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    辽东半岛隆昌地区~2 113 Ma变辉长岩地球化学与Hf同位素研究:对胶辽吉造山带构造演化的制约

    赵岩 寇林林 张朋 毕中伟 李东涛 陈聪

    赵岩, 寇林林, 张朋, 毕中伟, 李东涛, 陈聪, 2019. 辽东半岛隆昌地区~2 113 Ma变辉长岩地球化学与Hf同位素研究:对胶辽吉造山带构造演化的制约. 地球科学, 44(10): 3333-3345. doi: 10.3799/dqkx.2019.185
    引用本文: 赵岩, 寇林林, 张朋, 毕中伟, 李东涛, 陈聪, 2019. 辽东半岛隆昌地区~2 113 Ma变辉长岩地球化学与Hf同位素研究:对胶辽吉造山带构造演化的制约. 地球科学, 44(10): 3333-3345. doi: 10.3799/dqkx.2019.185
    Zhao Yan, Kou Linlin, Zhang Peng, Bi Zhongwei, Li Dongtao, Chen Cong, 2019. Characteristics of Geochemistry and Hf Isotope from Meta-Gabbro in Longchang Area, Liaodong Peninsula: Implications on Evolution of the Jiao-Liao-Ji Paleoproterozoic Orogenic Belt. Earth Science, 44(10): 3333-3345. doi: 10.3799/dqkx.2019.185
    Citation: Zhao Yan, Kou Linlin, Zhang Peng, Bi Zhongwei, Li Dongtao, Chen Cong, 2019. Characteristics of Geochemistry and Hf Isotope from Meta-Gabbro in Longchang Area, Liaodong Peninsula: Implications on Evolution of the Jiao-Liao-Ji Paleoproterozoic Orogenic Belt. Earth Science, 44(10): 3333-3345. doi: 10.3799/dqkx.2019.185

    辽东半岛隆昌地区~2 113 Ma变辉长岩地球化学与Hf同位素研究:对胶辽吉造山带构造演化的制约

    doi: 10.3799/dqkx.2019.185
    基金项目: 

    中国地质调查局项目 DD20190042-03

    国家重点研发计划项目 2016YFC0600108

    中国地质调查局项目 DD20190156

    国家重点研发计划项目 2018YFC0603804

    详细信息
      作者简介:

      赵岩(1985—), 男, 工程师, 主要从事辽东地区造山作用与成矿

    • 中图分类号: P595

    Characteristics of Geochemistry and Hf Isotope from Meta-Gabbro in Longchang Area, Liaodong Peninsula: Implications on Evolution of the Jiao-Liao-Ji Paleoproterozoic Orogenic Belt

    • 摘要: 辉长岩的成岩时代、成因等研究对限定胶辽吉造山带构造背景等关键问题具有重要意义.对其开展详细的岩石地球化学分析、全岩Nd同位素和锆石U-Pb测年及原位Hf同位素分析,结果显示样品受蚀变影响不大,TiO2含量较低(< 1.31%),FeOT(11.91%~14.25%)、MgO(6.88%~7.62%)含量不高,K2O含量中等偏高(0.85%~1.23%),属钙碱性-高钾钙碱性岩浆系列,岩石轻重稀土分馏不明显,富集Rb、Ba、K等大离子亲石元素,亏损高场强元素P、Hf等,岩石相对富集Nd同位素,εNdt)值介于-1.6~2.6,(176Hf/177Hf)i比值变化于0.281 497~0.281 612之间,εHft)值变化于2.2~6.3之间,模式年龄tDM1(Hf)值介于2.25~2.33 Ga.多种特征元素地球化学图解显示辉长岩具有E-MORB特征,与裂谷构造环境中产出的MORB和OIB不同.研究认为胶辽吉造山带在~2.1 Ga已存在洋壳俯冲,并可能已存在古岛弧,造山带演化过程中存在弧陆碰撞.

