• 中国出版政府奖提名奖

    中国百强科技报刊

    湖北出版政府奖

    中国高校百佳科技期刊

    中国最美期刊

    留言板

    尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

    姓名
    邮箱
    手机号码
    标题
    留言内容
    验证码

    夏玉洪, 赖绍聪, 朱韧之, 2026. 单斜辉石矿物结构及化学特征在岩浆储运系统重建中的应用. 地球科学. doi: 10.3799/dqkx.2026.142
    引用本文: 夏玉洪, 赖绍聪, 朱韧之, 2026. 单斜辉石矿物结构及化学特征在岩浆储运系统重建中的应用. 地球科学. doi: 10.3799/dqkx.2026.142
    Xia Yuhong, Lai Shaocong, Zhu Renzhi, 2026. Textural and Chemical Characteristics of Clinopyroxene for the Reconstruction of Magma Plumbing System. Earth Science. doi: 10.3799/dqkx.2026.142
    Citation: Xia Yuhong, Lai Shaocong, Zhu Renzhi, 2026. Textural and Chemical Characteristics of Clinopyroxene for the Reconstruction of Magma Plumbing System. Earth Science. doi: 10.3799/dqkx.2026.142

    单斜辉石矿物结构及化学特征在岩浆储运系统重建中的应用

    doi: 10.3799/dqkx.2026.142
    基金项目: 

    国家自然科学基金项目(Nos.42172056,42472085)。

    详细信息
      作者简介:

      夏玉洪(1998-),男,博士研究生,从事岩浆岩岩石学研究。ORCID:0009-0003-5743-8839.E-mail:xiayhgeo@163.com

      通讯作者:

      赖绍聪(1963-),男,教授,从事岩浆岩岩石学研究。ORCID:000-0003-0629-2748.E-mail:shaocong@nwu.edu.cn;朱韧之(1989-),男,教授,从事岩浆岩岩石学研究。ORCID:0000-0001-5433-9585.E-mail:rzzhunwu@163.com

      赖绍聪(1963-),男,教授,从事岩浆岩岩石学研究。ORCID:000-0003-0629-2748.E-mail:shaocong@nwu.edu.cn;朱韧之(1989-),男,教授,从事岩浆岩岩石学研究。ORCID:0000-0001-5433-9585.E-mail:rzzhunwu@163.com

    • 中图分类号: P571;P581

    Textural and Chemical Characteristics of Clinopyroxene for the Reconstruction of Magma Plumbing System

    • 摘要: 破译岩浆储运系统对于揭示幔源岩浆岩成因、演化及相关资源环境效应具有重要的意义。单斜辉石是岩浆岩中的常见造岩矿物,对其结晶时的物理化学条件极其敏感,是重建岩浆储运系统的重要载体。本文综述了单斜辉石所能揭露的主要岩石学信息,包括:矿物晶体成因、结构特征记录的岩浆过程、结晶物理化学条件(P-T-H2O-fO2)、元素扩散记录的时间尺度、微量元素反映的源区信息。综合利用这些信息,可以重建幔源岩浆从源区到浅表所经历的岩浆储运系统,并识别其中的岩浆演化过程,为幔源岩浆演化提供矿物学尺度的证据。未来研究应致力于提升单斜辉石温压计、湿度计及氧逸度计的精度与适用范围,并拓展其原位同位素分析体系;同时,将研究对象扩展至不同构造背景及不同种类岩石及地外样品,为深入理解地球乃至行星尺度的岩浆演化过程提供关键约束。

       

