新疆西昆仑东南部泉水沟岩体的年龄、成因及构造意义

乔耿彪; 伍跃中

doi:10.3799/dqkx.2018.588

新疆西昆仑东南部泉水沟岩体的年龄、成因及构造意义

doi: 10.3799/dqkx.2018.588

乔耿彪^1,2,,
伍跃中¹

1.
中国地质调查局西安地质调查中心, 自然资源部岩浆作用成矿与找矿重点实验室, 陕西西安 710054
2.
中国地质调查局造山带地质研究中心, 陕西西安 710054

基金项目:

国家自然科学基金项目 41302051

中国地质调查局项目 DD20160006

国家科技支撑计划项目 2011BAB06B05-02

详细信息

作者简介:
乔耿彪(1979-), 男, 教授级高级工程师, 硕士, 主要从事矿物学、岩石学、矿床学研究

中图分类号: P59
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出版历程
- 收稿日期: 2018-03-08
- 刊出日期: 2018-12-15

Geochronology, Petrogenesis and Tectonic Significance of Quanshuigou Pluton from Southeastern West Kunlun Mountain in Xinjiang, China

Qiao Gengbiao^{1,2
,},
Wu Yuezhong¹

1.
Xi'an Center of Geological Survey, China Geological Survey, Key Laboratory for the Study of Focused Magmatism and Giant Ore Deposits, Ministry of Natural Resources, Xi'an 710054, China
2.
Orogen Research Center, China Geological Survey, Xi'an 710054, China

摘要

摘要: 泉水沟岩体位于西昆仑造山带和巴彦喀拉褶断带夹持区域，对追溯西昆仑地区的区域发展演化具有重要指示意义.通过高精度同位素年代学、岩石矿物学与地球化学等手段，准确限定岩体的形成时代并查明其地球化学特征.LA-ICP-MS锆石U-Pb定年获得该岩体中花岗闪长岩的年龄为217.6±0.9 Ma，其中的暗色包体黑云母石英闪长岩年龄为217.4±0.7 Ma，均属晚三叠世（T₃）.花岗闪长岩具有富硅（SiO₂=67.21%~68.85%）、富碱（全碱变化于6.36%~6.76%，里特曼指数δ=1.56~1.86）、富钾（K₂O=3.50%~3.96%，K₂O/Na₂O=1.20~1.41），而贫TiO₂、MnO和P₂O₅（< 1%）的特点；岩体的铝饱和指数A/CNK为0.88~1.05；总体上属高钾钙碱性准铝质-弱过铝质I型花岗岩.岩石富集轻稀土，轻重稀土元素分馏明显（（La/Yb）_N为1.03~11.05），具有铕负异常（δEu为0.42~0.73）；富集Rb、Th、K和LREE等大离子亲石元素，而贫Ba、Sr、Ti、P等元素.岩石微量元素地球化学特征显示，泉水沟花岗闪长岩及其包体为下地壳变质玄武岩熔融的产物，在岩浆演化过程中岩体的分离结晶作用以斜长石、辉石和磷灰石为主，而角闪石分离结晶不明显.区域构造环境演化表明，晚三叠世时随着古特提斯洋向北消减至最终闭合，在康西瓦断裂带两侧发生大规模陆块碰撞挤压，致使地壳垂向增生加厚引起了强烈的岩浆活动，从而在下地壳发生重熔作用形成了泉水沟岩体，也表明该区当时已处于洋陆拼合后的碰撞造山新阶段.
- I型花岗岩 /
- 晚三叠世 /
- 同碰撞环境 /
- 泉水沟岩体 /
- 西昆仑 /
- 地球化学
Abstract: Lying in the transitional region of the West Kunlun area and Bayankala folded fault belt of Xinjiang, the Quanshuigou pluton has indicative significance for area evolution. In order to determine the formation time, geochemical characteristics and tectonic setting of the Quanshuigou pluton, geochronology, mineralogy, petrology and geochemistry were studied. Combined with the cathodoluminescence (CL) images and element U, Th and Pb features of zircon, this study yields two ages of 217.6±0.9 Ma and 217.4±0.7 Ma for granodiorite and quartz diorite using the LA-ICP-MS zircon U-Pb dating, belonging to the Late Triassic. The geochemical analyses show that the granodiorites are characterized by high SiO₂ (67.21%-68.85%), high alkali (Na₂O+K₂O=6.36%-6.76%, Rittman index δ=1.56-1.86), high potassium (K₂O=3.50%-3.96%, K₂O/Na₂O=1.20-1.41), and low TiO₂, MnO and P₂O₅ (content < 1%); and aluminum index A/CNK=0.88-1.05, indicating a transitional composition between metaluminous and peraluminous I-type granite series. The pluton is enriched in LREE, depleted in HREE ((La/Yb)_N=1.03-11.05), with negative Eu anomaly (δEu=0.42-0.73). While the trace elements are characterized by enrichment of Rb, Th, K and LREE, and depletion of Ba, Sr, Ti, P. The chemical signatures indicate that the pluton experienced the highly fractionated process and partial melting. The Quanshuigou diorite with characteristic source-mixed granite from mantle and crust should be likely derived from metabasalt in lower crust, and subsequently underwent the fractional crystallization of plagioclase, pyroxene and apatite without amphibole. In the Late Triassic, the Paleo-Tethys Ocean was gradually evolved from subduction toward north to the complete closure, and at the same time regional tectonic stress was transformed from subduction process to collision compressional action environment. Based on comprehensive analysis of the genetic type of the pluton and evolution of regional tectonic environment, it is suggested that the Quanshuigou pluton formed just after this tectonic stress transfromation, which shows that this area was in continent-continent collision orogenic regime in the Late Triassic.
- I-type granite /
- Late Triassic /
- syn-collision /
- Quanshuigou pluton /
- West Kunlun /
- geochemistry

