中条山上玉坡地区黑云母片岩成岩时代及成因

张晗; 孙丰月; 胡安新

doi:10.3799/dqkx.2013.002

中条山上玉坡地区黑云母片岩成岩时代及成因

doi: 10.3799/dqkx.2013.002

张晗^{1, 2,},
孙丰月¹,
胡安新¹

1.
吉林大学地球科学学院, 吉林长春 130061
2.
中国地质科学院矿产资源研究所, 北京 100037

基金项目:

全国危机矿山接替资源找矿项目"辽宁红透山、山西胡家峪铜矿床成矿规律总结" 20089940

详细信息

作者简介:
张晗(1983-), 男, 博士, 主要从事矿床地质学研究.E-mail: zhanghan2003@gmail.com

中图分类号: P611
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- 被引次数: 0
出版历程
- 收稿日期: 2012-02-15
- 刊出日期: 2013-01-15

Geochemistry and Geochronology of Shangyupo Biotite Schist in the Zhongtiaoshan Mountains: Implications for Its Petrogenesis

1.
College of Earth Science, Jilin University, Changchun 130061, China
2.
Institute of Mineral Resources, China Academy of Geological Sciences, Beijing 100037, China

摘要

摘要: 中条山上玉坡背斜核部主要有北峪花岗岩、变富钾流纹岩及(角闪石/方柱石)黑云母片岩为主的变镁铁质杂岩出露.上玉坡的黑云母片岩类的归属及成因争论已久.空间上, 上玉坡黑云母片岩类岩石及地球化学特征形成了一个以背斜核部为中心的环形的递变带, 岩石的主要造岩矿物特征及K、Ca、Na、Rr、Sr、Ba受退变质韧性剪切带高盐度流体改造均发生系统变化, Ta及LREE也显示有明显变化.上玉坡变富钾流纹岩LA-MC-ICPMS测年获得²⁰⁷Pb/²⁰⁶Pb加权平均年龄为2 164±8.9 Ma, 与绛县群竖井沟组富钾流纹岩(²⁰⁷Pb/²⁰⁶Pb加权平均年龄2 161.3±1.5 Ma)同时代产出.上玉坡产出的变富钾流纹岩-黑云母片岩与铜矿峪分布的绛县群双峰式火山建造岩性组合类似, 推断上玉坡背斜核部产出的黑云母片岩产出于2.20~2.15 Ga.使用在流体中保持相对稳定的高场强元素对图解, 判断中条山黑云母片岩的原岩更可能为亚碱性镁铁质火成岩, 并非前人认识的"超钾基性火山岩", 综合中条山古元古代地质特征, 该地区古元古代可能处于与俯冲活动有关的张性构造环境.
- 中条山 /
- 黑云母片岩 /
- 岩石地球化学 /
- 流体 /
- LA-MC-ICPMS锆石U-Pb年龄
Abstract: The primary compositions of the anticline core at Shangyupo are Beiyu meta-granitoid, meta-rhyolite and meta-mafic rocks. The age and petrogenesis of the biotite schist have been under debate for a very long time. The petrology features and geochemistry of Shangyupo amphibole/scapolite biotite schist are cricoid gradually distributed from the anticlinal core to its edge. The K, Ca, Na, Rr, Sr and Ba have been changed systematically by the high salinity fluid from the ductile shear belts, and Ta and LREE are also shown to have been dramatically changed in this event. LA-MC-ICPMS zircon U-Pb dating for the Shangyupo meta-rhyolite and the meta-ryholite of Jiangxian group yield the weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2 160.5±7.8 Ma and 2 161.3±1.5 Ma respectively. The Shangyupo meta-ryhorite and biotite schist may have been formed during the Jiangxian volcano event between 2.20~2.15 Ga, based on the chronology and comparison to related rocks. The HFSE pairs show that the biotite schist is a subalkaline mafic rocks instead of the alkaline mafic rocks as previously suggested. The Jiangxian event may represent a tensional event related to the subduction, based on the comprehensive geological information of Zhongtiaoshan area.
- Zhongtiaoshan Mountains /
- biotite schist /
- lithogeochemistry /
- fluid /
- LA-MC-ICPMS zircon U-Pb dating

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图 1 中条山上玉坡－铜矿峪地区地质图

1.担山石群；2.余家山组；3.篦子沟组；4.余元下组；5.龙峪组；6.界牌梁组；7.竖井沟组；8.西井沟组；9.骆驼峰组；10.圆头山组；11.横岭关亚群1~3段；12.铜矿床；13.变辉绿/辉长岩；14.北峪花岗岩；15.断层；16.韧性剪切带；17.采样位置

