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    海南荔枝沟中三叠世酸性火山岩年代学、地球化学特征及其构造意义

    芶琪钰 钱鑫 何慧莹 张玉芝 王岳军

    芶琪钰, 钱鑫, 何慧莹, 张玉芝, 王岳军, 2019. 海南荔枝沟中三叠世酸性火山岩年代学、地球化学特征及其构造意义. 地球科学, 44(4): 1357-1370. doi: 10.3799/dqkx.2018.161
    引用本文: 芶琪钰, 钱鑫, 何慧莹, 张玉芝, 王岳军, 2019. 海南荔枝沟中三叠世酸性火山岩年代学、地球化学特征及其构造意义. 地球科学, 44(4): 1357-1370. doi: 10.3799/dqkx.2018.161
    Gou Qiyu, Qian Xin, He Huiying, Zhang Yuzhi, Wang Yuejun, 2019. Geochronological and Geochemical Constraints on Lizhigou Middle Triassic Felsic Volcanic Rocks in Hainan and Its Tectonic Implications. Earth Science, 44(4): 1357-1370. doi: 10.3799/dqkx.2018.161
    Citation: Gou Qiyu, Qian Xin, He Huiying, Zhang Yuzhi, Wang Yuejun, 2019. Geochronological and Geochemical Constraints on Lizhigou Middle Triassic Felsic Volcanic Rocks in Hainan and Its Tectonic Implications. Earth Science, 44(4): 1357-1370. doi: 10.3799/dqkx.2018.161

    海南荔枝沟中三叠世酸性火山岩年代学、地球化学特征及其构造意义

    doi: 10.3799/dqkx.2018.161
    基金项目: 

    国家自然科学基金项目 41830211

    广东省自然科学基金项目 2018B030312007

    中国科学技术部国家重点研发计划课题 2016YFC0600303

    国家自然科学基金项目 U1701641

    国家自然科学基金项目 41702230

    详细信息
      作者简介:

      芶琪钰(1995-), 女, 硕士研究生, 主要从事岩石大地构造研究

      通讯作者:

      钱鑫

    • 中图分类号: P595

    Geochronological and Geochemical Constraints on Lizhigou Middle Triassic Felsic Volcanic Rocks in Hainan and Its Tectonic Implications

    • 摘要: 海南岛位于印支与华南陆块的交界地带,构造演化复杂,因此海南岛的拼合历史和构造属性一直备受争议.在海南岛三亚荔枝沟地区新识别出的酸性火山岩对于探讨海南岛早中生代的构造属性具有重要指示意义.LA-ICP-MS锆石U-Pb定年结果显示该套酸性火山岩中流纹岩的成岩年龄为241±6 Ma(MSWD=0.9).地球化学特征表明该套火山岩样品的SiO2含量介于72.34%~77.83%,具较高的Al2O3(10.51%~13.53%)、K2O(2.85%~4.85%)、Na2O(1.75%~3.79%)含量和A/CNK比值(0.99~2.07),为过铝质钙碱性酸性火山岩.样品稀土元素含量为∑REE=87×10-6~177×10-6,富集轻稀土元素,显示右倾岛弧型稀土元素配分模式,Eu负异常明显.样品富集大离子亲石元素,亏损高场强元素,εNdt)变化于-12.1~-11.3之间,可被解释为变沉积物部分熔融后经历分离结晶作用的产物.区域对比研究表明该套酸性火山岩可与三江地区的金沙江-哀牢山-松马构造带的中三叠世岩浆岩进行类比,应形成于印支与华南陆块汇聚的构造背景.

       

    • 图  1  东南亚地区构造划分(a)、海南岛地质简图(b)和研究区地质概况及采样点位置(c)

      图a据Wang et al.(2010, 2018)修改;图b据Zhang et al.(2011)修改

      Fig.  1.  Tectonic outline of Southeast Asia (a), geological sketch of Hainan Island (b) and geological sketch of the study area showing the sampling location (c)

      图  2  海南荔枝沟酸性火山岩野外照片(a, c, e)和岩石显微照片(b, d, f)

      Qtz.石英; Pl.斜长石; Bi.黑云母

      Fig.  2.  Field photographs (a, c, e) and photomicrographs (b, d, f) for the Lizhigou felsic volcanic rocks in Hainan

      图  3  荔枝沟酸性火山岩(11SY-3A)锆石CL、测试点位及206Pb/238U表观年龄(a)和锆石U-Pb谐和图(b)

      Fig.  3.  CL images, dating spots and 206Pb/238U apparent age (a) of the zircons and U-Pb concordia diagram for the Lizhigou felsic volcanic rocks (11SY-3A) (b)

      图  4  荔枝沟酸性火山岩TAS(a)、A/CNK-A/NK(b)和A.R.-SiO2图解(c)

      图a据Maitre et al.(1989);图c据Wright (1969)