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图 1 新疆西昆仑地区大地构造位置(a)及侵入岩分布(b)

据李荣社等(2008).TRMB.塔里木板块; WKLS.西昆仑造山带; TSH.甜水海地块; BYF.巴颜喀拉褶断带; SQ.南羌塘地块; KT.科西斯坦地块.主要断裂:F₁.公格尔-柯岗大断裂; F₂.康西瓦-鲸鱼湖大断裂; F₃.大红柳滩断裂; F₄.喀喇昆仑大断裂; F₅.班公湖-怒江大断裂

Fig. 1. Geotectonic position (a) and distribution of intrusive rocks (b) in the West Kunlun area of Xinjiang

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图 2 泉水沟岩体的野外露头(a、b)和显微镜正交偏光(c、d)照片

a.岩体野外露头; b.花岗闪长岩及其中产出的暗色包体黑云母石英闪长岩; c.花岗闪长岩中微斜长石发育格子状双晶; d.石英闪长岩中角闪石和黑云母等暗色矿物聚集成团.Mc.微斜长石; Pl.斜长石; Qtz.石英; Bt.黑云母; Am.角闪石

Fig. 2. Field photographs (a, b) and microphotographs (c, d) of the Quanshuigou pluton

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图 3 泉水沟岩体部分典型锆石阴极发光图像及U-Pb年龄值

a.花岗闪长岩; b.黑云母石英闪长岩

Fig. 3. Zircon CL images for microbeam analyzed spots and apparent U-Pb ages of the Quanshuigou pluton

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图 4 泉水沟岩体锆石U-Pb年龄谐和图

a, b.花岗闪长岩; c, d.黑云母石英闪长岩

Fig. 4. Zircon U-Pb concordia diagrams of the Quanshuigou pluton

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图 5 泉水沟岩体K₂O-SiO₂图解

据Maniar and Piccoli (1989)

Fig. 5. Diagram of K₂O-SiO₂ of the Quanshuigou pluton

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图 6 泉水沟岩体Hark图解

Fig. 6. Hark diagrams of the Quanshuigou pluton

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图 7 泉水沟岩体稀土元素球粒陨石标准化配分曲线图(a)和微量元素原始地幔标准化蛛网图(b)

a, b标准化值据Sun and McDonough(1989)

Fig. 7. Chondrite-normalized REE distribution patterns (a) and primitive mantle-normalized trace element distribution patterns (b) of the Quanshuigou pluton

