.004 0 0.017 3±0.000 1 - 515±3 111±1
      21 0.730 2 0.049 2±0.000 7 0.120 4±0.001 7 0.017 8±0.000 1 156±31 115±2 113±1
      F02-b1
      1 0.455 0 0.047 1±0.002 9 0.112 3±0.006 8 0.017 3±0.000 1 54±145 108±7 111±1
      2 0.240 7 0.047 4±0.002 0 0.115 7±0.005 0 0.017 7±0.000 1 69±101 111±5 113±1
      3 0.895 9 0.050 4±0.002 0 0.119 0±0.004 7 0.017 1±0.000 1 213±90 114±4 109±1
      4 0.375 7 0.048 4±0.001 6 0.116 5±0.004 1 0.017 5±0.000 1 120±80 112±4 112±1
      5 0.578 6 0.089 0±0.002 0 0.184 1±0.004 3 0.015 0±0.000 1 1 405±44 172±4 96±1
      6 0.402 9 0.048 8±0.002 6 0.114 9±0.006 1 0.017 1±0.000 1 139±126 110±6 109±1
      7 0.544 5 0.047 5±0.001 1 0.113 9±0.002 6 0.017 4±0.000 1 75±54 110±3 111±1
      8 0.641 5 0.048 5±0.003 1 0.114 9±0.007 5 0.017 2±0.000 1 125±151 110±7 110±1
      9 0.480 8 0.047 8±0.001 4 0.113 5±0.003 3 0.017 2±0.000 1 91±68 109±3 110±1
      10 0.772 7 0.049 0±0.002 0 0.115 5±0.004 8 0.017 1±0.000 1 149±97 111±5 109±1
      11 0.507 2 0.048 5±0.002 3 0.114 9±0.017 2 0.017 2±0.000 5 122±110 110±17 110±3
      12 0.637 1 0.086 2±0.002 2 0.194 7±0.005 8 0.016 4±0.000 1 1 342±50 181±5 105±1
      13 0.412 6 0.050 1±0.002 1 0.118 1±0.005 2 0.017 1±0.000 1 198±98 113±5 109±1
      14 0.597 4 0.068 1±0.001 4 0.152 5±0.003 5 0.016 2±0.000 1 872±43 144±3 104±1
      15 0.538 0 0.049 2±0.001 6 0.113 6±0.003 9 0.016 7±0.000 1 159±76 109±4 107±1
      16 0.316 9 0.071 2±0.001 5 0.160 2±0.003 8 0.016 3±0.000 1 964±43 151±4 104±1
      17 0.487 8 0.053 4±0.001 4 0.120 4±0.003 4 0.016 3±0.000 1 346±60 115±3 105±1
      18 0.618 8 0.050 6±0.001 5 0.118 2±0.003 7 0.017 0±0.000 1 221±69 113±4 108±1
      19 0.062 8 0.049 4±0.003 8 0.117 6±0.009 4 0.017 3±0.000 1 166±181 113±9 110±1
      20 0.611 8 0.048 9±0.002 1 0.116 5±0.005 0 0.017 3±0.000 1 145±100 112±5 110±1
      21 2.517 5 0.372 3±0.006 6 0.889 3±0.019 7 0.017 3±0.000 1 3 801±27 646±14 111±1
      22 0.973 2 0.046 9±0.000 7 0.113 5±0.001 8 0.017 6±0.000 1 44±38 109±2 112±1
      23 0.675 4 0.048 6±0.002 9 0.111 5±0.007 0 0.016 7±0.000 1 128±140 107±7 106±1
      24 0.551 4 0.048 4±0.001 9 0.115 2±0.004 5 0.017 3±0.000 1 117±91 111±4 110±1
      25 0.761 3 0.080 5±0.001 8 0.217 0±0.005 1 0.019 6±0.000 1 1 208±44 199±5 125±1
      26 0.704 6 0.077 2±0.002 0 0.182 5±0.005 4 0.017 2±0.000 1 1 125±53 170±5 110±1
      27 0.477 4 0.048 5±0.001 8 0.112 7±0.004 3 0.016 9±0.000 1 123±89 108±4 108±1
      下载: 导出CSV

      表  2  矾山地区花岗岩及花岗闪长岩LA-MC-ICP MS锆石Lu-Hf同位素分析结果

      Table  2.   LA-ICP MS zircon Lu-Hf isopote analyses for granite and granodiorite from the Fanshan area

