豫西火神庙岩体锆石U-Pb年代学、地球化学及Hf同位素组成

王赛; 叶会寿; 杨永强; 张兴康; 苏慧敏; 杨晨英

doi:10.3799/dqkx.2016.022

豫西火神庙岩体锆石U-Pb年代学、地球化学及Hf同位素组成

doi: 10.3799/dqkx.2016.022

1.
中国地质大学地球科学与资源学院，北京 100083
2.
中国地质科学院矿产资源研究所国土资源部成矿作用与资源评价重点实验室，北京 100037
3.
河北省地质调查院，河北石家庄 050081
4.
中国地质大学地球科学学院，湖北武汉 430074

基金项目:

国土资源部公益性行业基金项目 No.200911007-08

国家自然科学基金项目 No.41272104

国家科技支撑计划项目 No.2011BAB04B06

详细信息

作者简介:
王赛(1989-)，男，硕士研究生，主要从事斑岩-矽卡岩型钼矿床成矿理论方面的研究.E-mail: wangsainb@163.com

通讯作者:
叶会寿，E-mail: yehuishou@163.com

中图分类号: P581
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出版历程
- 收稿日期: 2015-07-21
- 刊出日期: 2016-02-15

Zircon U-Pb Chronology, Geochemistry and Hf Isotopic Compositions of the Huoshenmiao Pluton, Western Henan

1.
School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China
2.
MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, China Academy of Geological Sciences, Beijing 100037, China
3.
Hebei Institute of Geological Survey, Shijiazhuang 050081, China
4.
School of Earth Sciences, China University of Geosciences, Wuhan 430074, China

摘要

摘要: 火神庙岩体位于华北陆块南缘栾川矿集区西部，为一杂岩体，该岩体与火神庙钼矿床密切相关.目前，人们对火神庙岩体的研究程度较低，严重制约了对火神庙钼矿床成因的认识.系统开展了年代学、地球化学和Hf同位素组成研究.结果表明，石英闪长岩、二长花岗岩和花岗斑岩的形成年龄分别为150.3±0.6Ma、146.0±0.6Ma和145.1±0.5Ma，为栾川矿集区晚侏罗世第2次大规模岩浆活动的产物.火神庙杂岩体属于I型花岗岩，是不同源区部分熔融形成的岩浆上升就位的结果.石英闪长岩是富集岩石圈地幔部分熔融的产物；二长花岗岩和花岗斑岩是富集岩石圈地幔部分熔融形成的镁铁质岩浆与太华群TTG岩系部分熔融形成的长英质岩浆混合后上升就位的结果.
- 锆石U-Pb年代学 /
- 地球化学 /
- Hf同位素 /
- 火神庙岩体 /
- 豫西
Abstract: The Huoshenmiao pluton located in the west of the Luanchuan ore district, southern margin of the North China Craton (NCC) is mainly composed of quartz diorite, monzo-granite and granite porphyry. The Huoshenmiao pluton is closely related to the Huoshenmiao Mo deposit. While the degree of research on the Huoshenmiao pluton is very low, which seriously restrict the understanding of the genesis of the Huoshenmiao Mo deposit. Three types of rock including quartz diorite, monzo-granite and granite porphyry has been researched by zircon U-Pb chronology, geochemistry and Hf isotope. The forming ages of quartz diorite, monzo-granite and granite porphyry are 150.3±0.6Ma, 146.0±0.6Ma and 145.1±0.5Ma respectively, and are products of the second magmatism of the Luanchuan ore district, Late Jurassic. Geochemistry and zircon Hf isotope show that the Huoshenmiao pluton belongs to I-type granite, and it results from ascending magma formed by partial melting of different source regions. The quartz diorite stems from remelting of the enriched mantle, while the monzo-granite and granite porphyry are the products of mafic magma derived from remelting of the enriched mantle mixed with felsic magma derived from remelting of the Taihua TTG.
- zircon U-Pb chronology /
- geochemistry /
- Hf isotope /
- Huoshenmiao pluton /
- West Henan

HTML全文

图 1 栾川钼多金属矿集区地质简图

1.新元古界-早古生界陶湾群含砾灰岩、大理岩、千枚岩和石英岩；2.新元古界栾川群碎屑岩、碳酸盐岩和碱性火山岩；3.中元古界-新元古界宽坪群大理岩和基性火山岩；4.中元古界官道口群碎屑岩和含燧石条带大理岩；5.早白垩世花岗岩；6.晚侏罗世花岗斑岩；7.断裂；8.斑岩-矽卡岩型钼矿床；9.矽卡岩型多金属硫铁矿床；10.热液脉型铅锌银矿床；a.太行山断裂带；b.三门峡-宝丰断裂带；c.栾川断裂带；d.商丹断裂带；e.南漳断裂带；据叶会寿等(2006)修改