Fig. 1. Geological map of Shangyupo-Tongkuangyu region, Zhongtiaoshan Mountains

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图 2 上玉坡部分标本手标本及镜下照片

Fig. 2. Microscopic photos of Shangyupo biotite schist and meta-rhyolite

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图 3 部分典型锆石CL图像及测试点位

Fig. 3. Cathodeluminescence images and the ablated point of typical zircons

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图 4 锆石U-Pb谐和线图及锆石²⁰⁷Pb/²⁰⁶Pb年龄加权平均值

Fig. 4. Concordia diagram of ziron U-Pb isotopes and zircon weight mean ²⁰⁷Pb/²⁰⁶Pb age

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图 5 上玉坡黑云母片岩TAS及Harker图解(碱性岩数据来自GEOROC数据库)

Fig. 5. TAS figure and oxides vs.SiO₂ plots showing major element variations of Shangyupo biotite schist comparison with typical alkaline rocks

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图 6 黑云母片岩原始地幔标准化稀土分配及蛛网图

Fig. 6. Chondrite normalized rare-earth element distributions and spidergram for the Shangyupo biotite schist

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图 7 上玉坡背斜核部(角闪石)黑云母片岩一些主量元素空间变化

1.北峪花岗岩；2.变富钾流纹岩；3.角闪石黑云母片岩；4.强片理化黑云母片岩；5.余家山组大理岩；6.斜长角闪岩

Fig. 7. Modification of some major elements of amphibole biotite schist and biotite schist in the Shangyupo anticlinal core

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图 8 上玉坡背斜核部(角闪石)黑云母片岩微量元素空间变化

样品空间位置与图 7一致

Fig. 8. Modification of some trace elements of amphibole biotite schist and biotite schist in the Shangyupo anticlinal core

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图 9 高场强元素对显示上玉坡黑云母片岩原岩地球化学特征

Fig. 9. HFSE pairs determined original geochemistry characteristic of the Shangyupo biotite schist

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表 1 上玉坡变富钾流纹岩(TMG-8)及绛县群竖井沟组变富钾流纹岩(TKY-PM-B7)LA-MC-ICPMS锆石U-Pb同位素测年结果

Table 1. Analyzed LA-MC-ICPMS zircon U-Pb isotopic results of Shangyupo meta-rhyolite (TMG-8) and Jiangxian group meta-rhyolite (TKY-PM-B7)