       

    • 图  1  胶辽吉造山带构造简图(a)和隆昌地区辉长岩地质简图(b)

      Fig.  1.  Geotectonic framwork of the Jiao-Liao-Ji orogenic belt (a) and simplified geological map of the gabbro in Longchang area, Liaodong peninsula(b)

      图  2  隆昌地区辉长岩野外照片(a, b)和镜下显微照片(单偏光)(c)(正交偏光)(d)

      Pl.斜长石;Ep.绿帘石;Act.阳起石

      Fig.  2.  Fieldwork pictures (a, b) and microphotographs (c, d) of the gabbro in Longchang area, Liaodong peninsula

      图  3  隆昌地区辉长岩Zr/TiO2-Nb/Y图解(a)和FeOT/MgO-SiO2分类图解(b)

      图a据Winchester and Floyd(1977); 图b据Miyashiro(1974)

      Fig.  3.  Zr/TiO2 vs. Nb/Y (a) and FeOT/MgO vs. SiO2 (b) diagrams for the gabbro samples from the Longchang area

      图  4  隆昌地区辉长岩样品典型锆石CL图和U-Pb测年结果

      Fig.  4.  Cathodoluminescence(CL) dqkx-44-10-3333s for zircon grains of gabbro sample showing sites of U-Pb analyses (a) and results(b) from the Longchang area

      图  5  隆昌地区辉长岩稀土元素配分曲线(a)和微量元素蛛网图(b)

      OIB, E-MORB, N-MORB及标准化数据来自Sun and McDonough(1989)

      Fig.  5.  Chondrite-normalized REE patterns(a) and primitive mantle-normalized trace element patterns (b) for gabbro samples from the Longchang area

      图  6  隆昌地区辉长岩Ti-Sm-V三角图解(a)和Th/Yb-Nb/Yb判别图解(b)

      Fig.  6.  Ti-Sm-V (a) and Th/Yb-Nb/Yb (b) discrimination plots for the gabbro samples from the Longchang area

      图  7  隆昌地区辉长岩εNd(t)-(La/Sm)N (a)和εNd(t)-t (b)图解

      Fig.  7.  Plots of εNd(t) vs. (La/Sm)N (a) and εNd(t) vs. t (b) for the gabbro samples from the Longchang area

      图  8  隆昌地区辉长岩锆石Hf同位素组成(a)与εNd(t)-εHf(t)(b)图解

      图a据Griffin et al.(2002);图b据 Vervoort et al.(1999)

      Fig.  8.  Hf isotopic compositions of zircons(a) and εNd(t) vs. εHf(t) diagram(b) for the gabbro samples from the Longchang area

      表  1  隆昌地区辉长岩锆石U-Pb测年数据

      Table  1.   In-situ zircon U-Pb isotopic dating for gabbro in the Longchang area, Liaodong peninsula