      样品 年龄(Ma) 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf 2σ εHf(0) εHf(t) TDM1(Ma) TDM2(Ma) fLu/Hf
      X01-b2
      1 111 0.027 015 0.001 061 0.282 643 0.000 010 -4.6 -2.2 864 1 306 -0.97
      2 112 0.037 299 0.001 560 0.282 662 0.000 010 -3.9 -1.5 847 1 265 -0.95
      3 110 0.039 347 0.001 595 0.282 595 0.000 012 -6.2 -3.9 944 1 416 -0.95
      5 109 0.023 133 0.000 975 0.282 579 0.000 014 -6.8 -4.5 951 1 450 -0.97
      6 111 0.040 227 0.001 624 0.282 519 0.000 014 -8.9 -6.6 1 054 1 586 -0.95
      8 109 0.032 508 0.001 402 0.282 679 0.000 009 -3.3 -1.0 820 1 228 -0.96
      9 110 0.063 931 0.002 630 0.282 537 0.000 011 -8.3 -6.1 1056 1 551 -0.92
      18 109 0.038 288 0.001 569 0.282 692 0.000 010 -2.8 -0.5 805 1 200 -0.95
      19 112 0.028 630 0.001 117 0.282 683 0.000 010 -3.1 -0.8 808 1 216 -0.97
      20 111 0.030 854 0.001 131 0.282 701 0.000 011 -2.5 -0.2 783 1 177 -0.97
      21 113 0.050 733 0.001 987 0.282 681 0.000 011 -3.2 -0.9 830 1 224 -0.94
      FS02-b1
      2 111 0.013 678 0.000 535 0.282 682 0.000 010 -3.2 -0.8 797 1 216 -0.98
      3 113 0.037 866 0.001 593 0.282 751 0.000 012 -0.7 1.6 722 1 066 -0.95
      4 109 0.039 804 0.001 554 0.282 678 0.000 009 -3.3 -1.0 825 1 232 -0.95
      7 109 0.017 343 0.000 777 0.282 624 0.000 009 -5.2 -2.9 884 1 350 -0.98
      8 111 0.030 083 0.001 207 0.282 721 0.000 013 -1.8 0.5 757 1 133 -0.96
      9 110 0.017 760 0.000 748 0.282 687 0.000 012 -3.0 -0.6 795 1 207 -0.98
      10 110 0.029 363 0.001 315 0.282 673 0.000 014 -3.5 -1.2 826 1 241 -0.96
      11 109 0.034 150 0.001 321 0.282 705 0.000 012 -2.4 -0.1 782 1 171 -0.96
      12 110 0.025 608 0.001 050 0.282 658 0.000 009 -4.0 -1.7 842 1 274 -0.97
      14 109 0.032 049 0.001 304 0.282 663 0.000 011 -3.9 -1.5 841 1 264 -0.96
      16 107 0.020 797 0.000 899 0.282 624 0.000 009 -5.2 -2.9 886 1 351 -0.97
      18 105 0.023 738 0.001 059 0.282 645 0.000 010 -4.5 -2.3 860 1 305 -0.97
      19 108 0.014 048 0.000 628 0.282 658 0.000 012 -4.0 -1.7 833 1 274 -0.98
      20 110 0.024 369 0.001 071 0.282 708 0.000 012 -2.3 0.1 772 1 161 -0.97
      21 110 0.021 229 0.000 950 0.282 664 0.000 013 -3.8 -1.5 832 1 260 -0.97
      23 112 0.040 189 0.001 738 0.282 617 0.000 013 -5.5 -3.1 916 1 366 -0.95
      24 106 0.035 257 0.001 510 0.282 640 0.000 014 -4.7 -2.5 879 1 319 -0.95
      25 110 0.022 432 0.000 938 0.282 695 0.000 011 -2.7 -0.4 788 1 191 -0.97
      27 108 0.025 462 0.001 128 0.282 666 0.000 010 -3.8 -1.5 833 1 258 -0.97
      下载: 导出CSV

      表  3  矾山地区花岗岩及花岗闪长岩主量元素分析结果(%)

      Table  3.   Major element analytical results of granite and granodiorite from the Fanshan area