      Fig.  4.  SiO2 vs. Na2O+K2O(TAS) (a), A/NK vs. A/CNK (b) and A.R. vs. SiO2 (c) classification diagrams for the Lizhigou felsic volcanic rocks

      图  5  荔枝沟酸性火山岩10 000×Ga/Al-Nb (a)和10 000×(Ga/Al)-Zr图解(b)

      Whalen et al.(1987)

      Fig.  5.  10 000×Ga/Al vs. Nb (a) and 10 000×Ga/Al vs. Zr (b) diagrams for the Lizhigou felsic volcanic rocks

      图  6  荔枝沟酸性火山岩球粒陨石标准化稀土元素配分图(a)和标准化微量元素蛛网图(b)

      球粒陨石及原始地幔数据来自Sun and McDonough (1989),三叠纪高Al碰撞后火山岩数据来自Wang et al.(2010)

      Fig.  6.  Chondrite-normalized REE pattern(a) and primitive mantle-normalized spidergram (b) for the Lizhigou felsic volcanic rocks

      图  7  荔枝沟酸性火山岩(87Sr/86Sr)i-εNd(t)图解

      拉克兰褶皱带(LFB)数据、华南陆块(SCB)印支期、加里东期花岗岩以及滇西南临沧三叠纪花岗岩数据来自Healy et al.(2004); Wang et al.(2007, 2013, 2015)和Peng et al.(2013)

      Fig.  7.  (87Sr/86Sr)i vs. εNd(t) diagram for the Lizhigou felsic volcanic rocks

      图  8  荔枝沟酸性火山岩La-La/Sm (a)、Sr-Rb (b)和Sr-Ba图解(c)

      Fig.  8.  La vs. La/Sm (a), Sr vs. Rb (b) and Sr vs. Ba (c) diagrams for the Lizhigou felsic volcanic rocks

      图  9  荔枝沟酸性火山岩Rb/Sr-Rb/Ba(a)和(Al2O3+FeOT+MgO+TiO2)-Al2O3/(FeOT+MgO+TiO2)图解(b)

      图a据Sylvester (1998); 图b据Wang et al.(2016)

      Fig.  9.  Rb/Sr vs. Rb/Ba (a) and (Al2O3+FeOT+MgO+TiO2) vs. Al2O3/(FeOT+MgO+TiO2) (b) diagrams for the Lizhigou felsic volcanic rocks

      图  10  荔枝沟酸性火山岩Y

      Pearce (1996)

      Fig.  10.  Y+Nb vs. Rb discrimination diagram for the Lizhigou felsic volcanic rocks

      表  1  海南荔枝沟酸性火山岩样品(11SY-3A) LA-ICP-MS锆石U-Pb定年结果

      Table  1.   LA-ICP-MS U-Pb zircon geochronological data for the Lizhigou felsic volcanic rocks in Hainan

      样品编号 Th U Th/U 207Pb/206Pb 207Pb/235U
      11SY-3A-01 574 898 0.64 0.053 76 0.001 63 0.286 10 0.008 73
      11SY-3A-02 450 1 023 0.44 0.056 24 0.001 70 0.298 14 0.009 07
      11SY-3A-03 192 872 0.22 0.058 33 0.002 03 0.301 60 0.010 89
      11SY-3A-04 386 942 0.41 0.061 80 0.001 87 0.328 12 0.010 00
      11SY-3A-05 432 733 0.59 0.055 28 0.001 67 0.276 96 0.008 39
      11SY-3A-06 521 803 0.65 0.052 33 0.001 57 0.285 16 0.008 71
      样品编号 206Pb/238U 207Pb/206Pb 207Pb/235U 206Pb/238U
      11SY-3A-01 0.038 62 0.001 18 361 64 255 7 244 7
      11SY-3A-02 0.038 45 0.001 16 461 67 265 7 243 7
      11SY-3A-03 0.037 43 0.001 17 543 76 268 8 237 7
      11SY-3A-04 0.038 56 0.001 18 733 60 288 8 244 7
      11SY-3A-05 0.036 37 0.001 11 433 73 248 7 230 7
      11SY-3A-06 0.039 53 0.001 21 298 70 255 7 250 7
      下载: 导出CSV

      表  2  海南荔枝沟地区酸性火山岩主量元素(%)、微量元素(10-6)和Sr-Nd同位素组成分析结果

      Table  2.   Major oxides (%), trace elements (10-6) and Sr-Nd isotopic analytical results for the Lizhigou felsic volcanic rocks in Hainan