      测试点 含量(10-6) Th/U 同位素比值 同位素年龄(Ma)
      Th U 206Pb/238U 207Pb/235U 206Pb/238U 207Pb/235U 207Pb/206Pb
      LC-1 110 351 0.31 6.338 6 0.152 6 0.369 0 0.004 2 2 025 19.6 2 024 21.2 2 010 41.5
      LC-2 161 196 0.82 6.894 9 0.128 9 0.378 9 0.002 9 2 071 13.5 2 098 16.6 2 118 31.6
      LC-3 1 046 892 1.17 5.1142 0.081 4 0.299 9 0.002 4 1 691 11.9 1 838 13.6 2 003 27.9
      LC-4 283 346 0.82 7.486 1 0.127 6 0.406 6 0.0040 2 199 18.6 2 171 15.3 2 139 21.1
      LC-5 327 303 1.08 7.377 5 0.125 3 0.402 4 0.003 5 2 180 16.1 2 158 15.3 2 131 28.1
      LC-6 174 273 0.64 6.986 1 0.133 6 0.378 7 0.003 1 2 070 14.7 2 110 17.0 2 140 31.3
      LC-7 367 280 1.31 6.351 3 0.1144 0.349 9 0.002 7 1 934 12.8 2 026 15.9 2 122 31.2
      LC-8 201 241 0.83 7.347 2 0.131 0 0.393 1 0.003 1 2 137 14.5 2 155 16.0 2 162 29.9
      LC-9 128 165 0.78 7.294 1 0.1404 0.388 4 0.003 4 2 115 15.7 2 148 17.2 2 172 33.3
      LC-10 147 172 0.86 7.563 6 0.159 9 0.397 8 0.003 7 2 159 17.2 2 181 19.0 2 192 37.0
      LC-11 303 332 0.91 7.548 7 0.168 4 0.398 5 0.003 5 2 162 16.4 2 179 20.1 2 184 40.4
      LC-12 202 264 0.77 7.475 1 0.197 9 0.396 7 0.0046 2 154 21.2 2 170 23.8 2 176 52.6
      LC-13 585 702 0.83 5.231 3 0.122 6 0.296 3 0.002 6 1 673 12.9 1 858 20.0 2 057 42.6
      LC-14 284 339 0.84 7.327 5 0.185 1 0.393 2 0.003 9 2 138 18.1 2 152 22.6 2 150 42.4
      LC-15 299 313 0.95 7.485 4 0.148 6 0.396 6 0.003 9 2 153 17.8 2 171 17.8 2 173 33.6
      LC-16 184 232 0.79 7.383 9 0.138 3 0.396 0 0.003 6 2 151 16.8 2 159 16.8 2 154 31.6
      LC-17 134 206 0.65 7.267 1 0.137 2 0.392 7 0.003 7 2 136 17.1 2 145 16.9 2 139 32.1
      LC-18 168 215 0.78 7.1447 0.136 9 0.387 9 0.003 7 2 113 17.1 2 130 17.1 2 131 33.5
      LC-19 190 251 0.76 7.334 0 0.141 4 0.405 0 0.0045 2 192 20.7 2 153 17.3 2 103 33.6
      LC-20 33 65 0.51 7.918 5 0.169 0 0.435 4 0.005 2 2 330 23.2 2 222 19.3 2 115 37.3
      LC-21 371 369 1.00 7.109 9 0.112 4 0.392 2 0.003 3 2 133 15.1 2 125 14.2 2 106 27.2
      LC-22 209 244 0.86 7.139 1 0.121 9 0.394 5 0.003 7 2 144 16.9 2 129 15.3 2 102 28.9
      LC-23 223 265 0.84 7.776 3 0.149 7 0.424 3 0.005 5 2 280 24.7 2 205 17.4 2 128 28.7
      LC-24 197 250 0.79 7.003 6 0.129 6 0.391 0 0.003 5 2 127 16.4 2 112 16.5 2 088 32.7
      LC-25 137 238 0.58 6.643 7 0.125 3 0.374 5 0.003 1 2 051 14.5 2 065 16.7 2 069 32.7
      LC-26 359 382 0.94 7.181 6 0.123 2 0.396 5 0.003 6 2 153 16.8 2 134 15.4 2 105 27.8
      LC-27 106 146 0.72 7.371 8 0.135 9 0.408 9 0.0040 2 210 18.5 2 158 16.5 2 098 25.0
      LC-28 548 444 1.24 7.045 8 0.113 0 0.389 2 0.002 9 2 119 13.5 2 117 14.3 2 103 27.6
      LC-29 293 337 0.87 7.198 9 0.1341 0.397 4 0.0045 2 157 20.6 2 136 16.7 2 106 29.3
      LC-30 1 368 753 1.82 6.495 6 0.138 3 0.358 2 0.0047 1 974 22.3 2 045 18.8 2 106 32.4
      LC-31 270 329 0.82 7.432 8 0.145 4 0.409 9 0.0040 2 214 18.4 2 165 17.6 2 109 32.3
      LC-32 159 179 0.89 7.417 7 0.135 3 0.408 0 0.003 9 2 206 18.1 2 163 16.4 2 117 31.3
      LC-33 326 357 0.91 6.551 3 0.102 7 0.375 8 0.003 3 2 056 15.6 2 053 13.9 2 043 26.8
      LC-34 268 278 0.96 7.245 2 0.123 3 0.400 1 0.003 9 2 170 17.9 2 142 15.3 2 109 27.5
      LC-35 185 208 0.89 7.197 5 0.122 9 0.397 6 0.003 6 2 158 16.5 2 136 15.3 2 109 27.8
      LC-36 262 288 0.91 7.283 1 0.1343 0.409 3 0.0043 2 212 19.6 2 147 16.5 2 079 29.5
      LC-37 267 290 0.92 7.071 4 0.1306 0.401 0 0.003 9 2 174 18.0 2 120 16.5 2 062 30.6
      LC-38 43 101 0.42 7.298 3 0.138 4 0.406 5 0.0040 2 199 18.2 2 149 17.0 2 094 31.2
      LC-39 983 530 1.86 5.033 4 0.099 6 0.303 4 0.0041 1 708 20.5 1 825 16.8 1 950 25.9
      LC-40 377 395 0.95 6.987 5 0.107 6 0.397 8 0.003 3 2 159 15.4 2 110 13.8 2 054 25.9
      下载: 导出CSV

