Zircon U-Pb Age, Geochemistry and Tectonic Implications of Neoproterozoic Granite from South of Dabaishitou, East Tianshan
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摘要: 对东天山大白石头南片麻状花岗岩的研究,可以为新元古代早期Rodinia超大陆汇聚事件提供约束.在野外调查和岩相学研究的基础上,对该片麻状花岗岩开展了LA-ICP-MS锆石U-Pb定年、全岩地球化学和锆石原位Hf同位素分析.研究显示,片麻状花岗岩LA-ICP-MS锆石U-Pb年龄为922.7±7.9 Ma.岩石富SiO2(70.04%~71.60%)、碱(Na2O+K2O=5.93%~6.58%)、Al2O3(13.88%~14.91%)和低MgO(1.13%~1.29%).岩石Al2O3/TiO2(25~27)小于100,CaO/Na2O(0.7)大于0.3,K2O/Na2O(1.6~2.2)大于1.0,富集大离子亲石元素Rb、Th、K及La等,亏损Ba、Ta、Nb和Sr等,(La/Yb)N(7.29~8.11)小于10,δEu小于0.5,均显示出S型花岗岩特征.锆石εHf(t)均为正值(3.226 78~13.727 46),二阶段模式年龄为920~1 598 Ma,表明新元古代花岗岩形成于大陆边缘构造环境.综合已有研究结果,可以推断天山地区出露的该期构造岩浆事件可能对应于新元古代的罗迪尼亚(Rodinia)超大陆汇聚事件.Abstract: Researches on the south of Dabaishitou gneissic granite can provide constraints on early Neoproterozoic Rodinia supercontinent convergence in the East Tianshan. In this paper, zircon LA-ICP-MS U-Pb dating, in-situ Hf isotope and whole-rock geochemical composition analyses are presented for the gneissic granite. The results show that the LA-ICP-MS zircon U-Pb isotopic dating on the gneissic granite yields a mean U-Pb age of 922.7±7.9 Ma, which approximately represents the intrusive age of the granite. Geochemical characteristics of major elements of the granite exhibit high SiO2(70.04%-71.60%), Na2O+K2O(5.93%-6.58%) and Al2O3(13.88%-14.91%) contents, and low MgO(1.13%-1.29%) contents. Al2O3/TiO2(25-27) ratios are less than 100, while CaO/Na2O(0.7) and K2O/Na2O (1.6-2.2) ratios are more than 0.3 and 1.0, respectively. The gneissic granite is characterized by relative enrichment in Rb, Th, K, La, and depletion in Ba, Ta, Nb and Sr. All the samples are slightly enriched in LREE with (La/Yb)N ratios ranging from 7.29 to 8.11 (less than 10), and all the gneissic granite show clear negative Eu abnormalies (δEu < 0. 5). These characteristics are similar to values of typical S-type granite. Additionally, zircon εHf(t) values fall in the range of 3.226 78-13.727 46, with the two stage mode age from 920-1 598 Ma. Based on the chemical characteristics and Hf isotopic compositions, the Neoproterozoic gneissic granite was likely generated in a continental margin tectonic setting. With consideration of the age information on the ancient terranes from several areas, we suggest that the Tianshan ancient blocks probably formed a part of Rodinia during early Neoproterozoic period.
