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    福建紫金山矿田黑云母花岗岩锆石U-Pb年代学和Hf同位素组成

    谢其锋 蔡元峰 董云鹏 黎敦朋

    谢其锋, 蔡元峰, 董云鹏, 黎敦朋, 2019. 福建紫金山矿田黑云母花岗岩锆石U-Pb年代学和Hf同位素组成. 地球科学, 44(4): 1311-1326. doi: 10.3799/dqkx.2018.256
    引用本文: 谢其锋, 蔡元峰, 董云鹏, 黎敦朋, 2019. 福建紫金山矿田黑云母花岗岩锆石U-Pb年代学和Hf同位素组成. 地球科学, 44(4): 1311-1326. doi: 10.3799/dqkx.2018.256
    Xie Qifeng, Cai Yuanfeng, Dong Yunpeng, Li Dunpeng, 2019. Zircon Geochronology and Hf Isotope Compositions of Biotite Granite in Southeast Ore Section of Zijinshan Ore Field, Fujian Province. Earth Science, 44(4): 1311-1326. doi: 10.3799/dqkx.2018.256
    Citation: Xie Qifeng, Cai Yuanfeng, Dong Yunpeng, Li Dunpeng, 2019. Zircon Geochronology and Hf Isotope Compositions of Biotite Granite in Southeast Ore Section of Zijinshan Ore Field, Fujian Province. Earth Science, 44(4): 1311-1326. doi: 10.3799/dqkx.2018.256

    福建紫金山矿田黑云母花岗岩锆石U-Pb年代学和Hf同位素组成

    doi: 10.3799/dqkx.2018.256
    基金项目: 

    福州大学2017年国家级大学生创新训练计划项目 201710386031

    南京大学内生金属矿床成矿机制研究国家重点实验室项目 20-15-05

    详细信息
      作者简介:

      谢其锋(1981-), 男, 副教授, 博士, 主要从事矿产普查与勘探教学与研究

      通讯作者:

      蔡元峰

    • 中图分类号: P588.34;P597.3

    Zircon Geochronology and Hf Isotope Compositions of Biotite Granite in Southeast Ore Section of Zijinshan Ore Field, Fujian Province

    • 摘要: 紫金山矿田位于华南褶皱系东部,闽西南凹陷西南部,是我国大型-超大型浅成低温热液铜金矿床,区内发现多个与岩浆活动密切相关的金、银、铜等金属矿床.对紫金山矿田东南矿段与成矿密切相关的细粒黑云母花岗岩开展了详细野外地质调查、岩相学和锆石稀土元素、U-Pb年代学和Hf同位素研究.LA-ICP-MS法获得细粒黑云母花岗岩中岩浆结晶锆石206Pb/238U-207Pb/235U谐和年龄为109.5±1.9 Ma(MSWD=0.74,N=16),206Pb/238U加权平均年龄为107.44±0.94 Ma(MSWD=1.06,N=16),二者在误差范围内结果一致,结合锆石稀土元素和岩浆振荡环带特征及Th/U比值,上述年龄结果可代表岩石的结晶年龄,表明细粒黑云母花岗岩侵位于燕山期早白垩世.细粒黑云母花岗岩锆石Hf同位素初始比值εHft)均为负,介于-4.99~-1.06(平均值为-2.99);两阶段Hf模式年龄(tDM2)介于1 233.7~1 485.4 Ma(平均值为1 362.4 Ma).样品的εHft)、Hf同位素地壳模式年龄分布范围变化较小,暗示岩体的岩浆来源具有较为均一的锆石Hf同位素组成.紫金山矿田东南矿段早白垩世花岗岩体的锆石U-Pb年龄和Hf同位素特征,反映了闽西南早白垩世的岩浆成矿活动时间和源区特征,其成因与中国东南部岩石圈伸展减薄和壳源物质参与岩浆形成演化密切相关.