Fig. 1. Geological sketch of the Luanchuan ore district

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图 2 火神庙岩体地质简图

1.三川组大理岩；2.花岗斑岩；3.二长花岗岩；4.石英闪长岩；5.矽卡岩型钼矿体；6.年代学及Hf同位素分析样品及编号；7.地球化学分析样品及编号

Fig. 2. Geological sketch of the Huoshenmiao pluton

下载: 全尺寸图片幻灯片

图 3 火神庙岩体岩相学特征

a.石英闪长岩；b.石英闪长岩的中细粒粒状结构和斜长石聚片双晶；c.石英闪长岩中的斜长石环带结构；d.石英闪长岩中的角闪石简单双晶；e.二长花岗岩；f.二长花岗岩的中细粒粒状结构和斜长石聚片双晶；g.花岗斑岩；h.花岗斑岩的斑状结构；i.花岗斑岩中的石英发生溶蚀；Qz.石英；Pl.斜长石；Am.角闪石；Bi.黑云母；Kfs.钾长石

Fig. 3. Petrography of the Huoshenmiao pluton

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图 4 火神庙岩体锆石CL图像

小圈为U-Pb分析点，大圈为Hf同位素分析点，内部数字为分析点号，图像外部数字为U-Pb年龄(上方)和ε_Hf(t)值(下方)

Fig. 4. CL images of Zircons from the Huoshenmiao pluton

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图 5 火神庙岩体石英闪长岩(a)、花岗斑岩(b)和二长花岗岩(c)锆石U-Pb年龄谐和图及二长花岗岩锆石U-Pb年龄的Tera-Wasserburg图解(d)

Fig. 5. Zircon U-Pb concordia diagram for quartz diorite (a), granite porphyry (b) and monzo-granite(c) of the Huoshenmiao pluton and the Tera-Wasserburg plot for Monzo-granite (d)

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图 6 火神庙岩体A/CNK-A/NK图解(a)及SiO₂-K₂O图解(b)

据Peccerillo and Taylor(1976)和Rickwood(1989)

Fig. 6. SiO₂-K₂O diagrams (a) and A/CNK-A/NK (b) of the granites from the Huoshenmiao pluton

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图 7 火神庙岩体微量元素原始地幔标准化蛛网图和稀土元素球粒陨石标准化图

标准值据Sun and McDonough(1989)

Fig. 7. Primitive mantle normalized trace element spider diagrams and chondrite normalized REE patterns of the granites from the Huoshenmiao pluton

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图 8 火神庙岩体锆石Hf同位素组成ε_Hf(t)和两阶段模式年龄T_DM2柱状图

Fig. 8. Zircon Hf isotopic compositions and T_DM2 of the Huoshenmiao pluton

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图 9 火神庙岩体地球化学判别图解

Fig. 9. Geochemical discrimination diagrams for the Huoshenmiao pluton

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图 10 火神庙岩体岩浆形成温度判别图

据熊小林等(2011)

Fig. 10. The diagram of temperature of the Huoshenmiao pluton

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图 11 火神庙岩体岩浆形成压力判别图解

据熊小林等(2011)

Fig. 11. The diagram of pressure of the Huoshenmiao pluton

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表 1 火神庙岩体LA-MC-ICPMS错石U-Pb年龄测定结果

