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    豫南新县岩体地球化学、年代学和Hf同位素特征及地质意义

    刘清泉 邵拥军 陈昕梦 刘忠法 张喆

    刘清泉, 邵拥军, 陈昕梦, 刘忠法, 张喆, 2016. 豫南新县岩体地球化学、年代学和Hf同位素特征及地质意义. 地球科学, 41(8): 1275-1294. doi: 10.3799/dqkx.2016.507
    引用本文: 刘清泉, 邵拥军, 陈昕梦, 刘忠法, 张喆, 2016. 豫南新县岩体地球化学、年代学和Hf同位素特征及地质意义. 地球科学, 41(8): 1275-1294. doi: 10.3799/dqkx.2016.507
    Liu Qingquan, Shao Yongjun, Chen Xinmeng, Liu Zhongfa, Zhang Zhe, 2016. Petrogeochemistry, Geochronology and Hf Isotopes of the Monzogranite from Xinxian, Southern Region in Henan Province. Earth Science, 41(8): 1275-1294. doi: 10.3799/dqkx.2016.507
    Citation: Liu Qingquan, Shao Yongjun, Chen Xinmeng, Liu Zhongfa, Zhang Zhe, 2016. Petrogeochemistry, Geochronology and Hf Isotopes of the Monzogranite from Xinxian, Southern Region in Henan Province. Earth Science, 41(8): 1275-1294. doi: 10.3799/dqkx.2016.507

    豫南新县岩体地球化学、年代学和Hf同位素特征及地质意义

    doi: 10.3799/dqkx.2016.507
    基金项目: 

    中国地质调查局地质矿产调查评价专项 12120113091200

    中南大学创新驱动计划项目 2015CX008

    详细信息
      作者简介:

      刘清泉(1982-),男,博士研究生,矿产普查与勘探专业.E-mail: liu_qingquan@126.com

      通讯作者:

      邵拥军,E-mail: shaoyongjun@126.com

    • 中图分类号: P618

    Petrogeochemistry, Geochronology and Hf Isotopes of the Monzogranite from Xinxian, Southern Region in Henan Province

    • 摘要: 新县岩体位于秦岭-大别造山带上,对其进行系统的岩石地球化学探讨有助于加深对秦岭-大别造山带中生代构造-岩浆演化及地球动力学背景的认识.岩石地球化学分析结果显示,SiO2含量为74.94%~78.16%,K2O含量为3.87%~5.86%,Na2O含量为3.82%~4.24%,Al2O3含量为12.38%~13.57%,具有高钾钙碱性和过铝质(A/CNK=1.05~1.11) 特征.岩石稀土总量较低(42.67×10-6~110.45×10-6),轻稀土元素相对富集,重稀土元素相对亏损,具有Eu的负异常,岩体富集Rb、U、Hf和Y,亏损Ba、Nb、Ta和Ti,显示出Ⅰ型高分异花岗岩的特点.3个期次岩石的U-Pb年龄分别为153.4±1.1 Ma、146.4±1.6 Ma和131.6±1.8 Ma.锆石Hf同位素分析结果表明,新县岩体的εHf(t)值为-24.5~-20.3,位于地幔演化线之下,tDM2值为2.68~2.93 Ga,指示其源于扬子板块北缘的古老地壳,其组成类似于扬子板块北缘TTG型岩浆岩.结合区域地质背景,新县岩体形成于扬子陆块与华北陆块碰撞造山后的陆内伸展环境,对应的地球动力学背景为晚侏罗世-早白垩世地壳从挤压收缩向区域性伸展的构造体制大转换过程和大规模的地壳伸展和岩石圈减薄时期.

       

    • 图  1  新县花岗岩体地质简图

      1.第四系;2.白垩系下统陈棚组;3.泥盆系南湾组;4.震旦系-奥陶系肖家庙组;5.中元古界浒湾组上段;6.中元古界浒湾组下段;7.下元古界七角山组;8.下元古界新县组;9.下元古界卡房组;10.辉长岩;11.震旦系花岗岩;12.燕山期石英二长岩;13.燕山期花岗斑岩;14.燕山期二长花岗岩;15.断层;16.地质界线;17.花岗斑岩脉;18.采样位置;据陈伟等(2013)修改

      Fig.  1.  Geological sketch of the Xinxian granitic batholith in Henan Province

      图  2  二长花岗岩岩相学特征

      a.中粗粒二长花岗岩;b.中粒二长花岗岩;c.细粒二长花岗岩;d.中粗粒二长花岗岩结构;e.中粒二长花岗岩结构;f.细粒二长花岗岩结构.Qtz.石英;Bt.黑云母;Pth.条纹长石;Pl.斜长石;Kfs.钾长石