    • [1] Armienti, P., Perinelli, C., Putirka, K.D., 2013. A New Model to Estimate Deep-level Magma Ascent Rates, with Applications to Mt. Etna (Sicily, Italy).Journal of Petrology, 54(4): 795-813. https://doi.org/10.1093/petrology/egs085
      [2] Brugman, K.K., Till, C.B., 2019. A low-aluminum clinopyroxene-liquid geothermometer for high-silica magmatic systems.American Mineralogist, 104: 996-1004. https://doi.org/10.2138/am-2019-6842
      [3] Burchardt, S., 2018. Introduction to Volcanic and Igneous Plumbing Systems-Developing a Discipline and Common Concepts. In: Burkhardt, S. (ed.) Volcanic and Igneous Plumbing Systems. Amsterdam:Elsevier. https://doi.org/10.1016/B978-0-12-809749-6.00001-7
      [4] Cai, X.Y., Xu, Y., Yang, Z.N., et al., 2024. Genesis and tectonic significance of clinopyroxene from Neoproterozoic gabbro-diabase in Dahongshan area, northern margin of Yangtze Block.Acta Petrologica Sinica, 40(11): 3552-3567 (in Chinese with English abstract). https://doi: 10.18654/1000-0569/2024.11.13
      [5] Cameron, M., Papile, J.J., 1981. Structural and chemical variations in pyroxenes.American Mineralogist, 66: 1-50.
      [6] 0. https://doi.org/10.1016/S0012-821X(01)00582-9
      [7] Cao, Y.H., Xing, C.M., Wang, C.Y., 2023. Crystallization and Solidification of Poikilitic and Granular Rocks in the Ultramafic Sequence of the Xinjie Layered Intrusion (SW China): Constraints from Complex Growth Zoning of Clinopyroxene and Spatial Variation of Dihedral Angles.Journal of Petrology, 64(2): 1-24. https://doi.org/10.1093/petrology/egad007
      [8] Cao, Y.H., Xing, C.M., Wang, C.Y., et al., 2025. Determination of the oxidation state of iron in calcic pyroxene using the electron microprobe flank method.American Mineralogist, 110(8): 1257-1268. https://doi.org/10.2138/am-2024-9467
      [9] Caricchi, L., Blundy, J., 2015. The temporal evolution of chemical and physical properties of magmatic systems.Geological Society, London, Special Publications, 422: 1-15. https://doi.org/10.1144/SP422.11
      [10] 13-0895-0
      [11] Cashman, K.V., Sparks, R.S.J., Blundy, J.D., 2017. Vertically extensive and unstable magmatic systems: A unified view of igneous processes.Sciences, 355(6331): eaag3055. https://doi: 10.1126/science.aag3055
      [12] Chakraborty, S., 2008. Diffusion in solid silicates: A tool to track timescales of processes comes of age.Annual Review of Earth and Planetary Sciences, 36(1): 153-190. https://doi.org/10.1146/annurev.earth.36.031207.124125
      [13] Chen, H.B., Ji, W.Q., Zhang, S.H., 2022. The principles of diffusion chronometry and applications in magmatic systems.Acta Petrologica Sinica, 38(5): 1499-1511 (in Chinese with English abstract). https://doi: 10.18654/1000-0569/2022.05.14
      [14] Chen, S.J., Wang, M., Hou, T., et al., 2025. Sector-zoned clinopyroxene in alkaline basalts: insights from the Cenozoic Gelaoshan volcano, Datong Volcanic Field, North China Craton.Journal of Asian Earth Sciences, 285: 106562. https://doi.org/10.1016/j.jseaes.2025.106562
      [15] Chen, Z.X., Zeng, Z.G., Wang, X.Y., et al., 2020. Duration of magma chamber: Progress and prospect of element diffusion chronometry of minerals.Advances in Earth Science, 35(12): 1232-1242 (in Chinese with English abstract). https://doi: 10.11867/j.issn.1001-8166.2020.098
      [16] Class, C., Miller, D.M., Goldstein, S.L., et al., 2000. Distinguishing melt and fluid subduction components in Umnak volcanics, Aleutian arc.Geochemistry, Geophysics, Geosystems, 1(6). https://doi.org/10.1029/1999GC000010
      [17] Coltorti, M., Bonadiman, C., Hinton, R.W., et al., 1999. Carbonatite Metasomatism of the Oceanic Upper Mantle: Evidence from Clinopyroxenes and Glasses in Ultramafic Xenoliths of Grande Comore, Indian Ocean.Journal of Petrology, 40(1): 133-165. https://doi.org/10.1093/petroj/40.1.133