序号	点位	w(Th) (10^-6)	w(U) (10^-6)	Th/U	同位素比值						同位素年龄(Ma)
序号	点位	w(Th) (10^-6)	w(U) (10^-6)	Th/U	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁶Pb/²³⁸U	1σ	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁶Pb/²³⁸U	1σ
	TMG-8
1	TMG-8-1	26.2	28.1	0.93	0.136 14	0.000 94	7.255 23	0.084 43	0.386 27	0.003 59	2 188.9	12.0	2 143.3	10.4	2 105.5	16.7
2	TMG-8-2	22.1	27.5	0.80	0.134 64	0.000 98	7.391 39	0.096 21	0.398 25	0.004 50	2 161.1	12.7	2 159.9	11.6	2 161.0	20.8
3	TMG-8-3	32.7	35.9	0.91	0.135 30	0.000 73	7.209 39	0.071 24	0.386 41	0.003 28	2 168.5	9.6	2 137.7	8.8	2 106.2	15.2
4	TMG-8-5	27.4	30.9	0.88	0.135 76	0.000 67	7.357 41	0.080 77	0.393 14	0.004 00	2 173.8	9.1	2 155.8	9.8	2 137.4	18.5
5	TMG-8-6	20.9	23.4	0.89	0.135 85	0.002 88	7.173 76	0.127 21	0.389 55	0.006 00	2 175.9	37.0	2 133.2	15.8	2 120.8	27.8
6	TMG-8-8	20.3	26.9	0.75	0.135 47	0.002 19	7.245 07	0.161 30	0.381 48	0.008 48	2 170.1	27.6	2 142.1	19.9	2 083.2	39.6
7	TMG-8-9	40.0	55.2	0.72	0.135 21	0.002 00	6.892 77	0.070 83	0.375 19	0.003 75	2 168.5	25.9	2 097.7	9.1	2 053.8	17.6
8	TMG-8-11	19.8	22.4	0.88	0.135 45	0.002 13	6.695 78	0.100 83	0.365 67	0.005 53	2 170.1	27.9	2 072.1	13.3	2 009.0	26.1
9	TMG-8-12	29.1	30.8	0.94	0.134 94	0.000 99	7.158 39	0.179 55	0.384 32	0.008 22	2 164.8	12.7	2 131.3	22.4	2 096.4	38.3
10	TMG-8-13	17.8	23.0	0.77	0.132 80	0.000 86	7.096 55	0.116 21	0.388 00	0.006 20	2 135.5	11.4	2 123.6	14.6	2 113.5	28.8
11	TMG-8-14	10.3	17.4	0.59	0.135 04	0.002 92	6.803 75	0.117 54	0.368 00	0.007 21	2 164.5	36.9	2 086.2	15.3	2 020.0	34.0
12	TMG-8-15	27.2	33.0	0.82	0.134 02	0.000 72	7.003 15	0.181 04	0.381 41	0.008 95	2 151.5	9.1	2 111.8	23.0	2 082.9	41.8
13	TMG-8-16	239.4	30.2	7.93	0.135 21	0.001 57	7.081 49	0.093 31	0.383 47	0.005 12	2 168.5	20.1	2 121.7	11.7	2 092.5	23.9
	TKY-PM-B7
1	TKY-PM-B7-1	25.5	38.2	0.67	0.134 66	0.000 76	7.232 64	0.142 01	0.389 28	0.007 23	2161.1	9.9	2 140.5	17.5	2 119.5	33.6
2	TKY-PM-B7-2	35.3	61.7	0.57	0.135 00	0.000 38	7.188 17	0.062 19	0.386 41	0.003 42	2 164.8	4.9	2 135.0	7.7	2 106.2	15.9
