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    吉林临江八道沟二长花岗岩地球化学、Hf同位素特征及其成因

    田力丹 孙丰月 王力 刘金龙 吴琼

    田力丹, 孙丰月, 王力, 刘金龙, 吴琼, 2018. 吉林临江八道沟二长花岗岩地球化学、Hf同位素特征及其成因. 地球科学, 43(2): 436-448. doi: 10.3799/dqkx.2017.572
    引用本文: 田力丹, 孙丰月, 王力, 刘金龙, 吴琼, 2018. 吉林临江八道沟二长花岗岩地球化学、Hf同位素特征及其成因. 地球科学, 43(2): 436-448. doi: 10.3799/dqkx.2017.572
    Tian Lidan, Sun Fengyue, Wang Li, Liu Jinlong, Wu Qiong, 2018. Geochemistry, Hf Isotopes and Petrogenesis of Badaogou Monzonotic Granites from Linjiang, Jilin Province. Earth Science, 43(2): 436-448. doi: 10.3799/dqkx.2017.572
    Citation: Tian Lidan, Sun Fengyue, Wang Li, Liu Jinlong, Wu Qiong, 2018. Geochemistry, Hf Isotopes and Petrogenesis of Badaogou Monzonotic Granites from Linjiang, Jilin Province. Earth Science, 43(2): 436-448. doi: 10.3799/dqkx.2017.572

    吉林临江八道沟二长花岗岩地球化学、Hf同位素特征及其成因

    doi: 10.3799/dqkx.2017.572
    基金项目: 

    吉林省地质勘查基金项目 22201300111

    详细信息
      作者简介:

      田力丹(1993-), 女, 硕士研究生, 主要从事矿床学研究

      通讯作者:

      孙丰月

    • 中图分类号: P581

    Geochemistry, Hf Isotopes and Petrogenesis of Badaogou Monzonotic Granites from Linjiang, Jilin Province

    • 摘要: 八道沟具有复杂的构造环境,且侏罗纪花岗岩在该地区分布较为有限,因此十分缺乏对区域构造演化环境判断的证据.对八道沟二长花岗岩进行了地球化学、锆石U-Pb年代学及Hf同位素研究,结果显示:岩石样品中的锆石主要为长柱状,自形程度较好,发育较清晰的韵律生长环带结构,具岩浆锆石特征,该岩石形成于早侏罗世(176±1 Ma);岩石SiO2含量为68.93%~70.02%,贫MgO(1.27%~1.45%)、CaO(1.80%~2.78%),A/CNK值为0.92~1.02,轻稀土元素明显富集,铕异常不明显(0.96~1.03),属于准铝质高钾钙碱性系列,显示为I型花岗岩特征;岩石εHft)值为-20.21~-24.08,二阶段模式年龄tDM2(Hf)为2 498~2 740 Ma,且富集大离子亲石元素,亏损高场强元素Nb、Ta、P、Ti,Mg#值介于45~47,由此推断岩石源于新太古代下地壳熔融.结合区域同时代岩浆岩展布,认为八道沟地区二长花岗岩的形成与古太平洋板块向欧亚大陆俯冲有关.

       

    • 图  1  研究区大地构造位置及岩浆岩分布

      1.早白垩世侵入岩,2.侏罗纪花岗岩,3.晚三叠世碱性岩,4.晚三叠世闪长岩—花岗岩,5.晚二叠—中三叠世侵入岩,6.石炭纪—早二叠世侵入岩,7.断裂带,8.地名;据Xu(2001)Yang et al.(2003, 2005)Zhao et al.(2006)Li et al.(2012)Zhang et al.(2014)Deng and Wang(2016)刘金龙等(2016)