      [18] Costa, F., Shea, T., Ubide, T., 2020. Diffusion chronometry and the timescales of magmatic processes.Nature Reviews Earth & Environment, 1(4): 201-214. https://doi.org/10.1038/s43017-020-0038-x
      [19] Cottrell, E., Kelley, K.A., 2011. The oxidation state of Fe in MORB glasses and the oxygen fugacity of the upper mantle.Earth and Planetary Science Letters, 305(3-4): 270-282. https://doi.org/10.1016/j.epsl.2011.03.014
      [20] D’Orazio, M., Armienti, P., Cerretini, S., 1998. Phenocryst/matrix trace-element partition coefficients for hawaiite-trachyte lavas from the Ellittico volcanic sequence (Mt. Etna, Sicily, Italy).Mineralogy and Petrology, 64: 65-68. https://doi.org/10.1007/BF01226564
      [21] Dai, L.Q., Zhao, Z.F., Zheng, Y.F., et al., 2017. Geochemical Distinction between Carbonate and Silicate Metasomatism in Generating the Mantle Sources of Alkali Basalts.Journal of Petrology, 58(5): 863-884. https://doi.org/10.1093/petrology/egx038
      [22] Dai, L.Q., Zheng, F., Zhao, Z.F., et al., 2018. Geochemical insights into the lithology of mantle sources for Cenozoic alkali basalts in West Qinling, China.Lithos, 302-303: 86-98. https://doi.org/10.1016/j.lithos.2017.12.013
      [23] Dal Negro, A., Manoli, S., Secco, L., et al., 1989. Megacrystic clinopyroxenes from Victoria (Australia): crystal chemical comparisons of pyroxenes from high and low pressure regimes. EuropeanJournal of Mineralogy, 1(1): 105-121. https://doi: 10.1127/ejm/01/1/0105
      [24] Danyushevsky, L.V., 2001. The effect of small amounts of H2O on crystallisation of mid-ocean ridge and backarc basin magmas.Journal of Volcanology and Geothermal Research, 110(3-4): 265-280. https://doi.org/10.1016/S0377-0273(01)00213-X
      [25] Davidson, J.P., Tepley, F.J., 1997. Recharge in volcanic systems: Evidence from isotope profiles of phenocrysts.Science, 275(5301): 826-829. https://doi: 10.1126/science.275.5301.826
      [26] Davidson, J.P., Morgan, D.J., Charlier, B.L.A., et al., 2007. Microsampling and isotopic analysis of igneous rocks: Implications for the study of magmatic systems.Annual Review of Earth and Planetary Sciences, 35:273-311. https://doi.org/10.1146/annurev.earth.35.031306.140211
      [27] 24-07750-0
      [28] Deng, L.T., Li, C.W., Chen, S., et al., 2025. Construction of geological big data and machine learning -based high-precision clinopyroxene thermometer for basaltic magma.Journal of Chengdu University of Technology (Science & Technology Edition), 52(6):1196-1209 (in Chinese with English Abstract). https://doi: 10.12474/cdlgzrkx.2025092401
      [29] Di Stefano, F., Mollo, S., Ubide, T., et al., 2020. Mush cannibalism and disruption recorded by clinopyroxene phenocrysts at Stromboli volcano: New insights from recent 2003-2017 activity.Lithos, 360-361: 105440. https://doi.org/10.1016/j.lithos.2020.105440
      [30] Dimanov, A., Sautter, V., 2000. ‘average’ interdiffusion of (Fe, Mn)-Mg in natural diopside.European Journal Mineralogy, 12(4): 749-760. https://doi.org/10.1127/0935-1221/2000/0012-0749
      [31] Elliott, T., Plank, T., Zindler, A., et al., 1997. Element transport from slab to volcanic front at the Mariana arc.Journal of Geophysical Research: Solid Earth, 102(B7): 14991-15019. https://doi.org/10.1029/97JB00788
      [32] Fick, A., 1855. On liquid diffusion.The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, 10(63): 30-39. https://doi.org/10.1080/14786445508641925
      [33] Geng, X.L., Liang, Z.W., Zhang, W., et al., 2022. Formation of green-core clinopyroxene in continental basalts through magmatic differentiation and crustal assimilation: Insights from in-situ trace element and Pb isotopic compositions.Lithos, 410-411: 106587. https://doi.org/10.1016/j.lithos.2021.106587
      [34] Ginibre, C., Kronz, A., Wörner, G., 2002a. High-resolution quantitative imaging of plagioclase composition using accumulated backscattered electron images: new constraints on oscillatory zoning.Contributions to Mineralogy and Petrology, 142: 436-448. https://doi.org/10.1007/s004100100298