      表  2  隆昌地区辉长岩主微量元素数据(主量元素的单位为%, 微量元素的单位为10-6

      Table  2.   Whole rock chemical compositions of gabbro samples in the Longchang area, Liaodong peninsula

      样号 LC-1 LC-2 LC-3 LC-4 LC-5
      SiO2 46.67 45.83 48.42 46.72 47.65
      TiO2 1.09 1.30 1.24 1.22 1.31
      AI2O3 13.75 14.00 13.80 13.31 14.71
      Fe2O3 4.29 3.28 3.85 4.18 4.03
      FeO 8.63 10.29 9.21 9.57 7.87
      MnO 0.17 0.20 0.19 0.21 0.15
      MgO 7.62 7.32 7.36 7.37 6.88
      CaO 8.79 7.50 8.68 9.35 8.83
      Na2O 2.62 1.77 2.98 2.35 3.52
      K2O 1.23 1.10 0.85 1.08 1.13
      P2O5 0.083 0.130 0.130 0.120 0.088
      LOI 5.00 7.05 3.65 4.66 3.54
      SUM 99.94 99.76 100.36 100.12 99.70
      Hf 0.37 0.38 0.45 0.36 0.49
      Ta 0.25 0.70 0.55 0.86 0.75
      Li 16.4 29.2 15.4 16.7 13.5
      Be 0.50 0.48 0.63 0.55 1.44
      Sc 41.6 42.3 42.3 43.3 59.7
      Ni 51.6 47.5 50.4 53.7 31.3
      Cs 0.83 0.75 0.53 0.37 0.79
      Th 1.50 1.03 0.98 1.02 0.67
      U 0.22 0.24 0.26 0.23 0.29
      Ba 231 204 130 255 165
      Pb 3.14 3.27 3.33 4.15 6.32
      Nb 5.72 7.54 7.44 7.86 9.29
      Rb 59.4 53.4 42.5 38.4 55.6
      Sr 150 121 132 168 159
      Zr 55.6 91.4 91.0 89.7 97.1
      La 5.45 7.89 7.62 7.93 8.20
      Ce 12.8 18.9 18.0 18.8 16.9
      Pr 1.77 2.62 2.48 2.55 2.55
      Nd 8.73 12.80 12.20 12.50 12.50
      Sm 2.32 3.28 3.16 3.26 3.52
      Eu 0.80 0.97 0.93 0.99 0.99
      Gd 2.45 3.50 3.40 3.51 4.26
      Tb 0.47 0.66 0.66 0.65 0.78
      Dy 3.08 4.29 4.19 4.25 5.42
      Ho 0.65 0.88 0.88 0.89 1.07
      Er 1.85 2.49 2.44 2.49 3.04
      Tm 0.30 0.39 0.40 0.40 0.49
      Yb 2.07 2.71 2.72 2.74 3.20
      Lu 0.29 0.37 0.38 0.38 0.39
      Y 16.5 22.9 22.7 22.9 28.3
      EREE 43.01 61.76 59.45 61.35 63.35
      LREE 31.85 46.45 44.39 46.04 44.70
      HREE 11.16 15.3 15.06 15.31 18.66
      (La/Yb)N 1.88 2.08 2.01 2.08 1.84
      δEu 1.02 0.87 0.86 0.89 0.78
      下载: 导出CSV

