与海洋天然气水合物微纳米尺度赋存和开采储存技术有关的研究进展

樊栓狮; 于驰; 郎雪梅; 王燕鸿; 陈建标

doi:10.3799/dqkx.2018.412

与海洋天然气水合物微纳米尺度赋存和开采储存技术有关的研究进展

doi: 10.3799/dqkx.2018.412

樊栓狮^1,2, ,,
于驰^1,2,3,
郎雪梅^1,2,
王燕鸿^1,2,
陈建标^1,2

1.
华南理工大学化学与化工学院, 广东广州 510641
2.
华南理工大学传热强化与过程节能教育部重点实验室, 广东广州 510641
3.
中国科学院广州能源研究所天然气水合物重点实验室, 广东广州 510640

基金项目:

国家自然科学基金项目 51576069

国家自然科学基金项目 21736005

中国科学院天然气水合物重点实验室开放基金项目 Y607kg1001

详细信息

作者简介:
樊栓狮(1965-), 教授, 主要从事天然气水合物与能源新技术的研究

通讯作者:
樊栓狮

中图分类号: P618
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出版历程
- 收稿日期: 2017-10-01
- 刊出日期: 2018-05-15

Micro-Nano-Scale Studies on Occurrence and Gas Production and Storage Technology of Marine Gas Hydrates

Fan Shuanshi^{1,2
, ,},
Yu Chi^1,2,3,
Lang Xuemei^1,2,
Wang Yanhong^1,2,
Chen Jianbiao^1,2

1.
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China
2.
Key Lab of Enhanced Heat Transfer and Energy Conservation, Ministry of Education, South China University of Technology, Guangzhou 510641, China
3.
Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China

摘要

摘要: 天然气水合物是一类潜在的储量巨大的清洁能源.近年来，水合物的研究已经逐渐拓展至纳米、介观层面.纳米科学贯穿了水合物研究的全过程，包括上游天然气水合物成藏、开采和下游的储运、分离等水合物应用技术，其核心在于研究水合物在纳米材料表面、内部、间隙中生长和分解的传质传热过程.将以第九届国际水合物大会（ICGH9）为切入点，从水合物成藏、开采和下游技术应用几个方面综述近年来水合物研究中的纳米研究进展.目前对水合物的研究尺度并未做到全覆盖，水合物在纳米材料间隙中的传质传热过程研究较少，纳米材料的累积放大效应研究也存在空白.这正是水合物成藏、开采研究中的瓶颈问题.未来的研究应该着眼于水合物在纳米材料中生成和分解的传质传热作用，以此为主线将水合物技术和水合物成藏、开采研究中的核心问题进行统一协同研究.
- 天然气水合物 /
- 纳米 /
- 传质传热 /
- 赋存 /
- 开采 /
- 储存 /
- 二氧化碳封存 /
- 油气地质
Abstract: Natural gas hydrate is a kind of clean energy with potential huge reserves. Hydrate researches gradually extend to nano-and micro-scale recently. Nano science has been a part of hydrate researches, including occurrence, gas production and hydrate based technologies of downstream such as gas storage and separation. The common key is heat and mass transfer of hydrate formation and dissociation on the surface, inside and between nanomaterials. From 9th international conference on gas hydrates (ICGH9) as point of penetration in this paper, it reviews nano-scale studies on occurrence and gas production of marine gas hydrates, as well as downstream utilizations of gas hydrate technology.The results show that study of heat and mass transfer inside nanomaterial during hydrate formation and dissociation is needed to be developed. There is a blank area that accumulative effect of micro-nanomaterial during hydrate formation and dissociation. These questions have become bottleneck of gas hydrate occurrence and production. In the future, researches should focus on heat and mass transfer inside nanomaterial during hydrate formation and dissociation and use this as a link to systematively study occurrence and production of natural gas hydrates.
- natural gas hydrate /
- nano /
- mass and heat transfer /
- occurrence /
- gas production /
- gas storage /
- carbon dioxide storage /
- petroleum geology

HTML全文

图 1 中国南海某海域海底水合物矿样的SEM图和ESEM图

a~d.水合物矿样的SEM照片，放大倍数3万倍和6万倍；e，f.水合物矿样的ESEM照片，放大倍数2 000倍

Fig. 1. SEM and ESEM images of hydrate samples of the South China Sea

下载: 全尺寸图片幻灯片

图 2 水合物在纳米材料ZIF-8内部生长示意

据Zhang et al.(2015)

Fig. 2. Schematic of hydrate formation inside nanomaterial ZIF-8

下载: 全尺寸图片幻灯片

图 3 应用纳米材料ZIF-67浆液的水合物技术示意

据Pan et al.(2015)

Fig. 3. Hydrate-based technology by using nanomaterial ZIF-67 slurry

下载: 全尺寸图片幻灯片

表 1 测试SEM和ESEM的海底矿样信息

Table 1. Hydrate sample information of SEM and ESEM tests

样品名称	采样深度(m)	分析方法
S-10	124.65～125	SEM
S-26	133.5	SEM
S-31	135.1	SEM
S-40	160.8～160.9	SEM
S-1	148～148.8	ESEM
S-36	158.55～158.75	ESEM

下载: 导出CSV

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