Table 1. LA-MC-ICPMS zircon U-Pb data of the Huoshenmiao pluton

样品号	Pb(10^-6)	U(10^-6)	²³²Th/²³⁸U	同位素比值						同位素年龄(Ma)
样品号	Pb(10^-6)	U(10^-6)	²³²Th/²³⁸U	²⁰⁷Pb/²⁰⁶Pb	1_σ	²⁰⁷Pb/²³⁵U	1_σ	²⁰⁶Pb/²³⁸U	1_σ	²⁰⁷Pb/²⁰⁶Pb	1_σ	²⁰⁷Pb/²³⁵U	1_σ	²⁰⁶Pb/²³⁸U	1_σ
B34HSM1	9	350	0.700	0.0496	0.0021	0.1625	0.0070	0.0237	0.0002	178	97	153	7	151	1
B34HSM2	9	346	0.750	0.0491	0.0020	0.1603	0.0067	0.0237	0.0002	154	96	151	6	151	1
B34HSM-3	15	575	1.020	0.0494	0.0016	0.1611	0.0054	0.0236	0.0002	168	77	152	5	151	1
B34HSM-4	12	471	0.850	0.0498	0.0032	0.1610	0.0102	0.0234	0.0002	188	148	152	10	149	2
B34HSM-5	11	436	0.800	0.0494	0.0025	0.1610	0.0084	0.0236	0.0002	168	119	152	8	151	1
B34HSM-6	8	324	0.850	0.0496	0.0059	0.1618	0.0194	0.0237	0.0003	176	277	152	18	151	2
B34HSM-7	11	433	0.750	0.0495	0.0019	0.1606	0.0067	0.0235	0.0002	170	90	151	6	150	2
B34HSM-8	12	460	0.980	0.0498	0.0014	0.1617	0.0046	0.0235	0.0002	187	64	152	4	150	1
B34HSM-9	11	443	0.720	0.0493	0.0013	0.1601	0.0043	0.0236	0.0002	162	61	151	4	150	1
B34HSM-10	6	245	0.710	0.0496	0.0022	0.1612	0.0071	0.0236	0.0002	178	101	152	7	150	1
B34HSM-11	8	333	0.660	0.0497	0.0024	0.1614	0.0079	0.0235	0.0002	183	112	152	7	150	1
B34HSM-12	11	435	0.700	0.0494	0.0013	0.1606	0.0044	0.0236	0.0002	168	62	151	4	150	1
B34HSM-13	11	419	0.670	0.0499	0.0015	0.1625	0.0051	0.0236	0.0002	191	70	153	5	150	2
B34HSM-14	10	363	0.750	0.0499	0.0013	0.1626	0.0044	0.0236	0.0002	191	61	153	4	151	1
B34HSM-15	13	488	0.940	0.0491	0.0013	0.1595	0.0044	0.0236	0.0002	152	62	150	4	150	1
B34HSM-16	13	512	0.860	0.0496	0.0015	0.1617	0.0055	0.0237	0.0003	174	71	152	5	151	2
B34HSM-17	10	395	0.640	0.0492	0.0020	0.1606	0.0069	0.0237	0.0002	159	97	151	6	151	1
B34HSM-18	7	296	0.580	0.0496	0.0018	0.1601	0.0060	0.0234	0.0002	177	85	151	6	149	1
B34HSM-19	11	427	0.660	0.0498	0.0015	0.1609	0.0050	0.0234	0.0002	186	70	151	5	149	1
B34HSM-20	6	230	0.540	0.0494	0.0024	0.1611	0.0080	0.0237	0.0002	167	115	152	8	151	1
B34HSM-21	11	454	0.730	0.0497	0.0014	0.1598	0.0047	0.0233	0.0002	183	67	151	4	148	1
B34HSM-22	11	453	0.730	0.0491	0.0013	0.1603	0.0043	0.0237	0.0002	154	62	151	4	151	1
B34HSM-23	10	418	0.680	0.0493	0.0013	0.1610	0.0044	0.0237	0.0002	161	61	152	4	151	1
B34HSM-24	8	321	0.620	0.0494	0.0018	0.1616	0.0061	0.0237	0.0002	169	87	152	6	151	1
B64jHSM-1	30	527	0.585	0.0962	0.0025	0.7521	0.0512	0.0567	0.0029	1551	48	569	39	356	18
B64jHSM-2	13	567	0.593	0.0541	0.0014	0.1705	0.0044	0.0229	0.0001	374	58	160	4	146	1
B64jHSM-3	11	446	0.937	0.0592	0.0013	0.1868	0.0042	0.0229	0.0001	573	48	174	4	146	1
B64jHSM-4	12	480	0.808	0.0502	0.0009	0.1586	0.0029	0.0229	0.0001	204	42	149	3	146	1
B64jHSM-5	11	460	0.883	0.0671	0.0028	0.2119	0.0089	0.0229	0.0002	841	86	195	8	146	1
B64jHSM-6	11	462	0.890	0.0616	0.0040	0.1950	0.0138	0.0229	0.0002	662	140	181	13	146	1
B64jHSM-7	11	420	1.037	0.0635	0.0011	0.2148	0.0040	0.0245	0.0001	725	37	198	4	156	1
B64jHSM-8	33	466	0.692	0.0935	0.0009	0.8627	0.0267	0.0669	0.0017	1497	18	632	20	418	11
B64jHSM-9	9	378	1.235	0.0544	0.0012	0.1725	0.0040	0.0230	0.0001	388	48	162	4	147	1
B64jHSM-10	13	551	0.640	0.0513	0.0007	0.1619	0.0022	0.0229	0.0001	253	31	152	2	146	1
B64jHSM-11	13	554	0.625	0.0517	0.0008	0.1630	0.0026	0.0229	0.0001	270	37	153	2	146	1
B64jHSM-12	9	338	1.428	0.0548	0.0007	0.1733	0.0022	0.0229	0.0001	403	28	162	2	146	1