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Key words:
- East Tianshan /
- gneissic granite /
- isotopic chronology /
- Hf isotope /
- geochemistry
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图 6 SiO2-K2O(a)、SiO2-AR(b)和Na2O-K2O(c)图解
a.据Rickwood(1989);b.据Wright(1969);c.据Rollinson (1993)
Fig. 6. SiO2-K2O (a), SiO2-AR (b) and Na2O-K2O (c) diagrams
图 7 球粒陨石标准化稀土元素配分图(a)和原始地幔标准化微量元素蛛网图(b)
标准化值据Taylor and McLemann(1985)
Fig. 7. Chondrite-normalized REE patterns (a) and primitive-mantle normalized spider diagram for monzogranitic gneiss (b)
图 10 岩石Rb-(Ta+Yb) (a)和Rb-(Nb+Yb)(b)图解
syn-COLG.同碰撞花岗岩;WPG.板内花岗岩;VAG.火山弧花岗岩;ORG.洋脊花岗岩.据Pearce et al.(1984)
Fig. 10. Rb-(Ta+Yb) (a) and Rb-(Nb+Yb) (b) diagrams for samples
表 1 片麻状花岗岩锆石U-Pb数据
Table 1. U-Pb isotopic compositions of the gneissic granite
测点号 含量(10-6) Th/U 同位素比值 年龄(Ma) Th U 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 208Pb/232Th 1σ 206Pb/238U 1σ DMZ1601 129.84 375.41 0.35 0.156 19 0.001 81 0.070 66 0.001 54 1.526 33 0.032 96 0.048 67 0.000 86 935.6 10.10 DMZ1602 72.03 216.32 0.33 0.150 38 0.001 84 0.070 83 0.001 85 1.472 88 0.038 05 0.044 68 0.000 99 903.1 10.29 DMZ1603 84.88 215.71 0.39 0.157 38 0.001 90 0.070 09 0.001 78 1.525 34 0.038 41 0.045 20 0.000 89 942.2 10.58 DMZ1604 69.11 532.17 0.13 0.155 85 0.001 75 0.070 96 0.001 33 1.529 06 0.028 62 0.050 10 0.001 08 933.7 9.78 DMZ1605 290.32 549.57 0.53 0.158 66 0.001 76 0.069 90 0.001 23 1.533 46 0.027 01 0.048 01 0.000 60 949.3 9.81 DMZ1606 90.71 605.89 0.15 0.158 46 0.001 76 0.070 78 0.001 21 1.550 67 0.026 75 0.049 79 0.000 91 948.2 9.77 DMZ1607 51.81 705.55 0.07 0.155 91 0.001 72 0.070 48 0.001 17 1.518 95 0.025 52 0.046 74 0.001 14 934.0 9.60 DMZ1608 122.39 160.12 0.76 0.157 20 0.001 98 0.069 91 0.002 01 1.519 19 0.043 07 0.044 82 0.000 77 941.2 11.05 DMZ1609 494.98 890.75 0.56 0.198 95 0.002 18 0.088 13 0.001 31 2.423 63 0.036 69 0.058 64 0.000 66 1 169.7 11.74 DMZ1610 79.92 166.84 0.48 0.156 49 0.001 99 0.069 77 0.002 04 1.509 00 0.043 56 0.048 34 0.000 98 937.3 11.08 DMZ1611 124.85 285.96 0.44 0.152 16 0.001 82 0.069 65 0.001 67 1.464 63 0.034 81 0.045 47 0.000 81 913.0 10.17 DMZ1612 226.00 340.18 0.66 0.148 70 0.001 76 0.070 33 0.001 62 1.445 31 0.032 99 0.042 13 0.000 64 893.7 9.87 DMZ1613 48.37 270.85 0.18 0.149 07 0.001 76 0.068 68 0.001 59 1.414 60 0.032 46 0.044 74 0.001 11 895.7 