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    广西东平富Ga含锰岩系碳、氧同位素特征及意义

    李启来 伊海生 夏国清 季长军 金峰

    李启来, 伊海生, 夏国清, 季长军, 金峰, 2017. 广西东平富Ga含锰岩系碳、氧同位素特征及意义. 地球科学, 42(9): 1508-1518. doi: 10.3799/dqkx.2017.530
    引用本文: 李启来, 伊海生, 夏国清, 季长军, 金峰, 2017. 广西东平富Ga含锰岩系碳、氧同位素特征及意义. 地球科学, 42(9): 1508-1518. doi: 10.3799/dqkx.2017.530
    Li Qilai, Yi Haisheng, Xia Guoqing, Ji Changjun, Jin Feng, 2017. Characteristics and Implication of Carbon and Oxygen Isotopes in Ga-Rich Manganese-Bearing Rock Series in Dongping, Guangxi. Earth Science, 42(9): 1508-1518. doi: 10.3799/dqkx.2017.530
    Citation: Li Qilai, Yi Haisheng, Xia Guoqing, Ji Changjun, Jin Feng, 2017. Characteristics and Implication of Carbon and Oxygen Isotopes in Ga-Rich Manganese-Bearing Rock Series in Dongping, Guangxi. Earth Science, 42(9): 1508-1518. doi: 10.3799/dqkx.2017.530

    广西东平富Ga含锰岩系碳、氧同位素特征及意义

    doi: 10.3799/dqkx.2017.530
    基金项目: 

    国家科技支撑计划专题项目 2011BAB04B10-2

    详细信息
      作者简介:

      李启来(1989-), 男, 博士研究生, 主要从事沉积地球化学研究

      通讯作者:

      伊海生, E-mail:yhs@cdut.edu.cn

    • 中图分类号: P618.74

    Characteristics and Implication of Carbon and Oxygen Isotopes in Ga-Rich Manganese-Bearing Rock Series in Dongping, Guangxi

    • 摘要: 在广西东平碳酸锰矿含锰岩系中发现Ga含量高异常,Ga含量为5.16×10-6~82.80×10-6,平均含量为33.76×10-6,达到了Ga矿资源工业品位标准要求,但目前还未见有产Ga锰矿床的报道.为了提升对此富Ga现象的认识,对其进行了碳、氧同位素特征研究.结果显示:矿石和围岩δ13CPDB值分别为-6.40‰~-2.20‰、-8.90‰~0.90‰,δ18OPDB值分别为-9.00‰~-7.90‰、-9.90‰~-3.90‰.研究表明:(1)有机质参与了碳酸锰矿形成;(2)含锰岩系为热水沉积成因,Ga来源与海底热液活动密切有关;(3)海底热液活动一方面为形成锰碳酸盐直接或间接提供了大量有机质,另一方面为形成富Ga含锰岩系带来了大量Ga,被锰的氧化物或氢氧化物、海洋生物(多为热液微生物)所吸附、富集,经复杂的成岩、成矿作用而最终赋存于含锰岩系之中形成富Ga含锰岩系.

       

    • 图  1  东平锰矿区地质简图

      茹廷锵(1992)

      Fig.  1.  Geological sketch of Dongping manganese orefield

      图  2  东平锰矿区综合地层柱状图

      刘腾飞(1996)

      Fig.  2.  Comprehensive stratigraphic column of Manganese-bearing rock assemblages in Dongping area

      图  3  东平富Ga含锰岩系沉积结构和构造

      a.纹层状构造;b.条带状构造;c.斑状结构;d.角砾状构造

      Fig.  3.  Textures and sedimentary structures of Dongping Ga-rich manganese-bearing rock series

      图  4  根据分馏方程计算的不同矿物(方解石(a);菱锰矿(b))温度和流体氧同位素关系

      Fig.  4.  Plots of equilibrium relationship between temperature and δ18OPDB mineral (calcite (a); rhodochrosite (b)) for various δ18OSMOW fluid from fractionation equation

      图  5  东平富Ga含锰岩系Z与δ13CPDB(a)、δ18OPDB(b)的相关关系

      Fig.  5.  Plots of relationship between Z values and δ13CPDB (a) or δ18OPDB (b) for Dongping Ga-rich manganese-bearing rock series

      图  6  东平富Ga含锰岩系围岩(a)和矿石(b)δ18OPDB与δ13CPDB相关关系

      Fig.  6.  Plots of relationship between δ13C PDB and δ18O PDB for host rocks (a) or ores (b) of Dongping Ga-rich manganese-bearing rock series

      表  1  东平富Ga含锰岩系碳、氧同位素组成及古温度和Z

      Table  1.   δ13CPDB, δ18OPDB, Z values and paleotemperatures of Dongping Ga-rich manganese-bearing rock series

      序号 样品编号 采样深度(m) 岩石类型 δ13CPDB (‰) δ18OPDB (‰) t1 (℃) t2 (℃) t3 (℃) Z
      1 TK-14 地表 硅质泥灰岩 0.90 -3.90 35.90 33.53 35.50 127.20
      2 7213-H05 138 硅质泥灰岩 -2.20 -9.60 66.74 70.58 68.16 118.01
      3 7213-H07 177 碳酸锰矿 -6.40 -8.20 59.16 60.68 59.54 110.11
      4 7213-H08 184 硅质泥灰岩 -2.90 -9.60 66.74 70.58 68.16 116.58
      5 7213-H10 190 硅质泥灰岩 -2.90 -9.30 65.11 68.41 66.28 116.73
      6 7213-H11 192 碳酸锰矿 -3.50 -90 63.49 66.27 64.42 115.65
      7 7213-H12 196 硅质泥灰岩 -2.70 -9.90 68.36 72.78 70.06 116.84
      8 7601-H07 151 硅质泥灰岩 -2.40 -9.30 65.11 68.41 66.28 117.75
      9 7601-H08 154 碳酸锰矿 -3.50 -8.90 62.95 65.56 63.80 115.70
      10 7601-H11 159 碳酸锰矿 -4.80 -8.70 61.87 64.15 62.58 113.14
      11 7601-H16 251 碳酸锰矿 -4.10 -8.40 60.24 62.06 60.75 114.72
      12 7601-H18 260 碳酸锰矿 -3.50 -8.90 62.95 65.56 63.80 115.70
      13 7601-H20 267 碳酸锰矿 -3.50 -8.60 61.33 63.45 61.96 115.85
      14 7601-H22 280 硅质泥灰岩 -2.60 -9.60 66.74 70.58 68.16 117.19
      15 1102-H10 128 碳酸锰矿 -2.20 -8.80 62.41 64.85 63.19 118.41
      16 1102-H12 131 碳酸锰矿 -2.40 -7.90 57.54 58.63 57.74 118.45
      17 KC-1 地表 碳酸锰矿 -5.40 -8.50 60.79 62.75 61.36 112.01
      18 KC-2 碳酸锰矿 -5.50 -8.60 61.33 63.45 61.96 111.75
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