B64jHSM-13	9	346	1.380	0.0751	0.0019	0.2370	0.0061	0.0229	0.0001	1071	52	216	6	146	1
B64jHSM-14	49	504	0.461	0.0866	0.0009	1.1371	0.0343	0.0953	0.0025	1351	20	771	23	587	15
B64jHSM-15	8	326	1.545	0.0494	0.0019	0.1561	0.0061	0.0229	0.0001	165	89	147	6	146	1
B64jHSM-16	9	393	0.317	0.0587	0.0012	0.1851	0.0039	0.0229	0.0001	554	43	172	4	146	1
B64jHSM-17	9	452	0.063	0.0583	0.0006	0.1820	0.0019	0.0226	0.0001	543	22	170	2	144	1
B64jHSM-18	14	573	0.581	0.0554	0.0010	0.1748	0.0033	0.0229	0.0001	429	40	164	3	146	1
B64jHSM-19	8	291	1.829	0.0531	0.0013	0.1673	0.0042	0.0229	0.0001	332	55	157	4	146	1
B64jHSM-20	14	585	0.557	0.0555	0.0009	0.1752	0.0030	0.0229	0.0001	433	37	164	3	146	1
B64jHSM-21	13	540	0.658	0.0547	0.0009	0.1724	0.0027	0.0229	0.0001	401	36	162	3	146	1
B64jHSM-22	9	367	1.309	0.0510	0.0011	0.1607	0.0034	0.0229	0.0001	241	48	151	3	146	1
B64jHSM-23	12	507	0.738	0.0577	0.0012	0.1824	0.0041	0.0229	0.0001	519	48	170	4	146	1
B64jHSM-24	10	396	1.142	0.0676	0.0012	0.2129	0.0041	0.0228	0.0001	857	36	196	4	146	1
B33HSM-1	7	246	2.300	0.0491	0.0021	0.1525	0.0067	0.0226	0.0001	150	102	144	6	144	1
B33HSM-2	3	115	1.440	0.0485	0.0093	0.1526	0.0289	0.0228	0.0002	122	450	144	27	146	2
B33HSM-3	16	626	1.730	0.0489	0.0007	0.1513	0.0020	0.0224	0.0001	144	32	143	2	143	1
B33HSM-4	4	164	1.700	0.0492	0.0019	0.1527	0.0060	0.0225	0.0001	158	92	144	6	144	1
B33HSM-5	10	416	1.420	0.0491	0.0009	0.1521	0.0029	0.0225	0.0001	152	44	144	3	143	1
B33HSM-6	10	386	1.740	0.0489	0.0009	0.1523	0.0028	0.0226	0.0001	145	42	144	3	144	1
B33HSM-7	9	318	2.420	0.0487	0.0013	0.1528	0.0039	0.0228	0.0001	134	61	144	4	145	1
B33HSM-8	29	1077	1.990	0.0489	0.0007	0.1544	0.0020	0.0229	0.0001	141	33	146	2	146	1
B33HSM-9	19	705	1.730	0.0492	0.0008	0.1533	0.0024	0.0226	0.0001	158	37	145	2	144	1
B33HSM-10	19	596	2.570	0.0488	0.0008	0.1533	0.0025	0.0228	0.0001	139	38	145	2	145	1
B33HSM-11	7	268	1.500	0.0491	0.0017	0.1547	0.0054	0.0229	0.0001	151	81	146	5	146	1
B33HSM-12	11	384	1.560	0.0489	0.0011	0.1544	0.0035	0.0229	0.0001	141	54	146	3	146	1
B33HSM-13	10	286	2.270	0.0486	0.0013	0.1538	0.0040	0.0229	0.0001	129	61	145	4	146	1
B33HSM-14	16	539	1.400	0.0489	0.0012	0.1543	0.0038	0.0229	0.0001	145	57	146	4	146	1
B33HSM-15	17	528	1.510	0.0480	0.0008	0.1520	0.0025	0.0230	0.0001	100	40	144	2	146	1
B33HSM-16	19	466	2.790	0.0488	0.0009	0.1544	0.0028	0.0230	0.0001	141	43	146	3	146	1
B33HSM-17	10	253	2.390	0.0488	0.0018	0.1551	0.0056	0.0230	0.0001	140	84	146	5	147	1
B33HSM-18	3	106	0.970	0.0489	0.0031	0.1537	0.0099	0.0228	0.0002	143	150	145	9	145	1
B33HSM-19	16	516	1.390	0.0488	0.0007	0.1534	0.0022	0.0228	0.0001	140	34	145	2	145	1
B33HSM-20	22	761	1.090	0.0489	0.0008	0.1546	0.0025	0.0229	0.0001	143	38	146	2	146	1
B33HSM-21	16	555	1.320	0.0485	0.0007	0.1523	0.0020	0.0228	0.0001	122	32	144	2	145	1
B33HSM-22	12	419	1.250	0.0490	0.0012	0.1537	0.0038	0.0227	0.0001	148	57	145	4	145	1
B33HSM-23	14	493	1.310	0.0494	0.0009	0.1540	0.0026	0.0226	0.0001	167	40	145	2	144	1
B33HSM-24	8	228	2.430	0.0488	0.0016	0.1522	0.0051	0.0226	0.0001	136	76	144	5	144	1
B33HSM-25	10	367	1.020	0.0491	0.0015	0.1549	0.0046	0.0229	0.0001	152	69	146	4	146	1
B33HSM-26	7	228	1.470	0.0488	0.0017	0.1541	0.0055	0.0229	0.0001	138	83	145	5	146	1