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图 8 泉水沟岩体成因类型判别图解

a.SiO₂-Zr图解(Whalen et al., 1987); b.(Zr+Nb+Ce+Y)-TFeO/MgO图解(Eby, 1990); c.SiO₂-Y图解(Chappell and White, 1992); FG.高分异的M、I、S型花岗岩；OGT.未分异的M、I、S型花岗岩

Fig. 8. Discrimination diagrams of granite genetic types for the Quanshuigou pluton

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图 9 泉水沟岩体(Dy/Yb)_N-(Nb/Ta)图解和C/MF-A/MF图解

据Altherr et al.(2000)

Fig. 9. (Dy/Yb)_N vs. (Nb/Ta) and C/MF vs. A/MF diagrams for the Quanshuigou pluton

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图 10 泉水沟岩体的构造背景判别图解

据Pearce et al.(1984)

Fig. 10. Diagrams of tectonic environment for the Quanshuigou pluton

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表 1 泉水沟花岗闪长岩锆石LA-ICP-MS U-Pb同位素测试结果

Table 1. LA-ICP-MS U-Pb isotopic analyses for zircons from the Quanshuigou granodiorite

测点号	含量(10^-6)			Th/U	同位素比值						年龄(Ma)
测点号	Pb	Th	U	Th/U	²⁰⁷Pb/²⁰⁶Pb	±1σ	²⁰⁷Pb/²³⁵U	±1σ	²⁰⁶Pb/²³⁸U	±1σ	²⁰⁷Pb/²⁰⁶Pb	±1σ	²⁰⁷Pb/²³⁵U	±1σ	²⁰⁶Pb/²³⁸U	±1σ
Q101	163	451	1 429	0.32	0.050 1	0.000 7	0.237 8	0.004 3	0.034 3	0.000 5	211.2	31.5	216.6	3.6	217.7	3.0
Q102	133	351	1 345	0.26	0.050 3	0.000 6	0.238 6	0.003 8	0.034 4	0.000 5	209.3	21.3	217.3	3.1	217.7	3.0
Q107	270	697	2 260	0.31	0.050 5	0.000 6	0.240 1	0.003 0	0.034 3	0.000 3	220.4	32.4	218.5	2.5	217.7	1.8
Q108	105	241	1 139	0.21	0.049 3	0.000 7	0.234 8	0.004 1	0.034 4	0.000 4	161.2	31.5	214.1	3.3	217.8	2.3
Q109	119	324	1 119	0.29	0.050 8	0.000 7	0.240 7	0.004 2	0.034 2	0.000 4	231.6	33.3	219.0	3.4	216.8	2.5
Q110	431	1 268	2 689	0.47	0.049 6	0.000 7	0.235 0	0.003 2	0.034 2	0.000 3	189.0	35.2	214.3	2.6	216.8	2.0
Q111	256	643	1 974	0.33	0.050 4	0.000 7	0.240 0	0.003 6	0.034 4	0.000 4	213.0	36.1	218.4	2.9	217.8	2.3
Q112	144	371	1 334	0.28	0.051 9	0.000 8	0.247 6	0.004 4	0.034 5	0.000 5	283.4	30.6	224.6	3.6	218.4	3.4
Q113	164	404	1 501	0.27	0.050 7	0.000 7	0.241 4	0.003 7	0.034 4	0.000 4	233.4	31.5	219.5	3.0	217.9	2.6
Q114	190	514	1 730	0.30	0.050 9	0.000 9	0.241 0	0.003 9	0.034 2	0.000 4	239.0	38.9	219.3	3.2	216.6	2.5
Q115	61	160	297	0.54	0.050 5	0.001 3	0.239 7	0.006 3	0.034 3	0.000 5	220.4	57.4	218.1	5.1	217.3	2.9