      [35] Ginibre, C., Wörner, G., Kronz, A., (2002b). Minor- and trace-element zoning in plagioclase: implications for magma chamber processes at Parinacota volcano, northern Chile.Contributions to Mineralogy and Petrology, 143: 300-315. https://doi.org/10.1007/s00410-002-0351-z
      [36] Guo, Z., Zhu, Y., Li, Y., et al., 2024. Microscopic mineralogy of zoned pyroxene in NWA 12522: Implications for the crystallization histories of the shergottites.Meteoritics & Planetary Science, 59(12): 3340-3352. https://doi.org/10.1111/maps.14283
      [37] Hammer, J.E., 2008. Experimental studies of the kinetics and energetics of magma crystallization.Reviews in mineralogy and geochemistry, 69(1): 9-59. https://doi.org/10.2138/rmg.2008.69.2
      [38] Higgins, O., Sheldrake, T., Caricchi, L., 2022. Machine learning thermobarometry and chemometry using amphibole and clinopyroxene: a window into the roots of an arc volcano (Mount Liamuiga, Saint Kitts).Contributions to Mineralogy and Petrology, 177: 10. https://doi.org/10.1007/s00410-021-01874-6
      [39] Hoernle, K., Tilton, G., Le Bas, M.J., et al., 2002. Geochemistry of oceanic carbonatites compared with continental carbonatites: mantle recycling of oceanic crustalcarbonate.Contributions to Mineralogy and Petrology, 142: 520-542. https://doi.org/10.1007/s004100100308
      [40] Holloway, J.R., 2004. Redox reactions in seafloor basalts: possible insights into silicic hydrothermal systems.Chemical Geology, 210(1-4): 225-230. https://doi.org/10.1016/j.chemgeo.2004.06.009
      [41] Hu, J.H., 2018. The studies of trace element partition coefficient and chemical zonation of the clinopyroxene implication for magma processes. Guiyang:Institute of Geochemistry, University of Chinese Academy of Sciences, 1-10. (in Chinese with English Abstract)
      [42] Jorgenson, C., Higgins, O., Petrelli, M., et al., 2022. A machine learning-based approach to clinopyroxene thermobarometry: model optimization and distribution for use in Earth sciences.Journal of Geophysical Research: Solid Earth, 127: e2021JB022904. https://doi.org/10.1029/2021JB022904
      [43] Jugo, P.J., Wilke, M., Botcharnikov, R.E., 2010. Sulfur K-edge XANES analysis of natural and synthetic basaltic glasses: Implications for S speciation and S content as function of oxygen fugacity.Geochimica et Cosmochimica Acta, 74(20): 5926-5938. https://doi.org/10.1016/j.gca.2010.07.022
      [44] Kirkpatrick, R.J., 1981. Kinetics of crystallization of igneous rocks. In Kinetics of geochemical processes.Reviews in Mineralogy and Geochemistry, 8: 321-395.
      [45] Lange, R.A., Carmichael, I.S.E., 1987. Densities of Na2O-nK2O-CaO-MgO-FeO-Fe2O3-Al2O3-TiO2-SiO2liquids: new measurements and derived partial molar properties.Geochimica et Cosmochimica Acta, 51: 2931-2946. https://doi.org/10.1016/0016-7037(87)90368-1
      [46] Li, P.Y., Jiang, Y., Zhao, K., et al., 2026. A new pair of lunar gabbroic meteorites record magma recharge at ∼ 3.0 Ga.Geochimica et Cosmochimica Acta, https://doi.org/10.1016/j.gca.2026.02.040
      [47] Li, X.Y., Zhang, C., 2023. Applications of big data and machine learning in mineralogy research.Bulletin of Mineralogy, Petrology and Geochemistry, 42(2): 253-266+252 (in Chinese with English Abstract). https://doi.org/10.19658/j.issn.1007-2802.2023.42.031
      [48] Li, Y., Wu, L.G., Li, X.H., 2024. Progress and prospects of diffusion chronometry.Acta Geologica Sinica, 98(3): 862-875 (in Chinese with English Abstract). https://doi.org/10.19762/j.cnki.dizhixuebao.2024064
      [49] Lin, J.M., Gao, J.F., Jiang, Y.C., et al., 2026. Methodological progress in magmatic water content quantification.Acta Petrologica Sinica, 42(3): 1139-1155 (in Chinese with English Abstract). https://doi.org/10.18654/1000-0569/2026.03.22