       

    • 图  1  紫金山矿田中生代岩浆岩及矿床分布

      邱小平等(2010)和于波等(2013)修改

      Fig.  1.  Distribution of Mesozoic magmatic rocks and ore deposits in the Zijinshan ore field

      图  2  紫金山矿田东南矿段细粒黑云母花岗岩的野外宏观露头照片(a~d)和镜下照片(e, f)

      a.紫金山矿田东南矿段整体状况;b.蓝辉铜矿化、黄铁矿矿化花岗岩体,发育一组北北西向节理;c.岩体中发育北北西-北北东向两组近垂直节理;d.浅肉红色细粒黑云母花岗岩;e.花岗岩,细粒花岗结构;f.具环带结构的斜长石交代聚片双晶斜长石.矿物缩写:Qtz.石英;Kfs.钾长石;Pl.斜长石;Bt.黑云母;Chl.绿泥石;Zr.锆石;Ap.磷灰石

      Fig.  2.  Outcrop (a-d) and microscope images (e, f) the granite in southeast ore section of Zijinshan ore field

      图  3  紫金山矿区东南矿段花岗岩锆石的CL图像、U-Pb和Hf同位素测点位置及编号

      实线圆圈为U-Pb年龄测点,直径为32 μm;虚线圆圈为相应的Hf同位素测点,直径为44 μm

      Fig.  3.  Typical zircon U-Pb and Hf isotope analysis spot numbers, CL images, 206Pb/238U ages from granite zircons of southeast ore section in Zijinshan ore field

      图  4  紫金山矿田东南矿段花岗岩锆石U-Pb谐和图(a)和锆石稀土元素球粒陨石标准化图(b)

      球粒陨石标准数据采用Sun and McDonough(1989)

      Fig.  4.  Zircon 207Pb/235U-206Pb/238U concordia diagram and 206Pb/238U weighed average age (a), chondrite-normalized REE patterns diagram (b) of southeast ore section in Zijinshan ore field

      图  5  紫金山矿田东南矿段花岗岩锆石地壳模式年龄(tDM2)和εHf(t)柱状图

      Fig.  5.  Zircon tDM2 and Hf isotopic compositions of the granite of the Zijinshan from Zijinshan granite zircons, Southeast Fujian Province

      表  1  闽西南紫金山矿田花岗岩LA-MC-ICP-MS锆石原位Lu-Hf同位素组成分析结果

      Table  1.   LA-MC-ICP-MS in-situ analyses of zircon Lu-Hf isotopic composition of the Zijinshan granites, Southwest Fujian Province

      测点 年龄(Ma) 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf εHf(t) tDM1(Ma) tDM2(Ma) fLu/Hf
      比值 比值 比值
      14CL01 171.9 0.025 621 0.000 265 0.001 236 0.000 013 0.282 609 0.000 019 -2.1 916.0 1 353.8 -0.96
      14CL02 107.8 0.030 448 0.000 585 0.001 439 0.000 022 0.282 590 0.000 019 -4.2 947.3 1 433.9 -0.96
      14CL03 110.8 0.032 544 0.000 463 0.001 500 0.000 020 0.282 607 0.000 023 -3.5 925.4 1 395.4 -0.95
      14CL04 108.5 0.040 784 0.001 013 0.001 881 0.000 040 0.282 624 0.000 023 -3.0 910.5 1 360.1 -0.94
      14CL05 106.6 0.031 269 0.000 428 0.001 504 0.000 020 0.282 594 0.000 020 -4.1 943.7 1 426.6 -0.95
      14CL06 107.1 0.028 901 0.000 232 0.001 341 0.000 011 0.282 665 0.000 021 -1.5 838.3 1 265.2 -0.96
      14CL07 106.7 0.023 936 0.000 467 0.001 166 0.000 020 0.282 626 0.000 019 -2.9 889.6 1 352.5 -0.96
      14CL08 106.5 0.040 713 0.003 581 0.001 753 0.000 138 0.282 568 0.000 021 -5.0 987.1 1 485.7 -0.95
      14CL09 104.1 0.045 229 0.000 987 0.002 071 0.000 044 0.282 644 0.000 021 -2.4 885.4 1 317.2 -0.94
      14CL10 108.7 0.056 805 0.004 055 0.002 553 0.000 170 0.282 625 0.000 022 -3.0 925.8 1 360.4 -0.92
      14CL11 110.5 0.025 336 0.000 206 0.001 187 0.000 010 0.282 608 0.000 021 -3.5 916.4 1 392.2 -0.96
      14CL12 105.1 0.029 219 0.000 678 0.001 394 0.000 037 0.282 679 0.000 021 -1.1 819.4 1 234.8 -0.96
      14CL13 109.4 0.033 660 0.000 467 0.001 630 0.000 025 0.282 631 0.000 021 -2.7 894.2 1 342.6 -0.95
      14CL14 106.1 0.039 611 0.000 532 0.001 825 0.000 024 0.282 604 0.000 021 -3.7 937.8 1 406.0 -0.95
      14CL15 109.2 0.026 562 0.000 930 0.001 251 0.000 041 0.282 636 0.000 021 -2.5 878.6 1 330.7 -0.96
      14CL16 104.4 0.018 377 0.000 226 0.000 879 0.000 009 0.282 595 0.000 019 -4.0 926.8 1 423.1 -0.97
      14CL17 108.2 0.031 557 0.001 055 0.001 520 0.000 044 0.282 661 0.000 020 -1.7 848.6 1 275.1 -0.95
      下载: 导出CSV