3	TKY-PM-B7-3	30.9	54.9	0.56	0.134 91	0.000 41	7.263 94	0.076 16	0.390 51	0.003 98	2 162.7	5.2	2 144.4	9.4	2 125.2	18.5
4	TKY-PM-B7-5	51.3	75.8	0.68	0.134 69	0.000 37	7.103 21	0.074 21	0.382 65	0.004 01	2 161.1	4.9	2 124.4	9.3	2 088.6	18.7
5	TKY-PM-B7-6	58.4	89.5	0.65	0.134 41	0.000 35	7.311 83	0.075 75	0.394 78	0.004 19	2 166.7	4.6	2 150.3	9.3	2 144.9	19.4
6	TKY-PM-B7-7	8.6	12.4	0.70	0.135 34	0.000 75	7.159 85	0.113 85	0.383 78	0.005 89	2 168.2	15.0	2 131.5	14.2	2 093.9	27.4
7	TKY-PM-B7-8	87.3	115.3	0.76	0.134 27	0.000 37	7.367 23	0.081 03	0.398 25	0.004 53	2 154.6	5.7	2 157.0	9.8	2 161.0	20.9
8	TKY-PM-B7-9	46.0	71.2	0.65	0.134 58	0.000 44	7.145 38	0.086 18	0.385 00	0.004 48	2 158.3	5.4	2 129.7	10.7	2 099.6	20.9
9	TKY-PM-B7-10	45.9	72.6	0.63	0.134 71	0.000 47	6.976 43	0.082 37	0.375 89	0.004 54	2 161.1	6.2	2 108.4	10.5	2 057.1	21.2
10	TKY-PM-B7-11	44.0	60.0	0.73	0.135 32	0.000 52	7.275 95	0.085 32	0.390 13	0.004 52	2 168.2	7.3	2 145.9	10.5	2 123.4	21.0
11	TKY-PM-B7-12	66.9	86.4	0.77	0.134 63	0.000 58	7.274 48	0.121 07	0.392 07	0.006 57	2 161.1	8.5	2 145.7	14.9	2 132.4	30.4
12	TKY-PM-B7-13	41.4	65.5	0.63	0.133 90	0.000 56	7.409 77	0.077 13	0.401 38	0.003 96	2 149.7	7.4	2 162.2	9.3	2 175.4	18.2
13	TKY-PM-B7-14	31.8	51.1	0.62	0.134 22	0.000 48	7.285 46	0.048 46	0.393 93	0.002 63	2 154.0	6.6	2 147.0	5.9	2 141.0	12.2
14	TKY-PM-B7-15	20.9	44.1	0.47	0.134 75	0.000 45	7.217 30	0.053 18	0.388 41	0.002 52	2 160.8	5.6	2 138.6	6.6	2 115.5	11.7
15	TKY-PM-B7-16	93.4	135.4	0.69	0.134 60	0.000 43	7.300 18	0.051 21	0.393 48	0.002 68	2 159.0	5.6	2 148.8	6.3	2 139.0	12.4
16	TKY-PM-B7-17	44.4	71.1	0.62	0.134 90	0.000 39	7.279 71	0.044 77	0.391 48	0.002 18	2 162.7	5.4	2 146.3	5.5	2 129.7	10.1
17	TKY-PM-B7-18	76.1	119.2	0.64	0.134 31	0.000 44	7.451 00	0.067 53	0.402 45	0.003 46	2 155.2	5.4	2 167.1	8.1	2 180.3	15.9
18	TKY-PM-B7-19	42.1	53.1	0.79	0.134 79	0.000 42	7.218 16	0.054 84	0.388 51	0.002 69	2 161.4	0.9	2 138.7	6.8	2 115.9	12.5
19	TKY-PM-B7-20	48.7	70.5	0.69	0.134 35	0.000 46	7.240 33	0.042 05	0.391 18	0.002 10	2 166.7	5.9	2 141.5	5.2	2 128.3	9.7