      [50] Liu, J.Q., Erdmann, S., Chen, L.H., et al., 2021. Petrological evidence for magma recharge and mixing beneath the Ma'anshan monogenetic volcano of Xiaogulihe in Northeast China.Lithos, 382-383: 105928. https://doi.org/10.1016/j.lithos.2020.105928
      [51] Liu, S.Q., Zheng, Y.C., Hou, Z.Q., et al., 2026. Clinopyroxene In Situ Sr Isotopic Evidence for Crustal Assimilation of Potassic-Ultrapotassic Mafic Magmas in the Southeastern Tibetan Plateau.Journal of Petrology, 67(2): egag016. https://doi.org/10.1093/petrology/egag016
      [52] Liu, M., Lai, S.C., Zhang, D., et al., 2023. Polybaric fractional crystallization-driven magma differentiation in continental arcs: Insights from the intrusive complex in Langshan arc, southeastern Central Asian Orogenic Belt.Lithos, 446-447: 107122. https://doi.org/10.1016/j.lithos.2023.107122
      [53] Lloyd, A.S., Ferriss, E., Ruprecht, P., et al., 2016. An Assessment of Clinopyroxene as a Recorder of Magmatic Water and Magma Ascent Rate.Journal of Petrology, 57(10): 1865-1886. https://doi.org/10.1093/petrology/egw058
      [54] Lu, C.M., Yao, J.H., Yang, Z.F., et al., 2025. Olivine phosphorus zonings reveal distinct magmatic processes of shield and volatile-rich rejuvenated lavas in Hawaiian Maui Island.Journal of Earth Science, doi: 10.1007/s12583-025-0280-8
      [55] Luo, B.J., Wang, Z.C., Song, J.L., et al., 2023. The magmatic architecture and evolution of the Chang’e-5 lunar basalts.Nature Geoscience, 16: 301-308. https://doi.org/10.1038/s41561-023-01146-x
      [56] Luo, D., Hou, T., Wang, X.D., et al. 2022. Effects of Cooling Processes of Basaltic Magma System on the Texture, Mineral Composition and Estimated Thermodynamic Parameters of the Basalt.Bulletin of Mineralogy, Petrology and Geochemistry, 41(4): 759-775+693 (in Chinese with English abstract). https://doi.org/10.19658/j.issn.1007-2802.2022.41.051
      [57] Luo, Z.H., Yang, Z.F., Dai, G., et al., 2013. Crystal populations of igneous rocks and their implications in genetic mineralogy.Geology in China, 40(1):176-181 (in Chinese with English Abstract). https://doi.org/10.12029/gc20130112
      [58] Ma, C.Q., Zou, B.W., Gao, K., et al., 2020. Crystal Mush Storage, Incremental Pluton Assemblyand Granitic Petrogenesis.Earth Science, 45(12): 4332-4351 (in Chinese with English Abstract). https: 10.3799/dqkx.2020.316
      [59] Ma, J.F., Zhao, T.P., Hou, T., et al., 2024. Mineral Textures and Chemistry Trace the Origin and Transcrustal Evolution of the Sanyuangou Syenite in Southern North China Craton.Journal of Petrology, 65(6): egae056. https://doi.org/10.1093/petrology/egae056
      [60] Ma, R., Bi, X.W., Xu, L.L., et al., 2025. Magmatic processes in the plumbing system of the Cenozoic ultrapotassic volcanic rocks in the southeastern Tibetan Plateau.Geological Society of America Bulletin, 137(3-4): 1095-1115. https://doi.org/10.1130/B37600.1
      [61] Magee, C., Stevenson, C.T.E., Ebmeier, S.K., et al., 2018. Magma Plumbing Systems: A Geophysical Perspective.Journal of Petrology, 59(6): 1217-1251. https://doi.org/10.1093/petrology/egy064
      [62] Masotta, M., Mollo, S., Freda, C., et al., 2013. Clinopyroxene-liquid thermometers and barometers specific to alkaline differentiated magmas.Contributions to Mineralogy and Petrology, 166: 1545-1561. https://doi.org/10.1007/s00410-013-0927-9
      [63] Masotta, M., Pontesilli, A., Mollo, S., et al., 2020. The role of undercooling during clinopyroxene growth in trachybasaltic magmas: Insights on magma decompression and cooling at Mt. Etna volcano.Geochimica et Cosmochimica Acta, 268: 258-276. https://doi.org/10.1016/j.gca.2019.10.009
      [64] Mathez, E.A., 1984. Influence of degassing on oxidation states of basaltic magmas.Nature, 310(5976): 371-375. https://doi.org/10.1038/310371a0
      [65] Miller, C., Schuster, R., Klötzli, U., et al., 1999. Post-Collisional Potassic and Ultrapotassic Magmatism in SW Tibet: Geochemical and Sr-Nd-Pb-O Isotopic Constraints for Mantle Source Characteristics and Petrogenesis.Journal of Petrology, 40(9): 1399-1424. https://doi.org/10.1093/petroj/40.9.1399
