Geochronology, Zircon Trace Element and Lu-Hf Isotope Characteristics of the Biotite Granite and Their Geological Significance from Daolundaba Cu Polymetallic Deposit, Southern Great Hinggan Ling, China
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摘要: 道伦达坝铜多金属矿床位于大兴安岭成矿带南段，对道伦达坝矿床黑云母花岗岩开展了锆石U-Pb测年、锆石微量元素和Lu-Hf同位素研究.锆石U-Pb LA-ICP-MS测年结果显示黑云母花岗岩形成时代为282.2±4.5~287.0±3.7 Ma.锆石Lu-Hf同位素研究结果显示黑云母花岗岩锆石均具有较高的176Hf/177Hf（平均值分别为0.282 770和0.282 769）和低的176Lu/177Hf（平均值分别为0.002 224和0.001 984）同位素组成，εHf（t）值变化范围为3.05~8.58之间和2.31~7.36，二阶段模式年龄分别为730.22~1 083.46 Ma和812.42~1 134.56 Ma，暗示其来源为年轻的新生下地壳，可能遭受了古老地壳的混染.锆石微量元素研究显示，黑云母花岗岩的锆石具有低的Nb含量（< 2×10-6）和强烈的Eu异常，符合S型花岗岩特征.锆石的Ti饱和温度平均值为770℃和785℃，指示其源区经历了水近饱和情况下的部分熔融，暗示其可能形成于俯冲环境下.Abstract: Daolundaba Cu polymetallic deposit islocated in southern segment of Great Hinggan Ling metallogenic belt. In this study, we carried out chronological studies of LA-ICP-MS zircon U-Pb ages, zircon trace element and Lu-Hf isotope for the biotite granites in Daolundaba deposit. LA-ICP-MS zircon U-Pb dating results suggested that the formation age of the biotite granites range from 282.2±4.5-287.0±3.7 Ma.Lu-Hf isotope analysis of the biotite granite showed that the biotite granites had high isotopic compositions of 176Hf/177Hf (mean values of 0.282 770 and 0.282 769) and low isotopic compositions of 176Lu/177Hf (mean values of 0.002 224 and 0.001 984), εHf(t) values range from 3.05-8.58 and 2.31-7.36, with older two-stage ages (730.22-1 083.46 Ma and 812.42-1 134.56 Ma). Zircon trace element results suggest eda S-type granites characteristic with al ow Nb(< 2×10-6)values and large negative Euanomalies. The forming mean temperatures of the biotite granite calculated by zircon Tithermometer are 770℃ and 785℃, indicated that its magmas is like lytorelate to a subducted environment, and the source region probably experienced partial melting with water nearly saturation. The Daolundaba copper polymetallic deposit was formed in the Late Permian subduction environment.
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图 1 (a) 大地构造位置图；(b)矿区地质简图
第四系；2.下白垩统白音高老组；3.上侏罗统玛尼吐组；4.下二叠统寿山沟组；5.上石炭统阿木山组；6.上石炭统本巴图组；7.古元古界宝音图群；8.燕山期花岗岩类；9.华力西期花岗岩；10.华力西期辉长岩；11.华力西期石英闪长岩；12.石英斑岩脉；13.石英脉；14.花岗细晶岩脉；15.闪长玢岩脉；16.道伦达坝矿床；17.采样点; a.据Xiao et al.(2003)，周振华等(2014）; b.据陈公正等（2018）修改
Fig. 1. (a)Sketch map showing tectonic position; (b)schematic geological map
图 2 道伦达坝矿区构造示意图和A-A’矿体剖面图
1.第四系；2.二叠系寿山沟组；3.黑云母花岗岩；4.背斜及编号；5.向斜及编号；6.断裂及产状；7.蚀变带；8.矿体及编号；据潘小菲等(2009)修改
Fig. 2. Sketch of structure in Daolundaba deposit and orebody's section along A-A' line
图 3 道伦达坝花岗岩手标本（a，b）、野外露头（c，d）及镜下显微（e.单偏光；f.正交偏光）照片
Qz.石英；Pl.斜长石；Kfs.钾长石；Bio.黑云母；Ser.绢云母
Fig. 3. Photograph of specimens(a, b), fieldoutcrop(c, d)and microphotograph (e. polarized; f. orthogonal polarization)from Daolundaba biotite granite
图 6 锆石球粒陨石标准化稀土元素配分图与Hf-TTi-in-zircon关系图
a.标准化数值据Sun et al.（1989）；b.底图据周敖日格勒等（2017）
Fig. 6. Chondrite-normalized REE patterns(a) and plots of zircons Hf-TTi-in-zircon of zircons(b)
图 7 锆石La-（Sm/La）N（a）和（Sm/La）N-Ce/Ce*关系图（b）（底图引自Hoskin et al., 2005）
Fig. 7. Plots of zircon La-(Sm/La)N(a)and(Sm/La)N-Ce/Ce*(b)(modified from Hoskin et al., 2005)
图 9 锆石Hf同位素特征图（底图引自Vervoort et al., 1996; 周振华等, 2014）
Fig. 9. Hf isotopic composition of zircon(modified from Vervoort et al., 1996; Zhou et al., 2014)
图 10 锆石U-Yb(a)、U/Yb-Y（b）、U/Yb-Hf(c)关系图（底图引自Grimes et al., 2007）
Fig. 10. Plots of zircon U-Yb(a)、U/Yb-Y(b)、U/Yb-Hf(c)(modified from Grimes et al., 2007)
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