      Fig.  2.  Petrography of the monzogranite

      图  3  新县二长花岗岩中锆石代表性阴极发光照片(a);中粗粒二长花岗岩(X-01) 锆石U-Pb谐和图(b);中粒二长花岗岩(X-03) 锆石U-Pb谐和图(c)和细粒二长花岗岩(X-05) 锆石U-Pb谐和图(d)

      Fig.  3.  CL images of representative zircons in the Xinxian monzogranite with analytical positions (a), the zircon U-Pb concordian of the medium-coarse monzogranite (X-01) (b), the zircon U-Pb concordian of the medium monzogranite (X-03) (c) and the zircon U-Pb concordian of the fine monzogranite (X-05) (d)

      图  4  新县二长花岗岩K2O-SiO2(a)和ANK-ACNK(b)关系

      图a据Rickwood(1989)

      Fig.  4.  K2O-SiO2 (a) and ANK-ACNK (b) relations of the Xinxian monzogranite

      图  5  新县二长花岗岩Harker图解

      Fig.  5.  Harker diagram of the Xinxian monzogranite

      图  6  新县二长花岗岩原始地幔标准化微量元素蛛网图(a)与球粒陨石标准化稀土元素分布模式(b)

      Fig.  6.  PM-normalised trace element spider diagram (a) and chondrite-normalised REE pattern (b) of the Xinxian monzogranite

      图  7  新县二长花岗岩Q-A-P图解

      Q.石英;A.碱性长石;P.斜长石;据Bowden and Kinnaird(1984)

      Fig.  7.  Q-A-P diagram of the Xinxian monzogranite

      图  8  (Na2O+K2O)/CaO-Zr+Nb+Ce+Y和(Al2O3+CaO)/(Na2O+K2O+TFeO)-100×(TFeO+MgO+TiO2)/SiO2关系

      图a据Whalen et al.(1987),图b据Sylvester(1989)

      Fig.  8.  (Na2O+K2O)/CaO-Zr+Nb+Ce+Y and (Al2O3+CaO)/(Na2O+K2O+TFeO)-100×(TFeO+MgO+TiO2)/SiO2 relations

      图  9  新县二长花岗岩REE分布模式(a)及Sr-Yb关系(b)

      张旗等(2006)

      Fig.  9.  REE pattern (a) and Sr-Yb relation (b) for the Xinxian monzogranite

      图  10  新县二长花岗岩造岩矿物结晶分异判别关系

      PlAn50.斜长石(An=50);PlAn15.斜长石(An=15);Kfs.钾长石;Bt.黑云母;Ms.白云母;Grt.石榴子石;Amp.角闪石;据Janoušek et al.(2004)

      Fig.  10.  Ba-Sr and Rb-Sr relations for the Xinxian monzogranite

      图  11  新县二长花岗岩锆石εHf(t)-t关系

      Fig.  11.  Relation of Zircon εHf(t) and t for the Xinxian monzogranite

      图  12  新县二长花岗岩构造环境判别关系

      a.Al2O3-SiO2;b.TFeO/(TFeO+MgO)-SiO2;c.R1-R2;d.Rb-Y+Nb;图a, b据Pearce(1996);图c, d据Batchelor and Bowden(1985);POG.后造山花岗岩;IAG.岛弧花岗岩;CAG.大陆弧花岗岩;CCG.大陆碰撞花岗岩;RRG.裂谷型花岗岩;CEUG.大陆造陆隆升花岗岩

      Fig.  12.  Discriminant relations of tectonic environment of the Xinxian monzogranite

      图  13  新县二长花岗岩构造环境的lg(CaO/(K2O+Na2O))-SiO2判别关系

      Brown(1982)修改

      Fig.  13.  The lg(CaO/(K2O+Na2O))-SiO2 discriminant relation of tectonic environment of the Xinxian monzogranite