      [66] Mollo, S., Blundy, J., Scarlato, P., et al., 2018. An integrated P-T-H2O-lattice strain model to quantify the role of clinopyroxene fractionation on REE+Y and HFSE patterns of mafic alkaline magmas: Application to eruptions at Mt. Etna.Earth-Science Reviews, 185: 32-56. https://doi.org/10.1016/j.earscirev.2018.05.014
      [67] Mollo, S., Blundy, J., Scarlato, P., et al., 2013a. The partitioning of trace elements between clinopyroxene and trachybasaltic melt during rapid cooling and crystal growth.Contributions to Mineralogy and Petrology, 166: 1633-1654. https://doi.org/10.1007/s00410-013-0946-6
      [68] Mollo, S., Del Gaudio, P., Ventura, G., et al., 2010. Dependence of clinopyroxene composition on cooling rate in basaltic magmas: implications for thermobarometry.Lithos, 118: 302-312. https://doi.org/10.1016/j.lithos.2010.05.006
      [69] Mollo, S., Lanzafame, G., Masotta, M., et al., 2011. Cooling history of a dike as revealed by mineral chemistry: a case study from Mt. Etna volcano.Chemical Geology, 283: 261-273. https://doi.org/10.1016/j.chemgeo.2011.06.016
      [70] Mollo, S., Misiti, V., Scarlato, P., et al., 2012. The role of cooling rate in the origin of high temperature phases at the chilled margin of magmatic intrusions.Chemical Geology, 322-323: 28-46. https://doi.org/10.1016/j.chemgeo.2012.05.029
      [71] Mollo, S., Putirka, K., Misiti, V., et al., 2013b. A new test for equilibrium based on clinopyroxene-melt pairs: clues on the solidification temperatures of Etnean alkaline melts at post-eruptive conditions.Chemical Geology, 352: 92-100. https://doi.org/10.1016/j.chemgeo.2013.05.026
      [72] Mollo, S., Hammer, J.E., 2017. Dynamic crystallization in magmas.European Mineralogical Union Notes in Mineralogy, 16: 373-418. https://doi.org/10.1180/EMU-notes.16.12
      [73] Müller, T., Dohmen, R., Becker, H.W., et al., 2013. Fe-Mg interdiffusion rates in clinopyroxene: experimental data and implications for Fe-Mg exchange geothermometers.Contributions to Mineralogy and Petrology, 166: 1563-1576. https://doi.org/10.1007/s00410-013-0941-y
      [74] Neave, D.A., Maclennan, J., 2020. Clinopyroxene Dissolution Records Rapid Magma Ascent.Frontiers in Earth Science, 8: 188. https://doi.org/10.3389/feart.2020.00188
      [75] Neave, D.A., Putirka, K.D., 2017. A new clinopyroxene-liquid barometer, and implications for magma storage pressures under Icelandic rift zones.American Mineralogist, 102: 777-794. https://doi.org/10.2138/am-2017-5968
      [76] Neave, D.A., Stewart, A.G., Hartley, M.E., et al., 2024. Re-evaluating stoichiometric estimates of iron valence in magmatic clinopyroxene crystals.Contributions to Mineralogy and Petrology, 179: 5. https://doi.org/10.1007/s00410-023-02080-2
      [77] Ni, H.W., Zheng, Y.F., Mao, Z., et al., 2017. Distribution, cycling and impact of water in the Earth's interior.National Science Review, 4(6): 879-891. https://doi.org/10.1093/nsr/nwx130
      [78] Nimis, P., Taylor, W.R., 2000. Single clinopyroxene thermobarometry for garnet peridotites. Part I. Calibration and testing of a Cr-in-Cpx barometer and an enstatite-in-Cpx thermometer.Contributions to Mineralogy and Petrology, 139: 541-554. https://doi.org/10.1007/s004100000156
      [79] Nimis, P., Ulmer, P., 1998. Clinopyroxene geobarometry of magmatic rocks Part 1: An expanded structural geobarometer for anhydrous and hydrous, basic and ultrabasic systems.Contributions to Mineralogy and Petrology, 133: 122-135. https://doi.org/10.1007/s004100050442
      [80] Nimis, P., 1995. A clinopyroxene geobarometer for basaltic systems based on crystal-structure modeling.Contributions to Mineralogy and Petrology, 121: 115-125. https://doi.org/10.1007/s004100050093