9.90 DMZ1614 124.17 346.72 0.36 0.153 40 0.001 79 0.070 50 0.001 50 1.494 25 0.031 68 0.045 89 0.000 79 920.0 9.98 DMZ1615 58.62 261.43 0.22 0.153 52 0.001 86 0.068 98 0.001 74 1.463 03 0.036 58 0.044 88 0.001 11 920.6 10.42 DMZ1616 238.95 483.96 0.49 0.152 55 0.001 75 0.070 99 0.001 39 1.496 17 0.029 30 0.041 40 0.000 60 915.2 9.78 DMZ1617 437.82 870.44 0.50 0.152 77 0.001 73 0.074 22 0.001 32 1.566 22 0.028 10 0.045 66 0.000 62 916.5 9.65 DMZ1618 146.58 498.97 0.29 0.212 68 0.002 40 0.085 70 0.001 44 2.517 86 0.042 82 0.062 87 0.001 02 1 243.1 12.77 DMZ1619 165.83 665.61 0.25 0.149 79 0.001 70 0.070 57 0.001 29 1.460 13 0.026 95 0.040 93 0.000 70 899.8 9.52 DMZ1620 231.67 383.74 0.60 0.152 40 0.001 79 0.069 39 0.001 50 1.460 48 0.031 50 0.042 92 0.000 64 914.4 9.99 DMZ1621 100.66 608.97 0.17 0.151 84 0.001 72 0.069 68 0.001 24 1.461 05 0.026 32 0.043 70 0.000 84 911.2 9.60 DMZ1622 97.78 836.98 0.12 0.157 67 0.001 76 0.069 34 0.001 16 1.509 73 0.025 65 0.045 80 0.000 87 943.8 9.82 DMZ1623 65.96 697.53 0.09 0.156 42 0.001 76 0.069 72 0.001 19 1.505 91 0.025 99 0.050 15 0.001 12 936.8 9.79 DMZ1624 61.12 355.76 0.17 0.150 22 0.001 77 0.069 57 0.001 53 1.443 12 0.031 69 0.044 86 0.001 07 902.2 9.94 表 2 片麻状花岗岩锆石Hf同位素分析结果
Table 2. Zircon Hf isotopic compositions of the gneissic granite
样品 T(Ma) 176Yb/177Hf 1σ 176Lu/177Hf 1σ 176Hf/177Hf 1σ εHf(t) 1σ TDM(Ga) 1σ TDMC(Ga) 1σ fLu/Hf Hf-DMZ-01 935.6 0.072 548 0.004 513 0.001 604 0.000 089 0.282 465 0.000 026 8.828 03 0.916 98 1.131 93 0.037 37 1.251 69 0.037 37 -0.951 68 Hf-DMZ-02 903.1 0.065 190 0.001 182 0.001 514 0.000 016 0.282 427 0.000 021 6.839 23 0.723 12 1.183 48 0.029 37 1.354 14 0.029 37 -0.954 39 Hf-DMZ-03 942.2 0.058 122 0.000 694 0.001 312 0.000 016 0.282 441 0.000 017 8.291 06 0.597 09 1.157 49 0.024 13 1.291 32 0.024 13 -0.960 50 Hf-DMZ-05 949.3 0.083 186 0.000 453 0.001 834 0.000 010 0.282 493 0.000 018 9.975 74 0.622 47 1.098 37 0.025 54 1.188 50 0.025 54 -0.944 77 Hf-DMZ-06 948.2 0.096 117 0.001 334 0.002 268 0.000 013 0.282 527 0.000 027 10.886 46 0.951 21 1.061 85 0.039 53 1.128 99 0.039 53 -0.931 68 Hf-DMZ-07 934.0 0.049 232 0.000 405 0.001 032 0.000 011 0.282 346 0.000 022 4.937 44 0.764 51 1.281 59 0.030 59 1.499 96 0.030 59 -0.968 92 Hf-DMZ-08 941.2 0.094 719 0.000 471 0.002 059 0.000 017 0.282 636 0.000 023 14.717 51 0.818 83 0.898 58 0.033 93 