      Fig.  1.  Geotectonic location and magmatite distribution of the study area

      图  2  研究区地质简图

      1.新近系船底山组;2.侏罗系;3.奥陶系;4.寒武系;5.青白口系钓鱼台组;6.老岭群花山组;7.喜马拉雅期玄武岩;8.侏罗纪花岗岩;9.断裂及节理

      Fig.  2.  Geological map of the study area

      图  3  八道沟二长花岗岩显微照片

      Bt.黑云母;Mc.微斜长石;Pl.斜长石;Qz.石英

      Fig.  3.  Microscopic photographs from Badaogou monzonitic granites

      图  4  八道沟二长花岗岩部分锆石阴极发光(CL)图像

      Fig.  4.  Cathodoluminescene (CL) images of zircons from Badaogou monzonitic granites

      图  5  八道沟二长花岗岩U-Pb年龄谐和图

      Fig.  5.  U-Pb concordia diagram for Badaogou monzonitic granites

      图  6  八道沟二长花岗岩SiO2-K2O图解和A/CNK-A/NK图解

      Fig.  6.  SiO2 vs. K2O diagram (a) and A/CNK vs. A/NK diagram (b) of Badaogou monzonitic granites

      图  7  八道沟二长花岗岩稀土元素球粒陨石标准化配分模式(a)和微量元素原始地幔标准化蛛网图(b)

      球粒陨石标准化值据Boynton(1984),原始地幔标准化值据Sun and McDonough (1989)

      Fig.  7.  Chondrite-normalized REE pattern (a) and PM-normalized trace element spider diagram (b) of Badaogou monzonitic granites

      图  8  八道沟二长花岗岩Hf同位素特征

      Yang et al.(2006)

      Fig.  8.  Hf isotopic compositions of Badaogou monzonitic granites

      表  1  八道沟二长花岗岩锆石LA-ICP-MS U-Pb同位素分析结果

      Table  1.   Zircon LA-ICP-MS U-Pb isotope analysis results of Badaogou monzonitic granites

      测点号 含量(10-6) Th/U 同位素比值及误差 年龄(Ma)及误差 钛地质温度计算
      Th U 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ Ti(10-6) 最高温度(℃) 最低温度(℃)
      BDG-N1-1 441 851 0.52 0.055 2 0.004 4 0.207 0 0.016 4 0.027 2 0.000 5 433 180 191 14 173 3 15.8 789 776
      BDG-N1-3 1 455 3 395 0.43 0.053 0 0.002 1 0.199 0 0.008 2 0.027 1 0.000 4 328 91 184 7 172 2 63.7 942 928
      BDG-N1-5 1 306 2 307 0.57 0.052 6 0.002 6 0.203 6 0.010 2 0.028 0 0.000 4 322 119 188 9 178 3 12.0 763 751
      BDG-N1-6 893 3 381 0.26 0.053 1 0.002 2 0.200 6 0.007 9 0.027 4 0.000 4 332 99 186 7 174 2 7.97 727 716
      BDG-N1-7 1 545 4 679 0.33 0.053 9 0.002 0 0.203 1 0.007 5 0.027 2 0.000 4 369 85 188 6 173 2 8.41 732 720
      BDG-N1-9 1 049 3 394 0.31 0.055 0 0.002 3 0.210 4 0.009 0 0.027 6 0.000 3 409 91 194 8 175 2 19.4 809 797
      BDG-N1-10 1 012 1906 0.53 0.053 1 0.002 6 0.204 0 0.011 0 0.027 7 0.000 5 332 113 189 9 176 3 8.40 732 720
      BDG-N1-14 890 4 035 0.22 0.051 1 0.001 9 0.195 5 0.007 3 0.027 6 0.000 3 256 81 181 6 176 2 12.8 769 757
      BDG-N1-15 1 108 4 354 0.25 0.051 4 0.001 8 0.199 8 0.007 3 0.028 1 0.000 4 261 81 185 6 178 2 15.8 789 777
      BDG-N1-16 883 2 916 0.30 0.050 0 0.002 0 0.189 9 0.007 4 0.027 6 0.000 3 195 94 177 6 175 2 6.36 709 697
      BDG-N1-17 1 103 3 553 0.31 0.050 9 0.001 9 0.191 1 0.007 2 0.027 2 0.000 3 235 89 178 6 173 2 15.6 788 776
      BDG-N1-18 425 1 865 0.23 0.051 0 0.002 3 0.196 5 0.008 8 0.028 0 0.000 4 243 106 182 7 178 2 1.52 604 593
      BDG-N1-19 973 2 169 0.45 0.053 9 0.002 8 0.208 3 0.011 2 0.028 1 0.000 5 369 120 192 9 179 3 7.62 723 712
      BDG-N1-20 3 841 8 638 0.44 0.057 2 0.001 8 0.223 9 0.007 4 0.028 2 0.000 4 502 70 205 6 179 3 49.5 911 897
      BDG-N1-22 853 2 938 0.29 0.048 3 0.001 9 0.184 6 0.007 3 0.027 6 0.000 4 117 94 172 6 176 2 17.7 800 787
      BDG-N1-23 2 016 3 259 0.62 0.047 1 0.001 8 0.185 7 0.007 8 0.028 2 0.000 5 53.8 89 173 7 179 3 24.8 834 821
      BDG-N1-24 1 147 4 061 0.28 0.051 1 0.002 5 0.194 9 0.008 4 0.027 9 0.000 5 256 111 181 7 177 3 13.2 772 760
      BDG-N1-25 1 055 3 096 0.34 0.048 4 0.002 1 0.180 7 0.007 4 0.027 1 0.000 4 120 102 169 6 172 3 6.76 713 702
      注:常用的锆石Ti地质温度计算公式为T(℃)= (5 080±30)/[(6.01±0.03)-lg(Ti)]-273, 据Waston et al.(2006).
      下载: 导出CSV