      [81] Nimis, P., 1999. Clinopyroxene geobarometry of magmatic rocks. Part 2. Structural geobarometers for basic to acid, tholeiitic and mildly alkaline magmatic systems.Contributions to Mineralogy and Petrology, 135: 62-74. https://doi.org/10.1007/s004100050498
      [82] Pan, R.H., Hou, T., Wang, X.D., et al., 2022. Multiple Magma Storage Regions and Open System Processes Revealed by Chemistry and Textures of the Datong Tholeiitic Lavas, North China Craton.Journal of Petrology, 63(5): 1-34. https://doi.org/10.1093/petrology/egac034
      [83] Pan, S.K., Zheng, J.P., Yin, Z.W., et al., 2018. Spongy texture in mantle clinopyroxene records decompression-induced melting.Lithos, 320-321: 144-154. https://doi.org/10.1016/j.lithos.2018.08.035
      [84] Pearce, J.A., Peate, D.W., 1995. Tectonic implications of the composition of volcanic arc magmas.Annual Review of Earth and Planetary Sciences, 23: 251-285. https://doi.org/10.1146/annurev.ea.23.050195.001343
      [85] Pelullo, C., Chakraborty, S., Montagna, C.P., et al., 2024. A multi-methodological approach to record dynamics and timescales of the plumbing system of Zaro (Ischia Island, Italy).Contributions to Mineralogy and Petrology, 179: 54. https://doi.org/10.1007/s00410-024-02138-9
      [86] Perinelli, C., Mollo, S., Gaeta, M., et al., 2016. An improved clinopyroxene-based hygrometer for Etnean magmas and implications for eruption triggering mechanisms.American Mineralogist, 101(12): 2774-2777. https://doi.org/10.2138/am-2016-5916
      [87] Petrelli, M., Caricchi, L., Perugini, D., 2020. Machine learning thermo-barometry: application to clinopyroxene-bearing magmas.Journal of Geophysical Research: Solid Earth, 125: e2020JB020130. https://doi.org/10.1029/2020JB020130
      [88] Petrelli, M., 2024. Machine Learning in Petrology: State-of-the-Art and Future Perspectives.Journal of Petrology, 65(5): egae036. https://doi.org/10.1093/petrology/egae036
      [89] Petrone, C.M., Braschi, E., Francalanci, L., et al., 2018. Rapid mixing and short storage timescale in the magma dynamics of a steady-state volcano.Earth and Planetary Science Letters, 492: 206-221. https://doi.org/10.1016/j.epsl.2018.03.055
      [90] Petrone, C.M., Bugatti, G., Braschi, E., et al., 2016. Pre-eruptive magmatic processes re-timed using a non-isothermal approach to magma chamber dynamics.Nature Communications, 7(1): 12946. https://doi.org/10.1038/ncomms12946
      [91] Petrone, C.M., Mollo, S., Gertisser, R., et al., 2022. Magma recharge and mush rejuvenation drive paroxysmal activity at Stromboli volcano.Nature Communications, 13: 7717. https://doi.org/10.1038/s41467-022-35405-z
      [92] Pontesilli, A., Masotta, M., Nazzari, M., et al., 2019. Crystallization kinetics of clinopyroxene and titanomagnetite growing from a trachybasaltic melt: New insights from isothermal time-series experiments.Chemical Geology, 510: 113-129. https://doi.org/10.1016/j.chemgeo.2019.02.015
      [93] Prelević, D., Akal, C., Foley, S.F., et al., 2012. Ultrapotassic Mafic Rocks as Geochemical Proxies for Post-collisional Dynamics of Orogenic Lithospheric Mantle: the Case of Southwestern Anatolia, Turkey.Journal of petrology, 53(5): 1019-1055. https://doi.org/10.1093/petrology/egs008
      [94] Putirka, K., Johnson, M., Kinzler, R., et al., 1996. Thermobarometry of mafic igneous rocks based on clinopyroxene-liquid equilibria, 0-30 kbar.Contributions to Mineralogy and Petrology, 123(1): 92-108. https://doi.org/10.1007/s004100050145
      [95] Putirka, K., 1999. Clinopyroxene + liquid equilibria to 100 kbar and 2450 K.Contributions to Mineralogy and Petrology, 135(2-3): 151-163. https://doi.org/10.1007/s004100050503
      [96] Putirka, K.D., Mikaelian, H., Ryerson, F., et al., 2003. New clinopyroxene-liquid thermobarometers for mafic, evolved, and volatile-bearing lava compositions, with applications to lavas from Tibet and the Snake River Plain, Idaho.American Mineralogist, 88(10): 1542-1554 https://doi.org/10.2138/am-2003-1017