      表  1  新县二长花岗岩LA-ICP-MS锆石U-Pb分析结果

      Table  1.   LA-ICP-MS zircon U-Pb data for the Xinxian monzogranite

      测试点号 Th
      (10-6)
      U
      (10-6)
      Th/U 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 208Pb/232Th 1σ 年龄(Ma)
      207Pb/235U 1σ 206Pb/238U 1σ 208Pb/232U 1σ
      X-01-01 2 542 2 136 1.19 0.055 1 0.001 0 0.155 5 0.003 1 0.020 4 0.000 3 0.006 0 0.000 1 147 3 130 2 121 3
      X-01-02 3 205 2 343 1.37 0.047 1 0.000 9 0.135 9 0.002 8 0.020 8 0.000 2 0.006 3 0.000 1 129 3 132 2 126 3
      X-01-03 2 839 2 259 1.26 0.052 1 0.001 1 0.148 6 0.003 4 0.020 5 0.000 2 0.006 3 0.000 2 141 3 131 2 127 3
      X-01-06 182 152 1.20 0.051 4 0.003 5 0.146 3 0.008 8 0.021 6 0.000 5 0.006 4 0.000 2 139 8 138 3 128 5
      X-01-07 3 170 2 295 1.38 0.050 9 0.001 0 0.141 1 0.002 7 0.020 0 0.000 2 0.006 3 0.000 1 134 2 128 1 126 3
      X-01-08 357 292 1.22 0.057 2 0.003 7 0.174 0 0.013 0 0.021 3 0.000 4 0.007 5 0.000 3 163 11 136 2 152 7
      X-01-09 3 580 2 777 1.29 0.049 4 0.001 0 0.139 2 0.002 9 0.020 3 0.000 2 0.006 4 0.000 2 132 3 130 2 129 3
      X-01-10 4 873 2 774 1.76 0.050 3 0.001 2 0.145 5 0.003 7 0.020 9 0.000 3 0.006 9 0.000 2 138 3 133 2 139 4
      X-01-11 2 791 2 250 1.24 0.048 9 0.001 1 0.139 1 0.003 5 0.020 5 0.000 3 0.006 8 0.000 2 132 3 131 2 137 4
      X-01-12 5 125 2 790 1.84 0.047 9 0.000 9 0.134 5 0.002 8 0.020 3 0.000 2 0.006 7 0.000 1 128 2 129 1 134 3
      X-01-14 2 406 2 374 1.01 0.054 0 0.001 2 0.160 5 0.004 5 0.021 3 0.000 3 0.006 8 0.000 2 151 4 136 2 136 3
      X-03-01 3 590 5 224 0.69 0.057 0 0.001 1 0.180 2 0.003 4 0.022 7 0.000 2 0.006 9 0.000 2 168 3 144 1 140 3
      X-03-02 3 724 6 079 0.61 0.051 0 0.000 9 0.159 4 0.003 1 0.022 4 0.000 2 0.006 7 0.000 2 150 3 143 1 134 3
      X-03-03 2 650 3 437 0.77 0.054 1 0.001 1 0.172 5 0.004 8 0.022 8 0.000 4 0.007 3 0.000 2 162 4 145 3 147 4
      X-03-04 2 694 4 649 0.58 0.079 6 0.002 2 0.235 5 0.006 8 0.021 2 0.000 2 0.008 3 0.000 3 215 6 135 2 166 7
      X-03-06 655 1 064 0.62 0.053 1 0.002 0 0.168 3 0.005 7 0.023 1 0.000 3 0.007 6 0.000 2 158 5 147 2 153 4
      X-03-07 2 914 4 189 0.70 0.056 8 0.001 4 0.180 5 0.004 5 0.022 9 0.000 3 0.006 9 0.000 2 168 4 146 2 139 4