      表  2  八道沟二长花岗岩主量元素(%)、微量元素(10-6)和稀土元素(10-6)含量

      Table  2.   Major elements (%), trace elements (10-6) and REE (10-6) contents of Badaogou monzonitic granites

      样品 BDG-B1 BDG-B2 BDG-B3 BDG-B4 BDG-B5
      SiO2 69.19 70.02 69.48 69.51 68.93
      TiO2 0.31 0.31 0.30 0.28 0.30
      Al2O3 14.15 14.04 14.57 14.15 14.32
      Fe2O3T 3.25 3.14 3.05 3.07 3.32
      MnO 0.12 0.10 0.11 0.11 0.12
      MgO 1.36 1.41 1.27 1.33 1.45
      CaO 2.74 1.80 2.40 2.78 2.53
      Na2O 3.44 3.31 3.61 3.47 3.53
      K2O 4.25 4.68 4.32 4.28 4.41
      P2O5 0.10 0.09 0.10 0.09 0.09
      LOI 0.91 0.82 0.63 0.50 0.89
      Total 99.81 99.71 99.83 99.57 99.90
      ALK 7.69 7.99 7.92 7.74 7.94
      Na2O/K2O 0.81 0.71 0.84 0.81 0.80
      A/CNK 0.93 1.02 0.97 0.92 0.94
      Mg# 45 47 45 46 46
      La 20.7 22.2 20.7 13.9 15.8
      Ce 41.6 41.1 37.7 25.9 30.4
      Pr 4.81 5.02 4.71 3.51 3.88
      Nd 16.9 17.6 16.9 12.6 14.3
      Sm 3.37 3.34 3.40 2.79 3.15
      Eu 1.00 1.01 1.04 0.90 0.97
      Gd 2.85 2.88 2.85 2.41 2.86
      Tb 0.45 0.42 0.45 0.39 0.44
      Dy 2.31 2.27 2.36 2.11 2.43
      Ho 0.51 0.46 0.49 0.44 0.49
      Er 1.41 1.34 1.41 1.29 1.42
      Tm 0.23 0.21 0.22 0.20 0.22
      Yb 1.51 1.37 1.41 1.35 1.53
      Lu 0.25 0.21 0.22 0.22 0.24
      Y 11.4 10.6 11.3 10.3 11.5
      ΣREE 97.9 99.5 93.8 68.0 78.1
      LREE 88.4 90.4 84.4 59.6 68.5
      HREE 9.51 9.15 9.43 8.41 9.63
      LREE/HREE 9.29 9.87 8.95 7.09 7.11
      (La/Yb)N 9.82 11.7 10.5 7.38 7.41
      δEu 0.96 0.97 0.99 1.03 0.96
      δCe 0.99 0.92 0.90 0.89 0.93
      Rb 137 148 149 86.3 110
      Ba 550 643 611 488 530
      Th 12.8 11.5 12.4 8.95 9.37
      U 3.07 2.42 2.12 2.00 2.02
      Nb 12.0 11.4 12.7 10.4 11.3
      Ta 1.63 1.54 1.62 1.50 1.44
      Sr 370 317 341 304 356
      Zr 50.2 39.2 42.5 95.4 47.2
      Hf 2.58 2.19 2.32 3.87 2.48
      Nb/Ta 7.35 7.38 7.85 6.94 7.81
      Rb/Sr 0.37 0.47 0.44 0.28 0.31
      La/Nb 1.73 1.95 1.62 1.33 1.40
      Ba/Nb 46.0 56.5 48.0 46.9 47.1
      注:ALK=摩尔(Na2O+K2O), A/CNK=摩尔Al2O3/(CaO+Na2O+K2O);Na2O/K2O为质量分数比值;Mg#=100×(MgO/40.31)/(MgO/40.31+Fe2O3T×2/159.7).
      下载: 导出CSV