0.876 11 0.033 93 -0.937 98 Hf-DMZ-10 937.3 0.106 080 0.001 137 0.002 443 0.000 019 0.282 589 0.000 028 12.722 80 0.984 90 0.977 26 0.041 19 1.002 06 0.041 19 -0.926 42 Hf-DMZ-11 913.0 0.191 629 0.005 154 0.004 339 0.000 120 0.282 983 0.000 038 25.029 42 1.342 94 0.419 14 0.059 90 0.182 50 0.059 90 -0.869 30 Hf-DMZ-12 893.7 0.081 784 0.001 171 0.001 924 0.000 010 0.282 461 0.000 024 7.597 26 0.844 12 1.147 83 0.034 69 1.298 20 0.034 69 -0.942 04 Hf-DMZ-14 920.0 0.057 918 0.000 234 0.001 304 0.000 009 0.282 311 0.000 019 3.226 78 0.659 95 1.340 27 0.026 58 1.598 42 0.026 58 -0.960 71 Hf-DMZ-15 920.6 0.081 325 0.001 338 0.001 893 0.000 018 0.282 435 0.000 022 7.265 53 0.762 68 1.184 04 0.03130 1.34039 0.03130 -0.94298 Hf-DMZ-16 915.2 0.087 136 0.001 246 0.001 922 0.000 011 0.282 621 0.000 023 13.727 46 0.807 60 0.916 78 0.033 33 0.919 99 0.033 33 -0.942 11 Hf-DMZ-17 916.5 0.080 228 0.001 107 0.001 882 0.000 027 0.282 454 0.000 024 7.861 95 0.830 50 1.156 28 0.034 09 1.298 92 0.034 09 -0.943 32 Hf-DMZ-19 899.8 0.111 358 0.002 171 0.002 548 0.000 046 0.282 541 0.000 024 10.205 91 0.832 03 1.049 57 0.034 85 1.135 25 0.034 85 -0.923 24 Hf-DMZ-20 914.4 0.146 224 0.005 927 0.003 296 0.000 097 0.282 679 0.000 031 14.938 13 1.084 78 0.864 83 0.046 56 0.841 04 0.046 56 -0.900 72 Hf-DMZ-21 911.2 0.157 528 0.002 011 0.003 571 0.000 020 0.282 863 0.000 020 21.203 34 0.699 59 0.593 18 0.030 43 0.431 32 0.030 43 -0.892 43 Hf-DMZ-22 943.8 0.063 551 0.000 993 0.001 409 0.000 032 0.282 367 0.000 021 5.667 26 0.747 34 1.264 34 0.030 22 1.460 86 0.030 22 -0.957 57 Hf-DMZ-23 936.8 0.044 911 0.000 740 0.001 000 0.000 026 0.282 357 0.000 025 5.390 26 0.874 93 1.265 81 0.034 99 1.473 15 0.034 99 -0.969 87 Hf-DMZ-24 902.2 0.084 347 0.003 151 0.001 899 0.000 051 0.282 383 0.000 037 5.044 50 1.311 29 1.258 39 0.053 73 1.468 40 0.053 73 -0.942 79 表 3 片麻状花岗岩主量元素(%)及微量元素(10-6)化学组成
Table 3. Major element (%) and trace element (10-6) compositions of the gneissic granite
样号 D01-1 D01-2 D01-3 D01-4 D01-5 样号 D01-1 D01-2 D01-3 D01-4 D01-5 SiO2 70.32 71.60 71.15 70.04 71.83 Ho 1.77 1.50 1.92 1.57 1.51 Al2O3 14.46 13.94 13.96 14.91 13.88 Er 4.87 4.32 5.30 4.18 4.04 Fe2O3 1.37 1.09 1.27 1.11 1.00 Tm 0.74 0.64 0.82 0.63 0.64 FeO 2.20 2.05 2.12 1.82 1.98 Yb 4.75 4.08 5.34 4.15 4.04 MnO 0.048 0.045 0.046 0.048 0.050 Lu 0.74 0.63 0.78 0.62 0.60 MgO 1.29 