      X-03-08 4 121 5 773 0.71 0.054 3 0.001 0 0.171 7 0.004 0 0.022 7 0.000 3 0.007 2 0.000 2 161 4 144 2 145 4
      X-03-10 4 225 4 888 0.86 0.081 2 0.002 1 0.239 2 0.007 0 0.021 1 0.000 3 0.008 2 0.000 2 218 6 134 2 165 4
      X-03-12 4 157 5 321 0.78 0.061 4 0.002 2 0.179 8 0.005 7 0.021 4 0.000 3 0.007 6 0.000 2 168 5 137 2 153 4
      X-03-13 5 917 6 992 0.85 0.047 8 0.000 8 0.154 0 0.003 0 0.023 2 0.000 3 0.007 1 0.000 2 145 3 148 2 144 4
      X-03-14 4 375 4 597 0.95 0.060 0 0.001 2 0.187 4 0.004 5 0.022 5 0.000 3 0.007 4 0.000 2 174 4 143 2 148 3
      X-03-15 2 048 4 056 0.50 0.053 9 0.001 2 0.165 3 0.004 3 0.022 0 0.000 3 0.007 9 0.000 2 155 4 140 2 159 5
      X-05-01 4 557 14 296 0.32 0.051 4 0.000 8 0.173 1 0.002 9 0.024 1 0.000 2 0.006 8 0.000 3 162 3 153 1 138 6
      X-05-02 3 687 4 629 0.80 0.090 4 0.002 0 0.303 4 0.008 3 0.023 9 0.000 3 0.009 4 0.000 5 269 6 152 2 189 9
      X-05-03 1 922 3 688 0.52 0.083 4 0.003 3 0.278 7 0.003 1 0.024 3 0.001 0 0.011 7 0.000 8 250 10 155 6 235 17
      X-05-04 9 506 17 079 0.56 0.053 3 0.001 0 0.178 6 0.004 1 0.023 9 0.000 2 0.007 2 0.000 3 167 4 152 1 145 6
      X-05-05 7 929 22 043 0.36 0.068 1 0.003 0 0.238 3 0.004 4 0.024 2 0.000 3 0.010 1 0.000 6 217 12 154 2 203 12
      X-05-07 3 471 13 938 0.25 0.053 6 0.001 0 0.176 5 0.003 1 0.023 8 0.000 3 0.007 5 0.000 2 165 3 152 2 152 4
      X-05-08 2 275 6 130 0.37 0.0902 0.001 6 0.305 1 0.006 4 0.024 4 0.000 3 0.013 3 0.000 4 270 5 155 2 267 7
      X-05-09 6 837 20 129 0.34 0.054 5 0.000 7 0.183 2 0.003 0 0.024 2 0.000 3 0.010 5 0.000 2 171 3 154 2 211 5
      X-05-10 6 592 21 885 0.30 0.091 1 0.003 0 0.307 5 0.001 6 0.024 3 0.000 4 0.017 5 0.000 9 272 9 155 2 350 19
      X-05-11 7 229 19 846 0.36 0.048 4 0.000 8 0.160 8 0.003 6 0.023 9 0.000 3 0.007 9 0.000 2 151 3 152 2 159 5
      X-05-12 7 081 24 836 0.29 0.059 0 0.001 8 0.197 7 0.006 8 0.024 0 0.000 3 0.010 7 0.000 5 183 6 153 2 215 11
      X-05-13 5 247 15 865 0.33 0.052 8 0.001 1 0.178 3 0.003 7 0.024 4 0.000 3 0.007 8 0.000 2 167 3 155 2 156 4
      X-05-14 13 518 31 847 0.42 0.045 9 0.001 1 0.152 3 0.003 6 0.023 9 0.000 2 0.006 7 0.000 2 144 3 152 2 134 5
      下载: 导出CSV