下载: 导出CSV

表 2 火神庙岩体主量(%)测定结果

Table 2. Major elements (%)data of the Huoshenmiao pluton

样品号	石英闪长岩				二长花岗岩				花岗斑岩
样品号	B1/HSM	B22/HSM	B24/HSM	B25/HSM	B6	B10	B19	B28	B9/HSM	B11/HSM	B33/HSM	B65/HSM
SiO₂	61.96	56.79	56.87	60.84	71.10	70.40	71.90	69.70	70.91	70.36	72.40	71.10
TiO₂	0.50	0.75	0.75	0.53	0.21	0.21	0.19	0.23	0.16	0.16	0.14	0.16
Al₂O₃	16.13	16.88	17.97	17.57	15.10	15.75	14.90	15.90	14.09	14.49	14.60	14.95
TFe₂O₃	4.15	8.02	6.62	5.16	0.97	0.91	1.32	1.39	1.12	1.17	1.31	1.26
MnO	0.13	0.18	0.13	0.11	0.04	0.03	0.03	0.04	0.08	0.13	0.09	0.07
MgO	1.49	2.73	2.33	1.83	0.16	0.15	0.17	0.19	0.17	0.16	0.18	0.19
CaO	4.44	5.75	5.71	4.58	1.05	1.44	1.00	1.57	1.62	1.70	0.96	1.59
Na₂O	4.56	3.88	4.18	4.12	3.62	3.94	3.49	3.53	3.05	3.82	4.20	3.66
K₂O	4.80	3.10	2.92	3.33	6.78	5.56	6.75	6.55	5.66	5.75	5.02	5.07
P₂O₅	0.28	0.61	0.58	0.35	0.08	0.09	0.07	0.08	0.04	0.04	0.02	0.03
LOI	0.95	1.20	1.04	0.91	0.82	0.50	0.67	0.73	2.00	1.67	0.35	1.31
TATAL	99.39	99.89	99.10	99.33	99.93	98.98	100.49	99.91	98.90	99.45	99.30	99.40
K₂O+Na₂O	9.36	6.98	7.10	7.45	10.40	9.50	10.24	10.08	8.71	9.57	9.22	8.73
K₂O/Na₂O	1.05	0.80	0.70	0.81	1.87	1.41	1.93	1.86	1.86	1.51	1.20	1.39
A/CNK	0.78	0.83	0.88	0.94	0.99	1.04	1.00	1.01	1.00	0.93	1.04	1.04
A/NK	1.27	1.73	1.79	1.69	1.13	1.26	1.14	1.23	1.26	1.16	1.18	1.30
σ	4.62	3.53	3.63	3.11	3.85	3.29	3.63	3.81	2.72	3.35	2.89	2.71
DI	76	59	60	67	93	90	93	90	90	91	92	89
Mg^#	46	44	45	45	28	28	23	24	26	24	24	26
T_zr	736	735	733	762	791	795	777	797	769	765	776	781
注：A/CNK=(Al₂O₃)/(CaO+K₂O+Na₂O)摩尔数分数比；A/NK=(Al₂O₃)/(K₂O+Na₂O)摩尔数分数比；里特曼指数δ=(K₂O+Na₂O)²/(SiO₂-43);Mg^#=100×(MgO/40.31)/(MgO/40.31+T_Fe₂O₃×0.8998/71.85×0.85)；全岩锆饱和温度T_Zr=12900/(lnD_Zr+0.85M+2.95)-273.15，D_Zr=49600/w(Zr)，M=(2Ca+K+Na)/(Si×Al)，w(Zr)为岩石中Zr的质量分数；熔体组成参数FM=(1/Si)[Na+K+2(Ca+Mg+Fe)]/Al.