Q117	82	222	862	0.26	0.050 3	0.000 7	0.240 1	0.004 8	0.034 5	0.000 6	209.3	26.8	218.5	3.9	218.8	3.8
Q118	215	570	1 538	0.37	0.049 0	0.000 6	0.232 2	0.003 2	0.034 3	0.000 4	150.1	27.8	212.0	2.6	217.4	2.5
Q119	69	179	454	0.39	0.051 9	0.001 1	0.246 5	0.005 3	0.034 5	0.000 5	279.7	46.3	223.7	4.4	218.5	3.1
Q120	242	598	2 138	0.28	0.051 0	0.000 6	0.242 2	0.003 3	0.034 5	0.000 4	239.0	25.9	220.2	2.7	218.4	2.2
Q121	292	774	2 047	0.38	0.051 4	0.000 6	0.244 7	0.004 6	0.034 5	0.000 5	257.5	27.8	222.3	3.8	218.9	3.4
Q122	88	214	635	0.34	0.051 5	0.000 9	0.245 1	0.004 4	0.034 5	0.000 3	264.9	36.1	222.6	3.6	218.6	1.9
Q123	143	331	1 551	0.21	0.050 8	0.000 8	0.239 6	0.004 7	0.034 2	0.000 4	231.6	69.4	218.1	3.9	217.0	2.6
Q125	266	651	2 061	0.32	0.051 4	0.000 9	0.243 8	0.005 0	0.034 5	0.000 4	261.2	38.9	221.6	4.1	218.5	2.4
Q126	131	346	1 197	0.29	0.051 3	0.000 7	0.242 2	0.004 9	0.034 3	0.000 5	253.8	31.5	220.3	4.0	217.4	3.0
Q127	166	417	1 558	0.27	0.051 0	0.000 7	0.241 3	0.003 6	0.034 4	0.000 3	239.0	33.3	219.5	2.9	218.3	2.2
Q128	195	469	1 864	0.25	0.051 4	0.000 6	0.244 2	0.004 0	0.034 5	0.000 5	261.2	27.8	221.8	3.2	218.8	2.9
Q129	250	640	2 258	0.28	0.051 4	0.000 8	0.243 9	0.004 6	0.034 5	0.000 5	257.5	30.6	221.6	3.8	218.6	2.8
Q130	139	343	1 160	0.30	0.051 7	0.001 2	0.244 1	0.005 5	0.034 4	0.000 6	272.3	55.5	221.8	4.5	217.9	3.4
Q131	265	645	2 496	0.26	0.051 2	0.000 5	0.242 0	0.003 7	0.034 3	0.000 4	250.1	24.1	220.0	3.1	217.4	2.6
Q132	223	558	1 884	0.30	0.051 5	0.000 7	0.243 6	0.003 9	0.034 4	0.000 4	264.9	32.4	221.4	3.2	217.7	2.4
Q133	336	878	2 416	0.36	0.050 7	0.000 6	0.240 3	0.003 7	0.034 4	0.000 4	233.4	29.6	218.7	3.0	218.3	2.2
Q134	148	397	1 437	0.28	0.051 4	0.000 9	0.243 1	0.004 2	0.034 4	0.000 3	257.5	38.9	221.0	3.4	217.9	1.8
Q135	516	1 440	2 804	0.51	0.051 5	0.000 7	0.239 4	0.003 6	0.033 7	0.000 3	261.2	34.3	217.9	2.9	214.0	1.8
Q202	161	400	1 239	0.32	0.050 3	0.000 7	0.239 1	0.003 9	0.034 2	0.000 4	209.3	33.3	217.7	3.2	217.0	2.2

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表 2 泉水沟黑云母石英闪长岩锆石LA-ICP-MS U-Pb同位素测试结果

Table 2. LA-ICP-MS U-Pb isotopic analyses for zircons from the Quanshuigou biotite quartz diorite

