Effect of Mixing Effect and Scale-Dependent Dispersion for Radial Solute Transport near the Injection Well
-
摘要: 径向弥散是指溶质在径向流场下的迁移规律,被广泛用于描述含水层修复领域中污染物的迁移过程.然而,在现有描述径向弥散的模型中,往往忽略了井内混合效应对溶质径向弥散的影响.建立新的注入井附近溶质径向运移动力学模型,同时考虑井内混合效应与弥散度的尺度效应.采用Laplace变换推导该模型的半解析解,利用Stehfest数值逆变换获取溶质在实数空间的解.通过与不考虑混合效应的模型对比研究混合效应对溶质径向弥散的影响,并利用室内渗流槽中的溶质径向弥散实验数据验证模型的合理性与适用性.结果表明:混合效应和尺度效应对注水井附近溶质径向弥散有显著影响.具体地讲,井内的混合效应越显著,在井壁处及含水层中的穿透曲线越低,溶质浓度达到峰值所需时间越长,与不考虑混合效应模型的差异越明显;随尺度效应的增强,溶质提前穿透且扩散范围变大,溶质浓度达到峰值所需时间越长;与前人的模型相比,本研究模型能更好地模拟注水井附近的溶质径向弥散问题.Abstract: Radial solute transport refers to a dispersive transport process of a solute under a radial flow field, which has been widely used to describe the solute transport around the well in aquifer remediation. However, in the previous studies, the mixing effect in the wellbore has often been ignored, assuming that the wellbore is infinitely small or the concentration of the wellbore is constant during the injection period. In this study, a new mathematical model to describe radial solute transport of the injection well is proposed considering both the mixing effect and scale effect. The analytical solution is derived by the Laplace transform and Stehfest numerical inversion method. The linear dispersion model with mixing effect (LDM) is compared with the linear dispersion model with no-mixing effect (LDNM) to illustrate the mixing effect and the scale effect. Moreover, the robustness of the new model is tested using the experimental data. The results show that mixing effect and scale effect have a great influence on radial solute transport. Specifically, the greater mixing effect results in the lower the breakthrough curves (BTCs) in both wellbore and aquifer, the longer time for the solute concentration to reach its peak. With the well radius increasing, the difference between the models with and without mixing effect is more obvious. Additionally, with the increase of scale-dependent dispersion, the arrival time of the BTC peak values decreases. LDM (linear dispersion model with mixing effect) is more reasonable than LDNM (linear dispersion model with no-mixing effect) in describing radial solute transport.
-
表 1 溶质不同注入条件下的特定解析解
Table 1. The specific solution under different boundary conditions
溶质注入边界条件 LDM LDNM Laplace空间下的解 浓度通量连续 $C_{1}=\frac{C_{0} /(s \beta+1)}{s \varepsilon k r_{\mathrm{w}}^{\gamma+1} K_{\gamma+1}\left(\varepsilon r_{\mathrm{w}}\right)}$ $C_{1}=\frac{C_{0}}{s \varepsilon k r_{\mathrm{w}}^{\gamma+1} K_{\gamma+1}\left(\varepsilon r_{\mathrm{w}}\right)}$ $\bar{C}_{r}=C_{1} r^{\gamma} K_{\gamma}(\varepsilon r)$ 瞬时注入 $C_{1}=\frac{M /(s \beta+1)}{Q \varepsilon k r_{\mathrm{w}}^{\gamma+1} K_{\gamma+1}\left(\varepsilon r_{\mathrm{w}}\right)}$ $C_{1}=\frac{M}{Q \varepsilon k r_{\mathrm{w}}^{\gamma+1} K_{\gamma+1}\left(\varepsilon r_{\mathrm{w}}\right)}$ $\bar{C}_{r}=C_{1} r^{\gamma} K_{\gamma}(\varepsilon r)$ -
Bharati, V. K., Singh, V. P., Sanskrityayn, A., et al., 2017. Analytical Solution of Advection-Dispersion Equation with Spatially Dependent Dispersivity. Journal of Engineering Mechanics, 143(11):04017126. https://doi.org/10.1061/(asce)em.1943-7889.0001346 Chen, C. S., 1987. Analytical Solutions for Radial Dispersion with Cauchy Boundary at Injection Well. Water Resources Research, 23(7):1217-1224. https://doi.org/10.1029/wr023i007p01217 Chen, H. T., Chen, C.O.K., 1988. Hybrid Laplace Transform/Finite Difference Method for Transient Heat Conduction Problems. International Journal for Numerical Methods in Engineering, 26(6):1433-1447. https://doi.org/10.1002/nme.1620260613 Chen, H.T., Chen, T.M., Chen, C.O.K., 1987. Hybrid Laplace Transform/Finite Element Method for One-Dimensional Transient Heat Conduction Problems. Computer Methods in Applied Mechanics and Engineering, 63(1):83-95. https://doi.org/10.1029/WR023i007p01217 