      表  3  隆昌地区辉长岩锆石原位Hf同位素组成

      Table  3.   In-situ zircon Hf isotopic data for gabbro in the Longchang area, Liaodong peninsula

      点号 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf (176Hf/177Hf)i SHf(t) tDM1 tDM2
      LCZ-1 0.098 214 0.002 597 0.281 660 0.000 020 0.281 556 4.2 2 327 2 440
      LCZ-2 0.083 844 0.002 226 0.281 651 0.000018 0.281 562 4.5 2 317 2 427
      LCZ-3 0.155 910 0.003 544 0.281 728 0.000019 0.281 585 5.3 2 290 2 376
      LCZ-4 0.122 781 0.003 332 0.281 686 0.000018 0.281 552 4.1 2 337 2 449
      LCZ-5 0.141 439 0.003 430 0.281 703 0.000022 0.281 565 4.6 2 318 2 419
      LCZ-6 0.104 470 0.003 238 0.281 741 0.000037 0.281 610 6.2 2 251 2 321
      LCZ-7 0.079 143 0.002 104 0.281 671 0.000020 0.281 586 5.3 2 281 2 374
      LCZ-8 0.085 358 0.002 076 0.281 684 0.000015 0.281 601 5.8 2 261 2 342
      LCZ-9 0.102 462 0.002 562 0.281 673 0.000020 0.281 570 4.7 2 307 2 410
      LCZ-10 0.077 420 0.001 973 0.281 683 0.000016 0.281 603 5.9 2 256 2 336
      LCZ-11 0.140 272 0.003 607 0.281 757 0.000019 0.281 612 6.3 2 250 2 316
      LCZ-12 0.100 750 0.002 549 0.281 700 0.000019 0.281 597 5.7 2 267 2 349
      LCZ-13 0.105 547 0.003 020 0.281 619 0.000017 0.281 497 2.2 2 414 2 568
      LCZ-14 0.182 231 0.005 223 0.281 803 0.000020 0.281 593 5.6 2 287 2 360
      LCZ-15 0.154 204 0.003 991 0.281 728 0.000016 0.281 567 4.7 2 319 2 416
      注:所有点号的年龄都取2 113 Ma计算Hf同位素值.
      下载: 导出CSV

      表  4  隆昌地区辉长岩Nd同位素组成

      Table  4.   Whole rock Nd isotopic compositions for gabbro in the Longchang area, Liaodong peninsula

      点号 Sm Nd 147Sm/144Nd 143Nd/144Nd εNd TDM1(Ma) TDM2(Ma)
      LC-1 2.32 8.73 0.160 56 0.509 909 0.000009 0.2 2 873 2 536
      LC-2 3.28 12.8 0.154 39 0.510032 0.000011 2.6 2 482 2 342
      LC-3 3.16 12.2 0.156 62 0.509 981 0.000010 1.6 2 631 2 423
      LC-4 3.26 12.5 0.157 28 0.509 863 0.000015 -0.7 2 949 2 607
      LC-5 3.52 12.5 0.17008 0.509 819 0.000006 -1.6 3 346 2 677
      注:所有点号的年龄都取2 113 Ma计算Hf同位素值.
      下载: 导出CSV
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