测点号	含量(10^-6)			Th/U	同位素比值						年龄(Ma)
测点号	Pb	Th	U	Th/U	²⁰⁷Pb/²⁰⁶Pb	±1σ	²⁰⁷Pb/²³⁵U	±1σ	²⁰⁶Pb/²³⁸U	±1σ	²⁰⁷Pb/²⁰⁶Pb	±1σ	²⁰⁷Pb/²³⁵U	±1σ	²⁰⁶Pb/²³⁸U	±1σ
Q601	1 660	4 663	3 842	1.21	0.050 9	0.000 6	0.242 0	0.003 5	0.034 5	0.000 3	235.3	27.8	220.1	2.9	218.8	1.9
Q602	2 152	6 129	4 469	1.37	0.050 7	0.000 6	0.240 2	0.003 3	0.034 4	0.000 3	227.8	27.8	218.6	2.7	217.8	1.7
Q603	2 715	7 889	5 119	1.54	0.050 5	0.000 5	0.239 5	0.003 2	0.034 4	0.000 3	216.7	25.9	218.0	2.6	218.0	1.8
Q604	1 896	5 732	3 956	1.45	0.050 9	0.000 6	0.238 9	0.003 4	0.034 0	0.000 2	235.3	29.6	217.5	2.8	215.7	1.6
Q605	2 797	7 933	4 966	1.60	0.050 2	0.000 5	0.238 7	0.003 4	0.034 5	0.000 3	211.2	19.4	217.4	2.8	218.6	2.1
Q606	421	1 052	2 625	0.40	0.050 2	0.000 5	0.238 1	0.005 2	0.034 4	0.000 7	205.6	21.3	216.9	4.3	217.8	4.4
Q607	594	1 714	2 157	0.79	0.050 5	0.000 5	0.238 2	0.002 8	0.034 2	0.000 2	216.7	24.1	217.0	2.3	216.7	1.4
Q608	1 704	4 999	3 791	1.32	0.050 7	0.000 6	0.238 7	0.002 8	0.034 1	0.000 3	227.8	21.3	217.3	2.3	216.3	1.6
Q609	1 265	3 472	3 369	1.03	0.049 9	0.000 6	0.237 0	0.003 0	0.034 4	0.000 3	190.8	27.8	216.0	2.4	218.1	1.7
Q610	2 105	6 140	4 543	1.35	0.050 5	0.000 6	0.239 8	0.003 3	0.034 4	0.000 3	220.4	30.5	218.2	2.7	217.8	1.6
Q611	107	276	795	0.35	0.048 7	0.001 1	0.232 1	0.005 7	0.034 6	0.000 5	200.1	53.7	211.9	4.7	219.2	3.1
Q612	2 034	5 832	4 136	1.41	0.049 9	0.000 6	0.236 1	0.003 0	0.034 3	0.000 3	190.8	25.9	215.2	2.4	217.3	1.8
Q613	2 876	7 982	6 734	1.19	0.049 8	0.000 6	0.235 9	0.003 1	0.034 3	0.000 3	183.4	23.1	215.0	2.6	217.5	1.8
Q614	1 570	4 681	3 500	1.34	0.049 2	0.000 7	0.232 3	0.004 5	0.034 2	0.000 4	166.8	33.3	212.1	3.7	216.7	2.8
Q615	2 212	6 490	4 799	1.35	0.049 6	0.000 6	0.235 7	0.003 0	0.034 4	0.000 3	189.0	27.8	214.9	2.5	218.1	1.9
Q616	1 394	4 012	3 394	1.18	0.050 3	0.000 7	0.239 7	0.004 1	0.034 5	0.000 4	209.3	33.3	218.1	3.4	218.8	2.5
Q617	233	638	1 198	0.53	0.049 1	0.000 7	0.234 9	0.004 8	0.034 7	0.000 6	153.8	33.3	214.2	3.9	219.7	3.6
Q618	853	2 490	2 639	0.94	0.050 0	0.000 5	0.236 6	0.002 8	0.034 3	0.000 3	194.5	24.1	215.7	2.3	217.4	1.6
Q619	1 845	5 149	4 735	1.09	0.050 0	0.000 6	0.236 5	0.003 1	0.034 3	0.000 3	194.5	27.8	215.6	2.5	217.6	1.6
Q620	1 530	4 440	3 775	1.18	0.049 4	0.000 5	0.233 8	0.004 3	0.034 3	0.000 6	168.6	22.2	213.4	3.5	217.5	3.5
Q621	66	163	478	0.34	0.049 2	0.001 1	0.232 2	0.005 0	0.034 3	0.000 4	153.8	51.8	212.0	4.1	217.3	2.4
Q622	1 211	3 457	3 097	1.12	0.049 9	0.000 5	0.234 8	0.002 6	0.034 1	0.000 2	190.8	24.1	214.1	2.1	216.0	1.6
Q623	613	1 573	3 649	0.43	0.049 6	0.000 4	0.233 2	0.002 6	0.034 2	0.000 3	176.0	20.4	212.8	2.1	216.6	1.6
Q624	432	1 044	4 195	0.25	0.049 7	0.000 5	0.235 4	0.003 4	0.034 4	0.000 4	189.0	22.2	214.6	2.8	217.9	2.7
Q625	1 177	3 447	3 225	1.07	0.050 3	0.000 6	0.236 3	0.003 4	0.034 1	0.000 3	209.3	23.1	215.4	2.8	216.0	1.8
Q626	329	903	1 349	0.67	0.049 8	0.000 6	0.235 0	0.003 3	0.034 3	0.000 4	187.1	25.0	214.3	2.7	217.1	2.5
Q627	166	444	1 472	0.30	0.049 6	0.001 0	0.234 8	0.006 4	0.034 3	0.000 7	176.0	52.8	214.1	5.3	217.6	4.1
Q628	583	1 448	3 608	0.40	0.051 1	0.000 5	0.242 1	0.002 8	0.034 4	0.000 2	242.7	56.5	220.1	2.3	217.8	1.5
Q629	1 635	4 808	3 597	1.34	0.049 4	0.000 5	0.234 3	0.002 9	0.034 4	0.000 3	164.9	20.4	213.7	2.4	217.8	1.7
Q630	1 505	3 648	3 991	0.91	0.049 8	0.000 5	0.237 8	0.003 2	0.034 6	0.000 3	183.4	22.2	216.6	2.6	219.2	2.0