1.21 1.13 1.22 1.18 Y 47.8 42.3 51.5 40.4 40.3 CaO 1.53 1.45 1.56 1.49 1.49 ΣREE 274.43 213.11 290.50 219.95 234.26 Na2O 2.34 2.13 2.28 2.06 2.07 LREE 241.89 185.22 255.43 192.38 206.80 K2O 3.76 4.00 3.75 4.52 3.86 HREE 32.54 27.89 35.07 27.57 27.46 TiO2 0.57 0.52 0.55 0.57 0.53 LREE/HREE 7.43 6.64 7.28 6.98 7.53 P2O5 0.11 0.12 0.10 0.11 0.11 (La/Yb)N 8.11 7.45 7.62 7.29 8.10 LOI 1.94 1.81 2.04 2.05 1.97 δEu 0.38 0.38 0.40 0.44 0.38 Total 99.94 99.97 99.96 99.95 99.95 Rb 139 136 142 162 118 Mg# 36.96 37.12 34.77 40.13 37.34 Sr 90.3 80.8 108 93.9 82.8 A/CNK 1.35 1.33 1.31 1.36 1.35 Ba 792 772 916 925 780 SI 11.77 11.55 10.71 11.37 11.69 Nb 15.5 14.5 15.6 15.6 12.5 AR 2.23 2.32 2.27 2.34 2.26 Ta 1.21 1.20 1.39 1.20 0.94 σ 1.36 1.31 1.29 1.60 1.22 Zr 291 275 290 269 228 A/MF 11.21 11.52 12.35 12.22 11.76 Hf 8.66 7.97 8.48 7.96 7.04 C/MF 1.19 1.20 1.38 1.22 1.26 U 3.75 3.36 4.83 3.42 3.34 La 53.7 42.4 56.7 42.2 45.6 Th 30.9 26.6 34.0 30.5 26.7 Ce 112 82.2 120 90.7 96.9 Th/U 8.24 7.92 7.04 8.92 7.99 Pr 13.6 10.8 14.4 10.9 11.7 Zr/Hf 33.60 34.50 34.20 33.79 32.39 Nd 50.5 40.0 52.6 39.1 42.4 Rb/Ba 0.18 0.18 0.16 0.18 0.15 Sm 10.8 8.75 10.4 8.32 9.13 Sr/Ba 0.11 0.10 0.12 0.10 0.11 Eu 1.29 1.07 1.33 1.16 1.07 Nb/Ta 12.81 12.08 11.22 13.00 13.30 Gd 9.46 7.98 9.81 7.66 7.93 Rb/Nb 8.97 9.38 9.10 10.38 9.44 Tb 1.50 1.30 1.57 1.24 1.26 La/Nb 3.46 2.92 3.63 2.71 3.65 Dy 8.71 7.44 9.53 7.52 7.44 表 4 天山及西北邻区部分新元古代花岗岩年龄统计
Table 4. Some ages of Neoproterozoic granite in the Tianshan and Northwest China area
位置 样品名称 年代学方法 年龄 备注 阿拉塔格 花岗片麻岩 LA-ICP-MS锆石U-Pb 945±6 Ma,942±6 Ma 黄博涛等,2014 拉尔敦达坂北 片麻状花岗岩 LA-ICP-MS锆石U-Pb 882±33 Ma Chen et al., 2000 东天山星星峡 片麻状花岗岩 SHRIMP锆石U-Pb 942±7 Ma 胡霭琴等,2008 西天山温泉 片麻状花岗岩 SHRIMP锆石U-Pb 919±6 Ma 西天山赛里木湖以东 片麻状花岗岩 SHRIMP锆石U-Pb 930 Ma 胡霭琴等,2006 巴仑台北 片麻状花岗岩 SHRIMP锆石U-Pb 926±8 Ma 陈新跃等,2009 伊犁地块达根别里 花岗岩 LA-ICP-MS锆石U-Pb 942.5±2.6 Ma 李婷等,2015 塔里木盆地北缘 二云斜长片麻岩 LA-ICP-MS锆石U-Pb 822±7 Ma 杨鑫等,2017 塔里木盆地北缘辛格尔南托格拉克布拉克 斜长角闪岩 角闪石激光熔样40Ar/39Ar等时线年龄 866±6 Ma 胡蔼琴等,2006 兴地断裂南阔克苏 石英闪长岩 锆石U-Pb 828 Ma 胡蔼琴等,1997 库尔勒至阿克苏 片麻状花岗岩 锆石U-Pb 970 Ma,944 Ma,884 Ma 阿尔金环形山 二长花岗片麻岩 LA-ICP-MS锆石U-Pb 928±9 Ma 王立社等,2015 柴北缘锡铁山 花岗质片麻岩 独居石电子探针原位U-Th-Pb定年 886±18 Ma 张聪等,2016 北山柳园西古堡泉 花岗片麻岩 单颗粒锆石U-Pb 880±31 Ma 梅华林等,1999 中祁连山东段响河 花岗岩 单颗粒锆石U-Pb 917±12 Ma 郭进京等,1999 昆中断裂带两侧 花岗片麻岩 锆石U-Pb 900 Ma± 陆松年,2002 -
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