      样品号 X01-b1 X01-b2 X02-b1 X03-b1 X04-b1 X05-b1 X05-b2 X05-b3 F01-b1 F02-b1 F03-b1 F04-b1 F05-b1 F06-b1 F07-b1
      SiO2 77.60 76.50 75.48 74.62 69.21 77.37 77.77 77.57 64.78 69.88 67.02 64.34 64.26 64.61 62.98
      TiO2 0.14 0.14 0.24 0.22 0.43 0.14 0.14 0.15 0.63 0.41 0.53 0.66 0.68 0.68 0.71
      Al2O3 12.33 12.18 12.74 13.44 14.83 12.60 12.38 12.46 16.47 14.31 15.19 15.25 16.15 15.20 15.78
      Fe2O3 0.33 0.67 1.32 0.90 1.97 0.87 0.77 0.80 3.22 2.05 1.90 2.78 3.17 2.89 2.81
      FeO 0.43 0.11 0.52 0.77 1.37 0.18 0.13 0.11 1.81 1.27 1.86 2.52 2.31 2.53 3.06
      MnO 0.03 0.03 0.08 0.07 0.12 0.05 0.02 0.04 0.13 0.06 0.06 0.10 0.08 0.10 0.12
      MgO 0.11 0.11 0.41 0.41 1.15 0.11 0.12 0.12 1.75 1.07 1.62 1.99 2.03 2.10 2.31
      CaO 0.40 0.42 1.23 1.34 2.85 0.27 0.28 0.36 3.32 2.85 3.19 4.28 3.59 4.29 4.44
      Na2O 3.19 3.03 3.41 3.70 3.55 3.24 3.02 2.97 2.57 3.06 3.84 3.18 2.92 2.95 3.05
      K2O 5.03 5.06 4.09 4.18 3.75 5.09 4.90 5.20 2.97 3.94 3.11 3.10 2.87 3.06 2.84
      P2O5 0.02 0.02 0.06 0.06 0.14 0.02 0.01 0.01 0.21 0.12 0.17 0.21 0.22 0.21 0.23
      LOI 0.65 0.72 0.69 0.68 1.29 0.70 0.77 0.74 1.90 0.81 1.30 1.36 1.56 1.14 1.43
      Total 100.26 98.99 100.27 100.39 100.66 100.64 100.31 100.53 99.77 99.81 99.78 99.78 99.82 99.77 99.75
      ALK 8.25 8.29 7.53 7.90 7.35 8.34 7.96 8.19 5.54 6.99 6.95 6.29 5.78 6.02 5.89
      A.R 3.01 2.85 2.91 3.01 2.34 3.03 2.82 2.73 1.78 2.11 2.44 1.97 1.84 1.87 1.86
      下载: 导出CSV

      表  4  矾山地区花岗岩及花岗闪长岩稀土、微量元素分析结果(10-6)

      Table  4.   REE and trace element analytical results of granite and granodiorite from the Fanshan area