      表  2  新县二长花岗岩主量元素(%)、微量和稀土元素(10-6)分析结果

      Table  2.   Major elements (%), trace elements and rare earth elements (10-6) composition of Xinxian monzogranite

      样品号 X-01 X-02 X-03 X-04 X-05 X-06
      SiO2 78.16 77.32 75.7575.24 75.62 74.94
      Al2O3 12.38 12.38 13.57 13.54 13.33 13.52
      Fe2O3 0.62 0.66 0.78 0.95 1.09 1.06
      MgO 0.06 0.05 0.09 0.10 0.08 0.11
      CaO 0.27 0.24 0.50 0.58 0.36 0.39
      Na2O 3.82 3.94 4.24 4.24 3.83 4.07
      K2O 4.16 3.87 4.50 4.45 4.86 4.65
      MnO 0.01 0.01 0.04 0.06 0.02 0.02
      TiO2 0.04 0.03 0.08 0.05 0.09 0.10
      P2O5 0.006 0.006 0.011 0.010 0.008 0.009
      LOI 0.45 0.54 0.35 0.27 0.55 0.65
      Total 99.98 99.05 99.91 99.49 99.84 99.52
      TFeO 0.62 0.66 0.78 0.95 1.09 1.06
      A/CNK 1.10 1.11 1.06 1.05 1.09 1.09
      A/NK 1.15 1.16 1.15 1.15 1.15 1.15
      Mg# 16.09 13.05 18.60 17.25 12.69 17.05
      R1 2 874 2 872 2 478 2 460 2 530 2 459
      R2 276 275 326 335 306 316
      Q 39.43 39.46 32.68 32.20 33.92 32.68
      An 1.31 1.17 2.42 2.84 1.75 1.90
      Ab 32.49 33.86 36.05 36.18 32.66 34.85
      Or 24.71 23.23 26.72 26.52 28.94 27.81
      Rb 393.0 365.0 311.0 307.0 216.0 196.5
      Ba 40 30 120 130 260 250
      Th 20 20 30 20 20 20
      U 10 10 10 10 10 10
      Nb 41.3 37.5 33.3 25.8 22.6 23.1
      Ta 4.8 4.3 2.8 2.1 1.8 1.9
      Pb 42 40 39 39 25 29
      Sr 11 11 42 44 49 49
      Zr 112 134 141 120 140 127
      Hf 5.9 8.0 6.2 4.7 5.0 4.8
      Ti 240 180 480 300 540 600
      Y 13.4 16.0 10.1 8.8 12.8 11.7
      Nb/Ta 8.60 8.72 11.89 12.29 12.56 12.16
      Zr/Hf 18.98 16.75 22.74 25.53 28.00 26.46
      La 8.9 12.1 21.6 15.4 24.8 28.5
      Ce 18.9 26.1 38.2 26.7 44.4 51.0
      Pr 2.05 2.77 3.53 2.51 4.67 5.13
      Nd 6.1 8.9 10.5 7.4 14.6 15.7
      Sm 1.23 1.75 1.58 1.08 2.24 2.84
      Eu 0.05 0.07 0.17 0.15 0.31 0.32
      Gd 0.95 1.23 0.93 0.76 1.67 1.80
      Tb 0.16 0.21 0.17 0.12 0.28 0.26
      Dy 1.21 1.45 0.97 0.85 1.76 1.77
      Ho 0.25 0.33 0.22 0.18 0.36 0.36
      Er 0.93 1.11 0.88 0.62 1.22 0.96
      Tm 0.18 0.20 0.13 0.11 0.20 0.17
      Yb 1.54 1.81 1.17 0.90 1.35 1.48
      Lu 0.22 0.27 0.18 0.12 0.18 0.16
      ∑REE 42.67 58.30 80.23 56.90 98.04 110.45
      LREE/HREE 6.84 7.82 16.25 14.55 12.97 14.87
      (La/Yb)N 4.15 4.80 13.24 12.27 13.18 13.81
      δEu=Eu/Eu* 0.14 0.14 0.39 0.48 0.47 0.40
      TZr 807 824 825 809 826 816
        注:主量元素单位为%,微量元素单位为10-6;LOI为烧失量,单位为%;TZr单位为℃;δEu=Eu/Eu*=2EuN/(SmN+GdN),其中N为球粒陨石标准化值(引自Sun and Mcdonough, 1989);TFeO=FeO+0.899 8×Fe2O3;A/CNK=摩尔Al2O3/(CaO+Na2O+K2O);A/NK=摩尔Al2O3/(Na2O+K2O);Mg#=100×摩尔Mg(Mg+TFe2+);里特曼指数σ=(Na2O+K2O)2/(SiO2-43);AR=[Al2O3+CaO+(Na2O+K2O)]/[Al2O3+CaO-(Na2O+K2O)];R1=摩尔[4Si-11(Na+K)-2(Fe+Ti)];R2=摩尔(6Ca+2Mg+Al);TZr=12 900/[2.95+0.85M+ln(496 000/Zrmelt)]-273.15,M=(Na+K+2Ca)/(Al×Si),Zrmelt为锆含量(Watson and Harrison, 1983).
      下载: 导出CSV