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表 3 火神庙岩体微量和稀土元素(10^-6)测定结果

Table 3. Trace elements (10^-6) data of the Huoshenmiao pluton

样品号	石英闪长岩				二长花岗岩				花岗斑岩
样品号	B1/HSM	B22/HSM	B24/HSM	B25/HSM	B6	B10	B19	B28	B9/HSM	B11/HSM	B33/HSM	B65/HSM
Li	6.67	5.81	3.32	5.12	4.00	1.90	2.00	1.90	6.97	9.73	2.10	7.90
Be	2.15	1.82	2.65	1.68	2.82	2.45	1.71	2.23	4.00	2.21	2.69	2.72
Sc	12.45	9.24	5.93	8.59	1.80	1.70	1.70	1.70	2.83	2.05	1.40	1.60
V	140.1	145.0	78.5	87.3	18.0	13.0	15.0	9.0	12.0	8.7	5.0	7.0
Cr	6.30	9.45	8.72	7.57	1.00	1.00	2.00	1.00	5.43	3.52	1.47	3.66
Co	15.18	14.49	13.64	10.40	1.00	1.20	1.60	1.40	1.07	0.71	1.30	0.90
Ni	4.03	6.34	4.20	3.39	2.20	1.40	1.70	2.70	1.48	1.19	1.30	0.70
Cu	15.34	2.86	13.99	5.23	4.40	1.00	14.60	3.20	5.38	8.77	11.80	4.30
Zn	252.1	144.7	101.8	86.4	50.0	24.0	103.0	44.0	52.7	53.5	55.0	63.0
Ga	32.7	31.3	26.9	31.3	21.2	19.6	18.0	18.8	19.0	21.7	17.9	18.0
Rb	98	88	165	129	140	120	142	146	285	192	148	141
Sr	1377	1652	1062	1433	406	552	448	502	152	190	138	156
Y	20.4	18.9	16.2	20.6	17.0	13.7	12.2	14.4	13.9	13.6	15.2	12.1
Zr	176	154	177	177	187	185	156	201	238	151	168	180
Cd	0.86	0.77	0.47	0.61	0.19	0.11	0.26	0.17	0.27	0.26	0.21	0.26
In	0.09	0.07	0.09	0.07	0.07	0.06	0.05	0.07	0.04	0.03	0.04	0.03
Nb	31.2	28.8	33.2	32.8	39.7	34.4	28.1	39.4	50.5	33.1	37.9	35.6
Cs	4.43	5.09	3.80	4.73	2.38	1.87	1.58	1.83	1.93	1.26	1.22	1.19
Ba	2367	3108	3600	3155	2200	1980	1475	2050	1678	1537	512	823
La	76.4	62.2	53.4	72.0	22.7	23.9	26.6	16.1	50.5	49.5	39.0	47.7
Ce	149.6	116.2	97.8	132.2	64.3	57.4	53.6	40.4	87.7	82.9	70.2	86.0
Pr	16.12	11.96	9.06	12.64	7.23	7.45	6.35	5.81	7.73	7.37	7.78	9.61
Nd	52.8	45.2	31.6	45.5	24.2	25.1	21.2	21.7	24.9	23.5	25.4	29.1
Sm	9.28	8.17	5.41	7.76	3.97	3.75	3.27	3.94	4.29	3.95	4.04	4.16
Eu	2.19	2.17	1.48	1.89	0.90	1.00	0.93	1.13	0.78	0.77	0.81	0.84
Gd	6.90	5.86	3.99	5.75	2.88	2.81	2.64	2.80	3.11	2.98	3.35	3.32
Tb	0.87	0.73	0.50	0.74	0.46	0.43	0.39	0.44	0.44	0.41	0.52	0.52
Dy	4.64	3.91	2.81	4.10	2.68	2.40	2.11	2.65	2.69	2.46	3.36	2.90
Ho	0.88	0.72	0.55	0.80	0.53	0.51	0.43	0.56	0.56	0.51	0.64	0.61
Er	2.43	1.94	1.61	2.29	1.69	1.53	1.27	1.52	1.75	1.60	1.89	1.85
Tm	0.33	0.25	0.24	0.32	0.22	0.22	0.16	0.23	0.29	0.28	0.32	0.30
Yb	1.76	1.69	1.63	1.73	1.53	1.56	1.33	1.66	1.88	1.65	2.18	2.12
Lu	0.32	0.23	0.25	0.30	0.28	0.25	0.21	0.27	0.33	0.29	0.33	0.33
Hf	3.66	3.18	3.87	3.85	5.10	4.70	3.90	5.10	6.25	3.90	5.90	5.70
Ta	1.42	1.29	1.82	1.85	2.98	2.24	2.03	2.61	2.66	1.70	2.03	1.92
Pb	69.9	59.0	57.3	48.6	29.1	38.0	42.4	20.4	51.6	35.3	47.3	52.0
Bi	0.05	0.05	0.13	0.07	0.08	0.07	0.06	0.06	0.12	0.11	0.09	0.07
Th	13.3	11.3	18.0	18.1	24.8	20.9	17.1	20.6	24.9	23.5	24.5	23.8
U	3.12	2.44	3.85	3.63	2.28	1.31	2.43	1.33	5.28	4.18	4.94	5.21
∑REE	325	261	210	288	134	128	120	99	187	178	160	189
LREE	306	246	199	272	123	119	116	89	176	168	147	177
HREE	18.34	15.13	11.38	16.22	10.27	9.71	8.54	10.13	11.05	10.19	12.59	11.95
LREE/HREE	17	16	17	17	12	12	13	9	16	16	12	15
(La/Yb)_N	28	30	27	27	11	11	14	7	19	22	13	16
δEu	0.80	0.91	0.93	0.83	0.78	0.90	0.94	0.99	0.62	0.66	0.65	0.67
Sr/Y	66	68	87	70	24	40	37	35	11	14	9	13
Y/Yb	9.9	11.6	11.2	11.9	11.1	8.8	9.2	8.7	7.4	8.3	7.0	5.7
(Ho/Yb)_N	1.01	1.50	1.28	1.39	1.04	0.98	0.97	1.01	0.89	0.93	0.88	0.86
Nb/La	0.62	0.41	0.46	0.46	1.75	1.44	1.06	2.45	1.00	0.67	0.97	0.75
注：δEu=2Eu_N/(Sm_N+Gd_N).