      样品号 X01-b1 X01-b2 X02-b1 X03-b1 X04-b1 X05-b1 X05-b2 X05-b3 F01-b1 F02-b1 F03-b1 F04-b1 F05-b1 F06-b1 F07-b1
      La 46.18 63.68 41.65 43.06 28.70 40.29 56.94 44.96 41.39 48.56 31.56 33.70 33.34 29.99 31.39
      Ce 78.37 75.52 73.37 77.41 54.81 67.23 56.19 38.91 73.68 68.76 63.45 65.99 63.66 61.89 63.66
      Pr 9.61 14.28 8.32 8.72 6.12 8.10 11.66 10.07 9.83 10.52 7.24 7.82 8.55 7.60 7.72
      Nd 32.42 47.15 28.81 31.31 22.78 28.07 40.80 34.48 37.37 38.01 25.84 28.99 32.12 28.92 29.04
      Sm 5.55 8.33 5.22 6.03 4.43 5.06 7.12 5.96 6.94 7.12 4.75 5.52 6.26 5.58 5.52
      Eu 0.66 0.96 0.77 0.91 1.11 0.61 0.79 0.69 1.70 1.60 1.13 1.32 1.40 1.29 1.29
      Gd 4.60 6.44 4.93 6.59 4.05 4.65 5.93 4.60 6.55 7.07 4.20 5.28 6.01 4.98 4.93
      Tb 0.79 1.14 0.93 1.38 0.72 0.81 1.01 0.79 0.99 1.14 0.68 0.84 0.92 0.77 0.77
      Dy 4.40 5.95 5.63 9.14 4.06 4.59 5.34 4.15 6.03 7.20 4.14 5.28 5.75 4.63 4.70
      Ho 0.88 1.08 1.18 2.05 0.82 0.91 1.01 0.77 1.16 1.42 0.79 1.03 1.09 0.88 0.90
      Er 2.71 3.22 3.81 6.72 2.60 2.78 3.04 2.39 3.42 4.44 2.41 3.02 3.19 2.51 2.60
      Tm 0.47 0.53 0.68 1.20 0.44 0.47 0.50 0.40 0.58 0.78 0.42 0.51 0.55 0.42 0.44
      Yb 3.28 3.63 4.87 8.28 3.13 3.26 3.46 2.83 3.71 5.23 2.86 3.28 3.43 2.69 2.85
      Lu 0.45 0.47 0.60 0.94 0.40 0.46 0.50 0.41 0.61 0.92 0.49 0.56 0.55 0.43 0.45
      ∑REE 190.37 232.38 180.77 203.74 134.17 167.29 194.29 151.41 193.96 202.76 149.95 163.14 166.81 152.58 156.24
      L/H 9.83 9.35 6.99 4.61 7.27 8.33 8.35 8.27 7.42 6.19 8.38 7.24 6.76 7.81 7.86
      (La/Yb)N 10.10 12.58 6.13 3.73 6.58 8.87 11.80 1.21 8.90 8.75 8.27 8.54 9.14 9.46 9.53
      (La/Sm)N 5.37 4.94 5.15 4.61 4.18 5.14 5.16 1.88 4.93 4.87 4.86 4.83 4.86 4.94 4.91
      (Gd/Yb)N 1.16 1.47 0.84 0.66 1.07 1.18 1.42 0.56 1.14 1.14 1.10 1.13 1.19 1.21 1.21
      δEu 0.40 0.40 0.46 0.44 0.80 0.38 0.37 0.27 0.77 0.69 0.77 0.75 0.70 0.75 0.76
      Cs 2.33 2.09 2.46 2.36 2.95 2.86 3.08 3.20 3.49 5.31 2.26 3.09 3.42 1.72 1.82
      Rb 194.10 193.30 199.80 191.00 152.30 179.20 214.00 191.80 59.90 129.20 78.10 76.30 52.20 68.10 67.50
      Ba 437.70 443.20 578.20 649.70 711.10 508.50 662.60 589.40 701.10 605.40 674.90 642.10 698.90 766.30 682.70
      Th 20.30 22.52 25.30 21.74 14.81 21.29 25.13 23.21 17.72 25.14 21.21 17.50 15.16 13.64 14.31
      U 3.47 3.49 3.65 3.47 4.06 4.07 7.05 3.94 5.30 7.39 5.25 7.14 4.38 3.57 4.21
      Nb 6.50 9.49 8.69 6.49 3.67 6.39 7.06 6.28 9.10 11.40 10.90 8.70 8.90 9.50 9.10
      Ta 1.33 1.57 2.00 1.76 1.31 1.39 1.57 1.46 1.55 1.77 1.82 1.58 1.41 1.12 1.18
      Pb 18.89 16.10 23.67 24.21 27.01 19.86 25.03 17.37 11.44 16.05 28.32 17.43 28.18 13.15 19.03
      Sr 58.40 62.02 162.90 166.20 365.00 83.64 83.56 82.09 245.10 270.00 269.20 277.10 257.00 308.00 384.10
      Zr 92.00 86.45 117.19 118.91 136.30 87.16 86.54 94.31 82.30 101.80 89.70 91.80 87.30 107.10 128.00
      Hf 3.96 3.84 5.25 5.48 6.27 4.07 4.36 4.49 3.05 3.80 3.35 4.04 3.49 3.43 5.99
      Y 4.40 5.95 5.63 9.14 4.06 4.59 5.34 4.15 35.87 46.37 23.41 30.80 32.52 25.31 25.30
      Zr/Hf 23.23 22.49 22.34 21.70 21.74 21.42 19.87 21.01 26.97 26.77 26.78 22.70 25.02 31.19 21.35
      Nb/Ta 4.88 6.06 4.35 3.68 2.81 4.58 4.48 4.31 5.86 6.44 5.99 5.51 6.29 8.47 7.72
      Ba/Nb 67.30 46.72 66.55 100.08 193.90 79.58 93.92 93.91 77.04 53.11 61.92 73.80 78.53 80.66 75.02
      Nb/U 1.87 2.71 2.38 1.87 0.90 1.57 1.00 1.59 1.72 1.54 2.08 1.22 2.03 2.66 2.16
      Ba/La 9.48 6.96 13.88 15.09 24.78 12.62 11.64 13.11 16.94 12.47 21.38 19.05 20.96 25.55 21.75
      Ce/Pb 4.15 4.69 3.10 3.20 2.03 3.38 2.24 2.24 6.44 4.28 2.24 3.79 2.26 4.71 3.35
      Zr/Ba 0.21 0.20 0.20 0.18 0.19 0.17 0.13 0.16 0.12 0.17 0.13 0.14 0.12 0.14 0.19
      下载: 导出CSV
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    • 收稿日期:  2015-09-30
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