      表  3  新县二长花岗岩的锆石Hf同位素组成

      Table  3.   Zircon Hf isotope compositions of Xinxian monzogranite

      测试点号 t(Ma) 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf 2σ εHf(t) tDM1(Ma) tDM2(Ma)
      X-01-01 130 0.089 913 0.002 230 0.282 019 0.000 014 -24.0 1 793 2 790
      X-01-02 132 0.050 669 0.001 201 0.282 002 0.000 019 -24.5 1 768 2 876
      X-01-03 131 0.069 408 0.001 663 0.282 044 0.000 016 -23.0 1 731 2 915
      X-01-06 138 0.157 415 0.003 910 0.282 022 0.000 018 -23.9 1 874 2 824
      X-01-07 128 0.071 049 0.001 659 0.282 089 0.000 018 -21.5 1 666 2 877
      X-01-08 136 0.057 694 0.001 426 0.282 082 0.000 016 -21.6 1 666 2 722
      X-01-09 130 0.121 267 0.003 078 0.282 026 0.000 016 -23.8 1 825 2 745
      X-01-10 133 0.121 524 0.003 062 0.282 062 0.000 015 -22.5 1 771 2 861
      X-01-11 131 0.105 876 0.002 557 0.282 077 0.000 014 -21.9 1 725 2 785
      X-01-12 129 0.045 616 0.001 050 0.282 049 0.000 016 -22.8 1 695 2 751
      X-01-14 136 0.124 686 0.003 099 0.282 017 0.000 015 -24.0 1 839 2 810
      X-03-01 144 0.117 658 0.004 171 0.282 017 0.000 020 -23.9 1 895 2 886
      X-03-02 143 0.068 153 0.002 372 0.282 067 0.000 014 -22.0 1 731 2 894
      X-03-03 145 0.074 545 0.002 578 0.282 037 0.000 016 -23.1 1 783 2 786
      X-03-04 135 0.086 447 0.002 916 0.282 067 0.000 016 -22.2 1 757 2 851
      X-03-06 147 0.049 355 0.001 761 0.282 055 0.000 020 -22.3 1 719 2 777
      X-03-07 146 0.080 706 0.002 782 0.282 004 0.000 016 -24.2 1 842 2 814
      X-03-08 144 0.084 147 0.002 919 0.282 050 0.000 016 -22.7 1 781 2 925
      X-03-10 134 0.097 889 0.003 540 0.282 040 0.000 021 -23.3 1 828 2 822
      X-03-12 137 0.077 212 0.002 664 0.282 036 0.000 019 -23.3 1 790 2 835
      X-03-13 148 0.097 509 0.003 229 0.282 090 0.000 019 -21.2 1 737 2 847
      X-03-14 143 0.055 312 0.001 808 0.282 061 0.000 015 -22.2 1 713 2 738
      X-03-15 140 0.065 349 0.002 206 0.282 027 0.000 016 -23.5 1 780 2 798
      X-05-01 153 0.137 905 0.004 453 0.282 093 0.000 015 -21.1 1 795 2 869
      X-05-02 152 0.024 449 0.000 956 0.282 063 0.000 006 -21.8 1 671 2 737
      X-05-03 155 0.084 474 0.002 964 0.282 059 0.000 016 -22.1 1 770 2 802
      X-05-04 152 0.077 676 0.002 707 0.282 070 0.000 019 -21.8 1 742 2 813
      X-05-05 154 0.051 021 0.001 713 0.282 071 0.000 016 -20.3 1 839 2 787
      X-05-07 152 0.077 947 0.002 638 0.282 067 0.000 038 -21.9 1 744 2 682
      X-05-08 155 0.173 258 0.005 759 0.282 062 0.000 019 -22.3 1 914 2 795
      X-05-09 154 0.144 987 0.004 498 0.282 045 0.000 014 -22.8 1 870 2 807
      X-05-10 155 0.166 763 0.005 287 0.282 073 0.000 017 -21.9 1 871 2 843
      X-05-11 152 0.152 313 0.004 866 0.282 109 0.000 016 -20.6 1 792 2 784
      X-05-12 153 0.015 606 0.000 507 0.282 066 0.000 019 -21.7 1 648 2 702
      X-05-13 155 0.134 066 0.004 520 0.282 062 0.000 016 -22.2 1 847 2 797
      X-05-14 152 0.137 464 0.004 262 0.282 063 0.000 016 -22.2 1 831 2 808
        注:εHf(t)=10 000×{[(176Hf/177Hf)s-(176Lu/177Hf)s×(eλt-1)]/[(176Hf/177Hf)CHUR.0-(176Lu/177Hf)CHUR×(eλt-1)]-1}; tDM1=1/λ×ln{1+[(176Hf/177Hf)s-(176Hf/177Hf)DM]/[(176Lu/177Hf)s-(176Lu/177Hf)DM]}; tDM2=1/λ×ln{1+[(176Hf/177Hf)s.t-(176Hf/177Hf)DM.t]/[(176Lu/177Hf)c-(176Lu/177Hf)DM]}+t; (176Hf/177Hf)s和(176Lu/177Hf)s为样品测定值; (176Hf/177Hf)CHUR.0=0.282 772, (176Lu/177Hf)CHUR=0.033 2, (176Hf/177Hf)DM=0.283 25, (176Lu/177Hf)DM=0.038 4(Rubatto and Gebauer, 2000); λ=1.867×10-11/a (Griffin et al., 2000); (176Lu/177Hf)c=0.015; t为锆石结晶时间,单位为Ma.
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