Application of Mineral-Based Composite Materials for Aquatic Environmental Pollution Control: Properties, Mechanisms and Performances
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摘要: 矿物基复合材料融合了矿物材料的特性和复合材料的优势, 因其独特的功效而成为生态环境研究领域的热点, 已被广泛应用于水环境质量提升的工程实践中.综述了矿物基复合材料的结构与性能提升方法, 包括酸/碱刻蚀、热活化改性、表面改性及金属纳米颗粒负载改性, 并探讨了其高效固定/去除水环境中重金属、有机及无机污染物的机制, 包括吸附作用、催化反应及其与水体微生物和水生植物等水生生物的联合作用.矿物基复合材料可以通过强化生物生态修复, 促进水生植物生长, 增强微生物多样性, 从而进一步改善水环境质量.总结了矿物基复合材料在水环境治理中的工程应用案例, 并强调了未来重点研究方向, 评估其在不同水质环境下的效能及长期影响, 探索与先进技术的最佳联合应用, 优化生产工艺和材料成本.Abstract: Due to the coupled effects of the properties of minerals and the advantages offered by composite materials, mineral-based composite materials have exhibited unique performances and attracted significant attention in the field of eco-environmental studies with extensive applications in improving water quality. This paper reviews various methods for enhancing the structure and properties of mineral-based composites materials, including acid/alkali etching, thermal activation modification, surface modification, and metal nanoparticle load modification. The mechanisms of these materials in effectively fixing/removing heavy metals, organic and inorganic pollutants in the aquatic environmental pollutants include adsorption, catalytic reactions, and synergistic effects with aquatic organisms such as microorganisms and aquatic plants. Mineral-based composite material plays a vital role in advancing biological ecological restoration, promoting the growth of aquatic plants, and enhancing microbial diversity. And the paper summarizes application cases of mineral-based composite materials in water environment restoration and management, and emphasizes the focus of future research on assessing their performance and long-term effects in different water quality environments, exploring best approaches of their joint application with other advanced techniques, and optimizing their manufacturing processes and material costs.
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图 1 矿物材料联合水生生物协同提升水环境质量（据Liu et al., 2024修改）
Fig. 1. Synergistic enhancement of water environment quality through collaborative utilization of mineral materials and aquatic organisms （modified from Liu et al., 2024）
图 2 改性矿物材料提升湖泊底质碳氮磷生物地球化学转化（据Liu et al., 2020b修改）
Fig. 2. Enhanced biogeochemical transformation of carbon, nitrogen, and phosphorus in lake sediments with modified mineral materials （modified from Liu et al., 2020b）
表 1 矿物基复合材料在水环境治理中的典型工程应用案例
Table 1. Representative full scale projects of aquatic environmental pollution control using mineral-based composite materials
实施地点 恢复方法 恢复机制 恢复效果 成都市毗河九道堰段 麦饭石覆盖氮磷污染底泥 麦饭石的阻隔作用和吸附作用 底泥表层间隙水氨氮浓度保持在10 mg/L以下, 对表层沉积物磷阻隔率达到70%以上（胡易坤等, 2020） 同济大学三好坞富营养化景观水体 无机盐改性沸石覆盖污染底泥 沸石覆盖层的机械阻挡作用, CaCl2改性沸石离子交换作用, 沸石材料的吸附作用 CaCl2改性沸石覆盖后上覆水氨氮浓度0.42~0.60 mg/L, 对照为8.25 mg/L, 对底泥磷的抑制率达到81%（林建伟等, 2007） 江苏太湖 铝和锆改性沸石实验室处理太湖底泥 铝和锆改性沸石的配位体交换作用和沸石的吸附作用 改性沸石对太湖底泥磷释放均低于0.05 mg/L以下, 对照均大于0.085 mg/L（杨孟娟等, 2014） 安徽巢湖 改性硅藻土实验室除磷试验 改性硅藻土絮凝沉降作用 总磷去除率基本达到85%以上（郑西强等, 2019） 杭州西湖 底质改良材料覆盖底泥并包种沉水植物根部 底质改良材料改良底泥氧化还原电位, 抑制氮磷营养盐释放, 促进沉水植物生长, 营造根际有益微生态系统 恢复后的水质从Ⅳ类改善至Ⅲ类, 对表层沉积物总磷去除率达到55%, 沉水植物生物量从0.31 kg/m2提高至1.45 kg/m2, 盖度稳定维持在80%以上（Bai et al., 2020, 2023; Liu et al., 2022c） 苏格兰弗莱明顿湖 Phoslock锁磷剂与水混合后喷洒至水体表面 稀土元素镧与水体中磷形成不溶于水的磷酸镧沉淀物, 膨润土吸附作用 沉水植物物种数从修复前5种增加到修复后的12种, 特征种占比从修复前0%增加到修复后的28%（Gunn et al., 2014） 美国科罗拉多州 采用石灰石处理酸性矿水 化学中和作用 中和效率达90%（Skousen and Ziemkiewicz, 1996） 瑞典Finja湖和Vallentuna湖 采用硫酸铝对湖泊进行处理 铝盐絮凝作用 沉积物铁磷从2.16 mg/g降低至0 mg/g（Rydin and Welch, 1998） 澳大利亚墨尔本 城市雨水处理生物过滤器选择砂壤土和蛭石作为过滤介质 生物作用和吸附作用 有效降低氮磷浓度（Hatt et al., 2007） 新英格兰韦里斯克里克 采用天然沸石去除铵态氮 吸附作用 氨氮浓度从25 mg/L降低至1 mg/L以下（Booker et al., 1996） 
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