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表 2 上玉坡黑云母片岩全岩主量元素(%)、微量元素(μg/ g)含量

Table 2. Major (%) and trace element (μg/ g) data of Shangyupo biotite schist

样品^*	TMG-P1-B31	TMG-9	TMG-21	TMG-P2-B21	TMG-19	TMG-P2-B31	BZG-HY3	BZG-HY1	BZG-HY4	BZG-HY2	HJY-SM-JK1	HJY-SM-JK3
岩性	黑云母片岩	黑云母片岩	角闪石黑云母片岩	角闪石黑云母片岩	角闪石黑云母片岩	角闪石黑云母片岩	黑云母片岩	黑云母片岩	黑云母片岩	黑云母片岩	黑云母片岩	方柱石黑云母片岩
SiO₂	41.86	48.02	46.90	46.20	47.78	45.22	49.85	44.98	42.27	40.47	40.04	51.14
TiO₂	1.21	1.10	1.17	1.40	1.38	1.39	1.00	1.06	1.36	1.10	0.94	2.16
Al₂O₃	16.51	15.76	14.03	13.98	13.92	14.68	14.56	16.41	16.91	17.73	17.72	15.69
Fe₂O₃	5.90	7.24	4.74	8.85	3.96	1.75	7.61	7.73	1.50	9.80	10.26	11.59
FeO	7.37	6.30	7.69	8.10	6.26	7.06	6.84	6.95	1.35	8.82	9.23	11.59
MnO	0.24	0.24	0.21	0.43	0.30	0.37	0.14	0.16	0.13	0.09	0.08	0.18
MgO	12.26	7.18	9.36	6.49	7.07	10.44	11.10	9.60	11.28	14.28	14.89	6.41
CaO	0.79	0.83	7.45	5.59	4.44	7.07	3.45	4.75	2.66	0.74	0.69	2.58
Na₂O	2.39	2.58	3.62	3.44	5.13	3.86	3.31	3.15	2.03	1.32	0.99	2.62
K₂O	9.52	8.77	2.66	4.00	5.84	6.07	4.10	4.70	6.82	8.42	8.69	2.89
P₂O₅	0.12	0.12	0.23	0.27	0.13	0.14	0.16	0.15	0.15	0.12	0.15	0.51
LOI	1.67	1.68	1.57	1.05	3.61	1.74	1.73	1.70	1.37	1.73	1.80	1.17
Total	99.84	99.82	99.63	99.80	99.81	99.79	103.85	101.33	87.82	104.62	105.48	108.53
Sr	20.11	15.73	67.18	146.20	91.96	133.20	62.76	53.71	28.29	89.75	23.71	37.67
Rb	203.20	208.30	63.07	57.71	187.30	107.90	118.27	215.13	184.10	141.06	199.02	80.12
Ba	352.90	461.30	230.40	634.30	264.30	291.10	255.25	534.25	448.07	336.69	427.51	270.00
Th	0.70	1.00	0.82	0.79	2.10	0.28	0.48	0.89	1.25	0.48	0.86	6.22
Ta	0.78	0.59	0.34	0.40	0.76	0.58	0.19	0.40	0.20	0.23	0.18	0.68
Nb	3.36	2.36	3.18	3.16	5.05	2.41	2.39	3.62	3.25	2.45	1.88	8.40
Zr	75.88	46.14	72.32	66.06	104.80	45.58	44.47	73.53	52.42	51.74	44.27	91.69
Hf	2.74	1.45	2.16	1.94	2.98	1.53	1.21	1.98	1.50	1.47	1.23	1.83
Y	4.01	8.56	16.62	26.44	17.67	19.88	14.43	8.90	21.41	11.11	14.59	19.39
Sc	27.85	22.43	13.59	28.70	32.51	35.83	37.68	30.08	38.43	30.92	37.76	37.67
V	254.10	276.90	271.90	282.10	264.60	300.60	263.53	284.99	269.61	247.95	284.23	297.70
Cr	358.50	291.00	144.20	102.50	162.80	883.50	452.99	248.38	335.44	251.48	301.79	22.26
Co	58.05	63.93	67.15	92.95	62.56	67.72	50.69	54.10	59.33	47.48	61.82	31.83
Ni	228.60	217.80	149.20	96.22	164.40	340.30	186.89	194.74	143.76	194.10	151.85	28.74
Cu	2.38	7.19	13.62	13.62	645.70	17.69	13.03	11.64	20.09	9.06	7.01	7.11
Pb	0.92	1.03	2.09	1.49	2.99	0.72	1.27	2.92	1.20	2.02	3.03	1.97
U	0.68	0.08	0.12	0.14	0.29	0.16	0.18	1.62	0.60	0.67	0.42	0.73
La	0.38	2.48	5.04	10.27	12.17	3.52	4.77	18.01	34.24	8.96	22.13	26.37
Ce	0.58	5.22	11.70	21.35	27.10	8.61	11.07	36.21	73.68	18.96	48.63	61.51
Pr	0.14	0.95	1.91	3.00	3.52	1.30	1.52	4.27	9.24	2.41	6.19	6.94
Nd	0.78	4.85	10.23	13.43	15.61	6.48	7.41	17.82	41.77	10.96	27.57	29.06
Sm	0.34	1.41	2.74	3.47	3.35	1.98	1.70	3.42	7.91	2.38	5.49	6.40
Eu	0.18	0.57	1.46	1.66	1.05	1.04	0.78	1.03	2.12	0.94	1.39	1.64
Gd	0.59	1.84	2.96	4.69	3.80	2.71	2.20	3.49	7.35	2.62	5.21	6.26
Tb	0.12	0.34	0.49	0.81	0.62	0.52	0.39	0.45	0.98	0.37	0.72	0.91
Dy	0.78	1.89	3.08	4.83	3.65	3.49	2.66	2.13	5.06	2.16	3.54	4.85
Ho	0.17	0.41	0.76	0.98	0.79	0.74	0.53	0.36	0.88	0.41	0.60	0.82
Er	0.56	1.02	2.45	2.85	2.17	2.27	1.61	0.89	2.47	1.19	1.64	1.87
Tm	0.09	0.18	0.44	0.41	0.34	0.34	0.23	0.12	0.31	0.17	0.21	0.27
Yb	0.73	0.94	3.00	2.59	2.04	2.15	1.49	0.79	1.89	1.02	1.29	1.76
Lu	0.14	0.16	0.48	0.38	0.32	0.33	0.21	0.14	0.29	0.18	0.19	0.23
Zr/TiO₂	62.71	42.13	62.02	47.19	76.12	32.79	44.29	69.17	38.43	47.08	46.94	42.45
Nb/Y	0.84	0.28	0.19	0.12	0.29	0.12	0.17	0.41	0.15	0.22	0.13	0.43
ΣREE	5.58	22.26	46.74	70.71	76.55	35.47	36.58	89.11	188.17	52.72	124.80	148.89
LREE/HREE	0.75	2.28	2.42	3.03	4.57	1.83	2.92	9.66	8.78	5.50	8.30	7.77
(La/Yb)_N	0.38	1.89	1.20	2.84	4.28	1.18	2.30	16.40	12.97	6.32	12.29	10.75
δEu	1.20	1.08	1.56	1.26	0.90	1.36	1.23	0.90	0.83	1.14	0.78	0.78
δCe	0.61	0.83	0.92	0.93	1.00	0.99	1.00	0.98	1.00	0.98	1.00	1.09
*样品顺序按图 7剖面图自西向东排列.

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