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表 4 火神庙岩体的锆石Hf同位素分析结果

Table 4. Hf isotopic data of zircon from the Huoshenmiao pluton

测点号	年龄(Ma)	¹⁷⁶Yb/¹⁷⁷Hf	¹⁷⁶Lu/¹⁷⁷Hf	¹⁷⁶Hf/¹⁷⁷Hf	2σ	ε_Hf(0)	ε_Hf(t)	2σ	T_DM1(Ga)	T_DM2(Ga)	f_Lu/Hf
B34-HSM-1	151.2	0.018591	0.000844	0.282164	0.000020	-21.5	-18.3	0.7	1.53	2.36	-0.97
B34-HSM-2	150.8	0.020692	0.000938	0.282200	0.000018	-20.2	-17.0	0.6	1.48	2.28	-0.97
B34-HSM-3	150.7	0.024327	0.001090	0.282208	0.000021	-19.9	-16.7	0.8	1.47	2.26	-0.97
B34-HSM-4	149.3	0.019685	0.000886	0.282199	0.000017	-20.3	-17.1	0.6	1.48	2.28	-0.97
B34-HSM-5	150.6	0.024672	0.001110	0.282239	0.000017	-18.8	-15.6	0.6	1.43	2.19	-0.97
B34-HSM-6	150.8	0.021276	0.000977	0.282240	0.000017	-18.8	-15.6	0.6	1.43	2.19	-0.97
B34-HSM-7	150.0	0.024471	0.001076	0.282208	0.000020	-20.0	-16.8	0.7	1.48	2.26	-0.97
B34-HSM-8	150.0	0.017605	0.000783	0.282222	0.000018	-19.5	-16.3	0.6	1.44	2.23	-0.98
B34-HSM-9	150.1	0.024608	0.001104	0.282186	0.000020	-20.7	-17.5	0.7	1.51	2.31	-0.97
B34-HSM-10	150.1	0.014042	0.000641	0.282127	0.000019	-22.8	-19.6	0.7	1.57	2.44	-0.98
B34-HSM-11	150.0	0.018052	0.000807	0.282238	0.000018	-18.9	-15.7	0.6	1.42	2.20	-0.98
B34-HSM-12	150.1	0.021176	0.000970	0.282225	0.000020	-19.3	-16.2	0.7	1.45	2.22	-0.97
B34-HSM-13	150.4	0.022847	0.001042	0.282203	0.000018	-20.1	-16.9	0.6	1.48	2.27	-0.97
B34-HSM-14	150.5	0.021699	0.000963	0.282262	0.000018	-18.0	-14.8	0.7	1.39	2.14	-0.97
B34-HSM-15	150.1	0.030340	0.001324	0.282189	0.000022	-20.6	-17.5	0.8	1.51	2.31	-0.96
B34-HSM-16	150.8	0.028744	0.001169	0.282198	0.000020	-20.3	-17.1	0.7	1.49	2.28	-0.96
B34-HSM-17	150.7	0.017027	0.000727	0.282152	0.000020	-21.9	-18.7	0.7	1.54	2.38	-0.98
B34-HSM-18	149.1	0.020268	0.000897	0.282233	0.000019	-19.1	-15.9	0.7	1.43	2.21	-0.97
B34-HSM-19	149.3	0.020957	0.000929	0.282198	0.000019	-20.3	-17.1	0.7	1.48	2.28	-0.97
B34-HSM-20	150.7	0.017157	0.000768	0.282193	0.000020	-20.5	-17.2	0.7	1.48	2.29	-0.98
B64/HSM-2	145.8	0.062678	0.001776	0.282215	0.000019	-19.7	-16.7	0.7	1.49	2.25	-0.9
B64/HSM-3	146.0	0.086674	0.002499	0.282147	0.000015	-22.1	-19.1	0.5	1.62	2.41	-0.92
B64/HSM-4	146.1	0.086041	0.002449	0.282005	0.000017	-27.1	-24.2	0.6	1.82	2.72	-0.93
B64/HSM-5	146.0	0.075861	0.002098	0.282129	0.000018	-22.7	-19.7	0.6	1.63	2.45	-0.94
B64/HSM-6	146.2	0.068784	0.001907	0.282071	0.000016	-24.8	-21.8	0.6	1.70	2.58	-0.94
B64/HSM-9	146.6	0.078074	0.002465	0.282079	0.000017	-24.5	-21.6	0.6	1.72	2.56	-0.93
B64/HSM-10	146.0	0.081658	0.002413	0.282142	0.000018	-22.3	-19.3	0.6	1.62	2.42	-0.93
B64/HSM-11	145.9	0.103577	0.002919	0.282068	0.000015	-24.9	-22.0	0.5	1.76	2.59	-0.91
B64/HSM-12	146.2	0.093207	0.002458	0.282132	0.000019	-22.6	-19.7	0.7	1.64	2.44	-0.93
B64/HSM-13	145.9	0.082043	0.002161	0.282132	0.000019	-22.6	-19.7	0.7	1.63	2.44	-0.93
B64/HSM-15	146.2	0.077833	0.002103	0.282053	0.000017	-25.4	-22.4	0.6	1.74	2.62	-0.94