Chen, J. S., Liu, C. W., Chen, C. S., et al., 1996. A Laplace Transform Solution for Tracer Tests in a Radially Convergent Flow Field with Upstream Dispersion. Journal of Hydrology, 183(3-4):263-275. https://doi.org/10.1016/0022-1694(95)02972-9 Cheng, J.M., 2002.Analysis on Field Scale Effect of Dispersivity in Consideration of Relative Reliability Level of Data. Journal of Hydraulic Engineering, 33(2):90-94(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=slxb200202016 de Hoog F.R., Knight, J.H., Stokes, A.N., 1982.An Improved Method for Numerical Inversion of Laplace Transforms. SIAM Journal on Scientific and Statistical Computing, 3(3):357-366. https://doi.org/10.1137/0903022 Dubner, H., Abate, J., 1968. Numerical Inversion of Laplace Transforms by Relating Them to the Finite Fourier Cosine Transform. Journal of the ACM, 15(1):115-123. https://doi.org/10.1145/321439.321446 Gao, G.Y., Feng, S.Y., Huo, Z.L., et al., 2009.Semi-Analytical Solution for Solute Radial Transport Dynamic Model with Scale-Dependent Dispersion. Journal of Hydrodynamics(Ser.A), 24(2):156-163(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sdlxyjyjz200902005 Gelhar, L. W., Welty, C., Rehfeldt, K. R., 1992. A Critical Review of Data on Field-Scale Dispersion in Aquifers. Water Resources Research, 28(7):1955-1974. https://doi.org/10.1029/92wr00607 Gu, H.C., Wang, Q.R., Zhan, H.B., 2018. An Improved Approach in Modeling Injection-Withdraw Test of the Partially Penetrating Well. Earth Science(in Chinese with English abstract). http://kns.cnki.net/kcms/detail/42.1874.p.20181116.0912.008.html Han, C., Kang, J., Choe, J., 2003. Finite Difference Modeling for Scale-Dependent Dispersivity in a Fractured Medium. Energy Sources, 25(4):265-278. https://doi.org/10.1080/00908310390142316 Huang, J. Q., Liu, C. Q., 1986. Analytical Solution of Partial Differential Equations for Radial Transport of a Solute in Double Porous Media. Applied Mathematics and Mechanics, 7(4):327-336. https://doi.org/10.1007/bf01898222 Lai, K. H., Liu, C. W., Liang, C. P., et al., 2016. A Novel Method for Analytically Solving a Radial Advection-Dispersion Equation. Journal of Hydrology, 542:532-540. https://doi.org/10.1016/j.jhydrol.2016.09.027 Li, G.M., Chen, C.X., 1995.Fractal Geometry and Estimation of Scale-Dependent Dispersivity in Geologic Media. Earth Science, 20(4):405-409(in Chinese with English abstract). McGuire, J. T., Long, D. T., Klug, M. J., et al., 2002. Evaluating Behavior of Oxygen, Nitrate, and Sulfate during Recharge and Quantifying Reduction Rates in a Contaminated Aquifer. Environmental Science & Technology, 36(12):2693-2700. https://doi.org/10.1021/es015615q Mishra, S., Parker, J. C., 1990. Analysis of Solute Transport with a Hyperbolic Scale-Dependent Dispersion Model. Hydrological Processes, 4(1):45-57. https://doi.org/10.1002/hyp.3360040105 Moench, A. F., Ogata, A., 1981. A Numerical Inversion of the Laplace Transform Solution to Radial Dispersion in a Porous Medium. Water Resources Research, 17(1):250-252. https://doi.org/10.1029/wr017i001p00250 Novakowski, K. S., 1992a. An Evaluation of Boundary Conditions for One-Dimensional Solute Transport:1. Mathematical Development. Water Resources Research, 28(9):2399-2410. https://doi.org/10.1029/92wr00593 Novakowski, K. S., 1992b. An Evaluation of Boundary Conditions for One-Dimensional Solute Transport:2. Column Experiments. Water Resources Research, 28(9):2411-2423. https://doi.org/10.1029/92wr00592 Ogata, A., 1958. Dispersion in Porous Media(Dissertation). Northwestern University, Evanston, lllinois. Phanikumar, M. S., McGuire, J. T., 2010. A Multi-Species Reactive Transport Model to Estimate Biogeochemical Rates Based on Single-Well Push-Pull Test Data. Computers & Geosciences, 36(8):997-1004. https://doi.org/10.1016/j.cageo.2010.04.001 