      表  3  八道沟二长花岗岩锆石Hf同位素分析结果

      Table  3.   Zircon Hf isotopic compositions of Badaogou monzonitic granites

      样品 t(Ma) 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf 2σ εHf(0) εHf(t) 2σ tDM1(Hf) tDM2(Hf) fLu/Hf
      BDG-N1-1 176 0.040 955 0.001 710 0.282 023 0.000 014 -26.49 -22.83 0.50 1 764 2 662 -0.95
      BDG-N1-2 176 0.041 711 0.001 770 0.282 044 0.000 015 -25.73 -22.08 0.54 1 736 2 615 -0.95
      BDG-N1-3 176 0.037 639 0.001 569 0.282 039 0.000 013 -25.92 -22.25 0.45 1 735 2 626 -0.95
      BDG-N1-4 176 0.031 808 0.001 396 0.282 010 0.000 014 -26.96 -23.27 0.49 1 768 2 690 -0.96
      BDG-N1-5 176 0.032 890 0.001 437 0.282 018 0.000 017 -26.67 -22.98 0.59 1 758 2 671 -0.96
      BDG-N1-6 176 0.034 119 0.001 424 0.282 059 0.000 016 -25.22 -21.53 0.56 1 700 2 581 -0.96
      BDG-N1-7 176 0.038 575 0.001 623 0.282 036 0.000 013 -26.02 -22.35 0.45 1 741 2 632 -0.95
      BDG-N1-8 176 0.030 998 0.001 291 0.282 036 0.000 016 -26.04 -22.34 0.58 1 727 2 631 -0.96
      BDG-N1-9 176 0.048 996 0.001 986 0.281 989 0.000 017 -27.71 -24.08 0.61 1 826 2 740 -0.94
      BDG-N1-10 176 0.041 459 0.001 751 0.282 089 0.000 015 -24.14 -20.49 0.54 1 672 2 515 -0.95
      BDG-N1-11 176 0.047 229 0.001 990 0.282 050 0.000 015 -25.54 -21.92 0.52 1 739 2 605 -0.94
      BDG-N1-12 176 0.028 037 0.001 170 0.282 006 0.000 016 -27.07 -23.35 0.57 1 762 2 695 -0.96
      BDG-N1-14 176 0.052 130 0.002 129 0.282 098 0.000 016 -23.82 -20.21 0.56 1 676 2 498 -0.94
      BDG-N1-15 176 0.051 916 0.002 079 0.282 056 0.000 014 -25.33 -21.72 0.51 1 735 2 592 -0.94
      下载: 导出CSV
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