B64/HSM-16	145.9	0.086980	0.002270	0.282044	0.000020	-25.7	-22.8	0.7	1.76	2.64	-0.93
B64/HSM-18	145.9	0.070262	0.001851	0.282046	0.000017	-25.7	-22.7	0.6	1.74	2.63	-0.94
B64/HSM-19	145.8	0.082071	0.002452	0.282169	0.000022	-21.3	-18.4	0.8	1.59	2.36	-0.93
B64/HSM-20	145.9	0.106288	0.002679	0.282184	0.000017	-20.8	-17.9	0.6	1.58	2.33	-0.92
B64/HSM-21	145.7	0.080087	0.002110	0.282086	0.000015	-24.2	-21.3	0.5	1.69	2.54	-0.94
B64/HSM-22	145.7	0.059791	0.001771	0.282127	0.000015	-22.8	-19.8	0.5	1.62	2.45	-0.95
B64/HSM-23	146.1	0.071882	0.001942	0.282068	0.000016	-24.9	-21.9	0.6	1.71	2.58	-0.94
B64/HSM-24	145.6	0.073187	0.001883	0.282101	0.000015	-23.7	-20.7	0.5	1.66	2.51	-0.94
B33HSM-1	143.8	0.059567	0.002304	0.282063	0.000022	-25.1	-22.1	0.8	1.73	2.59	-0.93
B33HSM-2	145.6	0.051845	0.002094	0.282027	0.000019	-26.3	-23.3	0.7	1.77	2.67	-0.94
B33HSM-3	143.0	0.087118	0.003313	0.282110	0.000019	-23.4	-20.6	0.7	1.71	2.50	-0.90
B33HSM-4	143.5	0.057238	0.002296	0.281986	0.000020	-27.8	-24.9	0.7	1.84	2.77	-0.93
B33HSM-5	143.2	0.047320	0.001895	0.282005	0.000018	-27.1	-24.2	0.6	1.80	2.72	-0.94
B33HSM-6	143.9	0.055502	0.002218	0.282012	0.000018	-26.9	-23.9	0.6	1.80	2.71	-0.93
B33HSM-7	145.1	0.050196	0.002038	0.282026	0.000016	-26.4	-23.4	0.6	1.77	2.68	-0.94
B33HSM-8	146.1	0.045996	0.001832	0.282156	0.000020	-21.8	-18.8	0.7	1.58	2.38	-0.94
B33HSM-9	144.0	0.013993	0.000564	0.281782	0.000022	-35.0	-31.9	0.8	2.04	3.21	-0.98
B33HSM-10	145.1	0.050278	0.002057	0.282014	0.000018	-26.8	-23.8	0.6	1.79	2.70	-0.94
B33HSM-11	145.7	0.064744	0.002488	0.282112	0.000020	-23.3	-20.4	0.7	1.67	2.49	-0.93
B33HSM-12	146.1	0.082368	0.003161	0.282032	0.000021	-26.2	-23.3	0.7	1.82	2.67	-0.90
B33HSM-13	146.2	0.043282	0.001750	0.282080	0.000018	-24.5	-21.4	0.6	1.68	2.55	-0.95
B33HSM-14	145.7	0.056086	0.002168	0.282102	0.000022	-23.7	-20.7	0.8	1.67	2.51	-0.93
B33HSM-15	146.4	0.047132	0.001883	0.282026	0.000022	-26.4	-23.4	0.8	1.77	2.67	-0.94
B33HSM-16	146.4	0.041251	0.001646	0.282093	0.000020	-24.0	-21.0	0.7	1.66	2.52	-0.95
B33HSM-17	146.8	0.053522	0.002131	0.282018	0.000019	-26.7	-23.7	0.7	1.79	2.69	-0.94
B33HSM-18	145.3	0.049323	0.001949	0.282022	0.000017	-26.5	-23.5	0.6	1.77	2.68	-0.94
B33HSM-19	145.2	0.064493	0.002550	0.282027	0.000018	-26.3	-23.4	0.6	1.80	2.68	-0.92
B33HSM-20	146.2	0.040575	0.001599	0.282082	0.000023	-24.4	-21.4	0.8	1.67	2.55	-0.95
注：ε_Hf(t)={[(¹⁷⁶Hf/¹⁷⁷Hf)_s-(¹⁷⁶Lu/¹⁷⁷Hf)_s×(e^λt-1)]/[(¹⁷⁶Hf/¹⁷⁷Hf)_{CHUR, 0}-(¹⁷⁶Lu/¹⁷⁷Hf)_CHUR×(e^λt-1)]-1}×10000；T_DM1=1/λ×ln{1+ [(¹⁷⁶Hf/¹⁷⁷Hf)_s-(¹⁷⁶Hf/¹⁷⁷Hf)_DM]/[(¹⁷⁶Lu/¹⁷⁷Hf)_s-(¹⁷⁶Lu/¹⁷⁷Hf)_DM]}；T_DM2=1/λ×ln{1+[(¹⁷⁶Hf/¹⁷⁷Hf)_{s, t}-(¹⁷⁶Hf/¹⁷⁷Hf)_{DM, t}]/[(¹⁷⁶Lu/¹⁷⁷Hf)_C-(¹⁷⁶Lu/¹⁷⁷Hf)_DM]}+t；s=sample, (¹⁷⁶Hf/¹⁷⁷Hf)_{CHUR, 0}=0.282772，(¹⁷⁶Lu/¹⁷⁷Hf)_CHUR=0.0332，(¹⁷⁶Hf/¹⁷⁷Hf)_DM=0.28325，其中t=锆石结晶年龄，λ=1.867×10^-11a^-1，(¹⁷⁶Lu/¹⁷⁷Hf)_C=0.

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