      样品编号 11HN-61B 11SY-3A 11SY-3B 11SY-3C 11SY-3D 11SY-3E 11SY-3F 11SY-3G 11SY-5B 11SY-5C
      SiO2 76.92 74.83 71.61 70.51 74.03 71.06 71.31 75.56 74.01 74.34
      TiO2 0.35 0.36 0.46 0.39 0.49 0.51 0.43 0.33 0.53 0.51
      Al2O3 11.70 10.38 11.38 10.95 12.07 12.74 10.99 10.31 13.07 13.43
      Fe2O3 2.20 2.97 3.20 3.48 2.60 3.17 2.83 2.65 3.47 3.50
      MgO 1.73 3.08 3.54 3.68 2.61 3.35 3.40 2.74 2.32 2.37
      CaO 0.62 2.66 3.19 4.16 1.13 1.70 3.69 2.54 0.29 0.32
      K2O 4.73 2.79 3.40 3.01 4.61 4.76 4.02 2.98 3.78 3.80
      Na2O 0.53 0.89 0.76 0.76 0.97 0.85 0.91 0.89 1.25 0.87
      MnO 0.01 0.03 0.04 0.05 0.02 0.02 0.04 0.03 0.01 0.01
      P2O5 0.04 0.04 0.06 0.06 0.06 0.06 0.08 0.05 0.10 0.09
      L.O.I 0.98 1.31 1.68 2.25 0.79 1.10 1.65 1.30 0.60 0.55
      Total 99.81 99.35 99.31 99.3 99.38 99.33 99.36 99.37 99.44 99.79
      Mg# 32 32 37 32 30 42 35 39 33 11
      A/CNK 1.65 1.22 1.12 1.01 1.45 1.30 0.99 1.25 2.05 2.07
      A/NK 1.81 2.82 2.74 2.91 2.16 2.27 2.23 2.67 2.60 2.88
      Sc 7.04 5.09 6.32 5.97 7.33 9.80 7.33 6.23
      V 39.7 25.6 29.8 26.3 33.8 46.0 36.8 29.8
      Cr 20.7 27.1 34.0 25.3 34.6 30.6 36.1 23.0
      Co 3.99 6.33 5.69 5.41 5.20 7.23 6.38 6.00
      Ni 5.78 12.80 13.50 11.20 12.30 16.50 19.60 23.00
      Rb 124.0 84.6 113.0 93.8 115.0 139.0 105.0 97.0
      Sr 82.9 76.6 95.9 84.9 62.0 67.3 89.3 76.9
      Y 9.2 13.2 22.9 22.9 33.0 20.8 23.4 23.3
      Zr 186 178 246 205 412 221 219 227
      Nb 9.10 7.19 9.64 8.19 10.50 11.20 9.10 8.66
      Ba 562 709 675 543 1 090 800 989 474
      La 20.2 19.1 25.7 29.1 37.4 26.9 26.9 23.1
      Ce 41.2 35.5 54.8 60.0 68.4 55.2 55.7 52.6
      Pr 3.75 3.99 6.19 6.90 8.52 6.28 6.54 5.88
      Nd 13.3 15.4 24.9 26.1 32.6 24.9 26.0 24.5
      Sm 2.10 3.17 5.27 5.33 6.83 5.05 5.67 5.12
      Eu 0.40 0.64 0.88 0.91 1.09 0.77 0.86 0.74
      Gd 1.54 2.82 4.35 4.78 6.16 3.73 4.29 3.86
      Tb 0.25 0.43 0.75 0.81 1.00 0.63 0.63 0.63
      Dy 1.23 2.50 4.43 4.70 6.17 3.71 3.78 3.64
      Ho 0.29 0.46 0.84 0.88 1.13 0.79 0.73 0.78
      Er 1.01 1.60 2.56 2.66 3.59 2.43 2.31 2.39
      Tm 0.17 0.26 0.40 0.39 0.53 0.36 0.32 0.36
      Yb 1.37 1.76 2.50 2.61 3.50 2.44 2.25 2.35
      Lu 0.26 0.30 0.41 0.42 0.55 0.39 0.37 0.36
      Hf 4.58 5.38 6.68 6.05 11.60 6.14 5.76 5.72
      Ta 0.50 0.82 0.71 0.66 0.83 0.78 0.62 0.56
      Pb 10.7 15.2 15.8 11.3 16.2 16.2 19.1 15.1
      Th 7.86 7.96 9.75 8.87 12.10 10.00 8.36 8.04
      U 1.89 1.81 2.57 2.30 3.12 2.41 2.37 2.09
      Eu/Eu* 0.65 1.38 1.72 2.04 1.98 1.54 1.59 1.74
      (La/Yb)N 26.6 18.8 35.1 39.5 39.3 31.9 41.9 43.8
      (Gd/Yb)N 0.58 0.56 1.18 1.33 1.36 1.01 1.18 1.39
      87Rb/86Sr 3.209 3.209 3.417
      147Sm/144Nd 0.124 0.124 0.132
      87Sr/86Sr 0.751 057 0.746 798 0.751 993
      6 11 11
      143Nd/144Nd 0.511 947 0.511 922 0.511 919
      6 11 11
      (87Sr/86Sr)i 0.740 1 0.735 8 0.740 3
      εNd(t) -11.3 -11.7 -12.1
      TDM2(Ga) 1.67 1.71 1.73
      下载: 导出CSV
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