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    西太平洋海山富钴结壳的稀土和铂族元素特征及其意义

    任江波 何高文 姚会强 张伙带 杨胜雄 邓希光 朱克超

    任江波, 何高文, 姚会强, 张伙带, 杨胜雄, 邓希光, 朱克超, 2016. 西太平洋海山富钴结壳的稀土和铂族元素特征及其意义. 地球科学, 41(10): 1745-1757. doi: 10.3799/dqkx.2016.503
    引用本文: 任江波, 何高文, 姚会强, 张伙带, 杨胜雄, 邓希光, 朱克超, 2016. 西太平洋海山富钴结壳的稀土和铂族元素特征及其意义. 地球科学, 41(10): 1745-1757. doi: 10.3799/dqkx.2016.503
    Ren Jiangbo, He Gaowen, Yao Huiqiang, Zhang Huodai, Yang Shengxiong, Deng Xiguang, Zhu Kechao, 2016. Geochemistry and Significance of REE and PGE of the Cobalt-Rich Crusts from West Pacific Ocean Seamounts. Earth Science, 41(10): 1745-1757. doi: 10.3799/dqkx.2016.503
    Citation: Ren Jiangbo, He Gaowen, Yao Huiqiang, Zhang Huodai, Yang Shengxiong, Deng Xiguang, Zhu Kechao, 2016. Geochemistry and Significance of REE and PGE of the Cobalt-Rich Crusts from West Pacific Ocean Seamounts. Earth Science, 41(10): 1745-1757. doi: 10.3799/dqkx.2016.503

    西太平洋海山富钴结壳的稀土和铂族元素特征及其意义

    doi: 10.3799/dqkx.2016.503
    基金项目: 

    国家自然科学基金项目 No.91428207

    国际海域资源调查与开发“十二五”课题项目 Nos.DY125-13-R-01

    国土资源部海底矿产资源重点实验室开放基金课题项目 No.KLMMR-2013-A-05

    国际海域资源调查与开发“十二五”课题项目 DY125-13-R-05

    国际海域资源调查与开发“十二五”课题项目 DY125-13-R-08

    国际海域资源调查与开发“十二五”课题项目 DY125-13-R-09

    详细信息
      作者简介:

      任江波 (1985-),男,工程师,硕士,主要从事地球化学和海洋地质工作和研究

    • 中图分类号: P736.4

    Geochemistry and Significance of REE and PGE of the Cobalt-Rich Crusts from West Pacific Ocean Seamounts

    • 摘要: 为了探讨富钴结壳的稀土和铂族元素是否有相似的形成机制,对西太平洋海山富钴结壳稀土和铂族元素进行了类比研究.结果表明:富钴结壳的∑REY范围为1 433.7×10-6~2 888.0×10-6,其中Ce占到近50%,北美页岩标准化后显示较平坦的稀土模式和显著的Ce正异常特征.根据稀土配分模式及已有的Nd同位素结果,富钴结壳具有亲陆壳属性.富钴结壳具有极高的Pt (115.5×10-9~1 132.0×10-9)、(Pt/Pd)N和 (Pt/Os)N值,Ir与Pt及Rh与Pt显示良好相关性.经球粒陨石标准化后显示较一致PGE (platinum-group elements) 配分模式,从Os到Pt逐渐富集,Pd元素强烈亏损.已有的Os同位素研究结果显示物源在地质历史时期从幔源属性向陆源属性变化,但富钴结壳PGE元素内部相对含量仍在一定程度上保持稳定.研究认为:富钴结壳对海水中的稀土清扫具有选择性,Ce的正异常恰恰是结壳对海水稀土中Ce的优先选择造成的,从而导致海水亏损Ce.然而海水中Ce的亏损并未改变新形成富钴结壳的稀土模式,原因是在海洋中存在适量的具有亏损Ce特征的磷酸盐等组分,理论上只需要氧化物类稀土与磷酸盐类稀土消耗的稀土与海水中的补给平衡即可.只是在相关过程中,海洋中氧化物类对稀土的选择更具有主动性,而磷酸盐类表现更多的继承关系.尽管Os同位素显示物源供给发生变化,然而富钴结壳PGE模式相对稳定.因此富钴结壳PGE模式同样可以用富钴结壳对PGE的选择性吸收解释,因富钴结壳优先选择Pt与Ir以及相对排斥Pd和Os,形成了现有独特的PGE模式.

       

    • 图  1  西太平洋海山位置及其时代

      洋壳年代据Müller et al.(2008);海山年代据Koppers et al.(2003)、Koppers and Staudigel(2005)

      Fig.  1.  Location and age of seamounts in western Pacific Ocean

      图  2  富钴结壳成因判别

      底图据Halbach et al.(1981);西太平洋富钴结壳和COMRA结核据何高文 (2006)

      Fig.  2.  Fe-Mn-10(Ni+Cu) and Fe-Mn-100Co triangular diagrams of Fe-Mn crust genesis

      图  3  结壳中REE、PGE与其他元素关系

      其他数据任向文 (2005)和卜文瑞

      Fig.  3.  Plots of REE and PGE vs. other elements of cobalt-rich Fe-Mn crust

      图  4  富钴结壳的稀土元素球粒陨石标准化图 (a) 和北美页岩标准化图 (b)

      海水数据据Alibo and Nozaki (1999);北美页岩数据据Gromet et al.(1984);N-MORB、OIB和球粒陨石数据据Sun and McDonough

      Fig.  4.  Chondrite-normalized (a) and NASC-normalized (b) REE patterns of cobalt-rich Fe-Mn crust

      图  5  富钴结壳的铂族元素球粒陨石标准化

      球粒陨石数据据Sun and McDonough (1989);陆壳数据据Wedepohl (1995);海水数据据Nozak

      Fig.  5.  Chondrite-normalized PGE patterns of cobalt-rich Fe-Mn crust

      图  6  地质历史时期太平洋海水的Nd同位素特征 (a) 和Os同位素特征 (b)

      εNd(0) 图展示近赤道太平洋不同水深富钴结壳的Nd同位素特征,据Van De Flierdt et al.(2004)修改;187Os/188Os图中样品为富金属沉积物,据Klemm et al.(2005)修改

      Fig.  6.  Nd (a) and Os (b) isotope time-series of Pacific Ocean seawater

      图  7  海水稀土的补给与消耗示意

      Fig.  7.  Sketch map of supply and consume of seawater REE

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