      表  2  闽西南紫金山矿田东南矿段花岗岩锆石LA-ICP-MS稀土元素数据

      Table  2.   Rare earth elements measured by LA-ICP-MS from southeast ore field of Zijinshan granite zircons, Southeast Fujian Province

      测点 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
      14CL01 0.09 39.63 0.38 6.35 11.44 2.31 52.59 18.17 208.44 77.48 340.77 74.99 740.58 127.34
      14CL02 19.06 64.24 4.83 20.19 4.53 1.58 13.28 5.00 64.77 28.73 152.12 40.63 473.54 100.59
      14CL03 1.05 25.40 0.30 1.93 1.53 0.71 9.40 3.34 45.30 20.29 109.88 28.99 343.53 72.92
      14CL04 0.01 32.78 0.05 0.69 1.81 1.03 11.96 4.54 56.03 23.25 119.09 30.58 349.96 71.39
      14CL05 0.01 22.92 0.02 0.71 1.39 0.76 9.33 3.53 46.53 20.43 105.34 27.14 321.66 66.47
      14CL06 0.02 20.10 0.02 0.31 1.30 0.72 8.09 3.26 44.02 19.42 104.37 28.32 328.81 70.64
      14CL07 0.14 23.93 0.08 0.50 1.63 0.64 8.86 3.65 48.97 21.58 115.54 30.40 355.93 76.69
      14CL08 0.01 26.29 0.02 0.56 1.68 0.70 9.66 4.14 55.71 25.12 134.03 35.37 412.69 90.32
      14CL09 0.01 32.52 0.03 0.60 1.94 1.03 12.44 5.16 69.38 32.40 172.63 44.97 524.85 113.56
      14CL10 0.01 22.30 0.03 0.63 1.05 0.68 9.16 3.41 46.87 19.90 102.18 26.68 308.49 65.70
      14CL11 0.06 29.08 0.05 0.65 1.42 0.96 11.25 4.29 59.90 27.13 145.66 38.45 455.44 99.39
      14CL12 0.02 22.65 0.02 0.53 1.13 0.70 9.55 3.65 48.37 21.14 114.12 29.24 352.29 76.63
      14CL13 0.04 23.58 0.02 0.59 1.22 0.67 9.50 3.52 47.74 21.33 113.13 29.28 343.91 76.52
      14CL14 0.72 38.14 0.27 1.44 2.71 1.16 16.72 6.49 85.44 37.32 195.60 49.63 554.49 119.83
      14CL15 0.26 22.56 0.15 1.18 1.42 0.78 9.57 4.09 55.63 24.38 132.97 35.64 423.28 93.75
      14CL16 0.03 25.25 0.04 1.04 2.45 1.26 14.66 5.63 73.90 32.88 174.94 46.04 539.69 124.65
      14CL17 0.01 30.33 0.03 0.80 1.74 0.74 9.70 3.93 52.39 22.63 119.27 30.76 356.40 80.34
      下载: 导出CSV
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