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表 3 泉水沟岩体主量元素(%)、微量元素(10^-6)、稀土元素(10^-6)分析结果

Table 3. Compositions of major elements (%), trace elements (10^-6) and REE (10^-6) of the Quanshuigou pluton

样品	花岗闪长岩				石英闪长岩
样品	15QS01	15QS03	15QS04	15QS05	15QS06	15QS07	15QS08
SiO₂	67.21	67.56	68.18	68.85	58.30	59.38	58.83
TiO₂	0.42	0.42	0.38	0.40	0.64	0.63	0.75
Al₂O₃	15.65	15.31	15.37	14.97	16.46	15.87	16.69
Fe₂O₃	0.74	0.77	0.64	0.61	1.96	1.03	1.50
FeO	3.12	3.07	2.94	3.04	5.25	6.33	5.43
MnO	0.09	0.09	0.08	0.09	0.22	0.21	0.19
MgO	1.52	1.52	1.41	1.42	3.40	3.84	3.58
CaO	3.52	3.26	3.41	3.21	6.38	5.78	5.70
Na₂O	2.97	2.80	2.92	2.83	2.90	2.87	2.87
K₂O	3.58	3.96	3.50	3.53	2.06	2.16	2.31
P₂O₅	0.15	0.14	0.13	0.14	0.16	0.17	0.20
烧失量	0.98	1.05	0.84	0.86	2.18	1.65	1.88
总和	99.95	99.95	99.80	99.95	99.91	99.92	99.93
K₂O+Na₂O	6.55	6.76	6.42	6.36	4.96	5.03	5.18
K₂O/Na₂O	1.21	1.41	1.20	1.25	0.71	0.75	0.80
TFeO/MgO	2.49	2.48	2.49	2.53	2.06	1.89	1.89
δ	1.98	1.62	1.65	0.93	1.67	1.64	1.70
A/CNK	1.03	1.03	1.04	1.05	0.88	0.90	0.95
A/NK	1.79	1.72	1.79	1.77	2.35	2.25	2.31
Mg^#	46.48	46.88	46.09	45.43	53.58	51.95	54.03
AI	0.56	0.58	0.56	0.57	0.43	0.44	0.43
Pb	< 0.01	< 0.01	< 0.01	< 0.01	0.18	0.09	< 0.01
Zn	< 0.01	< 0.01	< 0.01	< 0.01	0.02	0.04	0.01
Cr	16.00	12.80	12.70	11.40	14.60	27.20	30.30
Ni	7.19	6.28	6.35	6.22	7.44	10.10	14.30
Co	13.20	10.20	10.60	10.60	19.40	19.70	20.00
Rb	41.50	59.40	122.00	58.50	77.60	79.50	67.80
Sr	145.00	134.00	247.00	161.00	242.00	216.00	223.00
Ba	441.00	448.00	518.00	444.00	344.00	243.00	363.00
V	66.20	65.40	64.50	62.20	212.00	144.00	171.00
Sc	12.30	15.10	16.10	13.20	31.20	23.50	22.50
Nb	9.42	9.24	8.84	9.02	10.70	7.63	8.93