Pickens, J. F., Grisak, G. E., 1981a. Modeling of Scale-Dependent Dispersion in Hydrogeologic Systems. Water Resources Research, 17(6):1701-1711. https://doi.org/10.1029/wr017i006p01701 Pickens, J. F., Grisak, G. E., 1981b. Scale-Dependent Dispersion in a Stratified Granular Aquifer. Water Resources Research, 17(4):1191-1211. https://doi.org/10.1029/wr017i004p01191 Ren, L., 1994.A Hybrid Laplace Transform Finite Element Method for Solute Radial Dispersion Problem in Subsurface Flow. Journal of Hydrodynamics(Ser.A), 9(1):37-43(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199400399541 Schapery, R.A., 1962. Approximate Methods of Transform Inversion for Viscoelastic Stress Analysis. Proc. Fourth USN at Congr. Appl. Mech., 2:1075-1085. http://cn.bing.com/academic/profile?id=404faa0d2b48fffb86324f69c0e6e983&encoded=0&v=paper_preview&mkt=zh-cn Schulze-Makuch, D., 2005. Longitudinal Dispersivity Data and Implications for Scaling Behavior. Ground Water, 43(3):443-456. https://doi.org/10.1111/j.1745-6584.2005.0051.x Stehfest, H., 1970a. Algorithm 368:Numerical Inversion of Laplace Transforms[D5]. Communications of the ACM, 13(1):47-49. https://doi.org/10.1145/361953.361969 Stehfest, H., 1970b. Remark on Algorithm 368:Numerical Inversion of Laplace Transforms. Communications of the ACM, 13(10):624. https://doi.org/10.1145/355598.362787 Tang, D. H., Babu, D. K., 1979. Analytical Solution of a Velocity Dependent Dispersion Problem. Water Resources Research, 15(6):1471-1478. https://doi.org/10.1029/wr015i006p01471 Valocchi, A. J., 1986. Effect of Radial Flow on Deviations from Local Equilibrium during Sorbing Solute Transport through Homogeneous Soils. Water Resources Research, 22(12):1693-1701. https://doi.org/10.1029/wr022i012p01693 Wang, Q., Shi, W., Zhan, H., et al., 2018. Models of Single-Well Push-Pull Test with Mixing Effect in the Wellbore. Water Resources Research, 54(12):10155-10171. https://doi.org/10.1029/2018WR023317 Wang, Q. R., Zhan, H. B., 2013. Radial Reactive Solute Transport in an Aquifer-Aquitard System. Advances in Water Resources, 61(11):51-61. https://doi.org/10.1016/j.advwatres.2013.08.013 Wang, Q. R., Zhan, H. B., 2015. On Different Numerical Inverse Laplace Methods for Solute Transport Problems. Advances in Water Resources, 75:80-92. https://doi.org/10.1016/j.advwatres.2014.11.001 Yates, S.R., 1990. An Analytical Solution for One-Dimensional Transport in Heterogeneous Porous Media. Water Resources Research, 26(10):2331-2338. https://doi.org/10.1029/wr026i010p02331 You, K. H., Zhan, H. B., 2013. New Solutions for Solute Transport in a Finite Column with Distance-Dependent Dispersivities and Time-Dependent Solute Sources. Journal of Hydrology, 487(2):87-97. https://doi.org/10.1016/j.jhydrol.2013.02.027 Zhang, D.S., Chang, A.D., Shen, B., et al., 2005.Quasi-Analytical Solution and Numerical Simulation for Advection-Dispersion Model of Adsorbed Solute Transport through Soils under Steady State Flow. Journal of Hydrodynamics(Ser.A), 20(2):226-232(in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sdlxyjyjz200502014 成建梅, 2002.考虑可信度的弥散度尺度效应分析.水利学报, 33(2):90-94. doi: 10.3321/j.issn:0559-9350.2002.02.016 高光耀, 冯绍元, 霍再林, 等, 2009.考虑弥散尺度效应的溶质径向运移动力学模型及半解析解.水动力学研究与进展(A辑), 24(2):156-163. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sdlxyjyjz200902005 顾昊琛, 王全荣, 詹红兵, 2018.非完整井下单井注抽试验数值模拟方法改进.地球科学. http://kns.cnki.net/kcms/detail/42.1874.p.20181116.0912.008.html 李国敏, 陈崇希, 1995.空隙介质水动力弥散尺度效应的分形特征及弥散度初步估计.地球科学, 20(4):405-409. http://www.earth-science.net/article/id/232 任理, 1994.地下水溶质径向弥散问题的混合拉普拉斯变换有限单元解.水动力学研究与进展(A辑), 9(1):37-43. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199400399541 张德生, 常安定, 沈冰, 等, 2005.土壤中吸附性溶质运移对流-弥散模型的准解析解及其数值模拟.水动力学研究与进展(A辑), 20(2):226-232. http://d.old.wanfangdata.com.cn/Periodical/sdlxyjyjz200502014