Ta	1.04	1.09	1.07	1.24	1.08	0.80	0.92
Zr	106.00	114.00	132.00	112.00	63.50	127.00	104.00
Hf	3.42	3.49	3.87	3.61	2.08	3.71	2.98
Cs	5.26	5.66	6.96	7.98	6.23	5.26	7.32
U	1.99	1.80	2.13	1.69	4.48	2.58	2.08
Th	13.90	19.20	18.80	13.20	1.70	6.73	8.66
La	23.40	34.20	33.70	16.20	7.34	13.20	21.00
Ce	34.20	52.30	65.50	34.20	21.20	35.30	49.20
Pr	5.65	7.99	7.61	4.80	3.46	5.32	6.32
Nd	23.20	31.60	29.20	20.30	19.80	26.10	27.10
Sm	4.90	6.13	6.22	4.63	7.33	7.68	7.56
Eu	1.12	1.15	1.28	1.09	1.10	1.25	1.18
Gd	4.47	5.36	5.44	4.50	8.78	7.58	7.38
Tb	0.65	0.76	0.80	0.68	1.37	1.12	1.12
Dy	3.56	4.22	4.21	3.91	8.80	6.62	6.45
Ho	0.72	0.82	0.83	0.84	1.86	1.40	1.33
Er	2.05	2.32	2.37	2.45	5.30	3.83	3.62
Tm	0.32	0.35	0.36	0.37	0.78	0.56	0.54
Yb	2.01	2.22	2.34	2.41	5.12	3.71	3.56
Lu	0.29	0.32	0.35	0.35	0.69	0.51	0.48
Y	20.80	24.00	24.40	24.80	49.30	40.80	39.40
Rb/Ba	0.09	0.13	0.24	0.13	0.23	0.33	0.19
Rb/Sr	0.29	0.44	0.49	0.36	0.32	0.37	0.30
Nb/Ta	9.06	8.48	8.26	7.27	9.91	9.54	9.71
Zr/Hf	30.99	32.66	34.11	31.02	30.53	34.23	34.90
∑REE	106.54	149.74	160.21	96.73	92.93	114.18	136.84
LREE	92.47	133.37	143.51	81.22	60.23	88.85	112.36
HREE	14.07	16.37	16.70	15.51	32.70	25.33	24.48
LREE/HREE	6.57	8.15	8.59	5.24	1.84	3.51	4.59
(La/Yb)_N	8.35	11.05	10.33	4.82	1.03	2.55	4.23
δEu	0.73	0.61	0.67	0.73	0.42	0.50	0.48
δCe	0.73	0.78	1.00	0.95	1.03	1.03	1.05
注：A/CNK = Al₂O₃/(CaO+Na₂O+K₂O)(mol); A/NK=Al₂O₃/(Na₂O+K₂O) (mol); AI= (Na₂O+K₂O)/Al₂O₃ (mol); δEu=(Eu_N)/$ \sqrt {{\rm{(S}}{{\rm{m}}_{\rm{N}}}{\rm{)}} \times {\rm{(G}}{{\rm{d}}_{\rm{N}}}{\rm{)}}} $; δCe=(Ce_N)/$\sqrt {{\rm{(L}}{{\rm{a}}_{\rm{N}}}{\rm{)}} \times {\rm{(P}}{{\rm{r}}_{\rm{N}}}{\rm{)}}} $.

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