      [97] Putirka, K.D., 2008. thermometers and Barometers for Volcanic Systems.Reviews in Mineralogy & Geochemistry, 69: 61-120. https://doi.org/10.2138/rmg.2008.69.3
      [98] Robie, R.A., Hemingway, B.S., Fisher, J.R., 1979. Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and at higher temperatures.US Geological Survey Bulletin, 1452: 456. https://doi.org/10.3133/b2131
      [99] Roeder, P.L., Emslie, R.F., 1970. Olivine-liquid equilibrium.Contributions to Mineralogy and Petrology, 29: 275-289. https://doi.org/10.1007/BF00371276
      [100] Rudnick, R.L., McDonough, W.F., Chappell, B.W., 1993. Carbonatite metasomatism in the northern Tanzanian mantle: petrographic and geochemical characteristics.Earth and Planetary Science Letters, 114: 463-475. https://doi.org/10.1016/0012-821X(93)90076-L
      [101] Salviulo, G., Secco, L., Marzoli, A., et al., 2000. Ca-rich pyroxene from basic and silicic volcanic rocks from the Cameroon Volcanic Line (West-Africa): crystal chemistry and petrological relationships.Mineralogy and Petrology, 70: 73-88. https://doi.org/10.1007/s007100070014
      [102] Sang, L.K., Ma, C.Q., Wang, G.Q., et al., 2012. Petrology (3rd ed.).Beijing: Geological Publishing House, 50-60 (in Chinese).
      [103] Schweitzer, E.L., Papike, J.J., Bence, A.E., 1979. Statistical analysis of clinopyroxenes from deep-sea basalts.American Mineralogist, 64(5-6): 501-513.
      [104] Shi, Y.N., Zhang, Z.C., Cheng, Z.G., et al., 2026. Microtextural Evidence for Magma Mixing in the Petrogenesis of Melilite-Bearing Nephelinite from Southeast China.Journal of Petrology, 67(2): egag018. https://doi.org/10.1093/petrology/egag018
      [105] Simpson, B., Ubide, T., Spandler, C., 2025. Drivers of critical metal enrichment in peralkaline magmas recorded by clinopyroxene zoning.Communications Earth & Environment, 6: 89. https://doi.org/10.1038/s43247-025-02040-7
      [106] Soesoo, A., 1997. A multivaiate statistical analysis of clinopyroxene composition: empirical coordinates for the crystallisation PT-estimations.GFF, 119(1): 55-60. https://doi.org/10.1080/11035899709546454
      [107] Sparks, R.S.J., Annen, C., Blundy, J.D., et al., 2019. Formation and dynamics of magma reservoirs.Philosophical Transactions of the Royal Society A, 377: 20180019. https://doi.org/10.1098/rsta.2018.0019
      [108] Streck, M.J., 2008. Mineral textures and Zoning as evidence for Open System Processes.Reviews in Mineralogy & Geochemistry, 69: 595-622. https://doi.org/10.2138/rmg.2008.69.15
      [109] Su, B.X., Zhang, H.F., Sakyi, P.A., et al., 2011. The origin of spongy texture in minerals of mantle xenoliths from the Western Qinling, central China.Contributions to Mineralogy and Petrology, 161(3): 465-482. https://doi.org/10.1007/s00410-010-0543-x
      [110] Sun, C., Liang, Y., 2014. An assessment of subsolidus re-equilibration on REE distribution among mantle minerals olivine, orthopyroxene, clinopyroxene, and garnet in peridotites.Chemical Geology, 372: 80-91. https://doi.org/10.1016/j.chemgeo.2014.02.014
      [111] Szabó, C., Bodnar, R.J., 1998. Fluid-inclusion evidence for an Upper-Mantle origin for green clinopyroxenes in late cenozoic basanites from the Nógrád-Gömör Volcanic Field, Northern Hungary/Southern Slovakia.International Geology Review, 40(9): 765-773. https://doi.org/10.1080/00206819809465237
      [112] Tang, M., Erdman, M., Eldridge, G., et al., 2018. The redox "filter" beneath magmatic orogens and the formation of continental crust.Science Advances, 4(5): eaar4444. https://doi.org/10.1126/sciadv.aar4444
      [113] Tian, Y., Hou, T., 2022. Theoretical Basis and Geological Application of Fe-Mg Interdiffusion of Olivine in Magmatic System.Geotectonica et Metallogenia, 46(4): 814-828 (in Chinese with English Abstract). https://doi.org/10.16539/j.ddgzyckx.2022.02.015
      [114] Ubide, T., Kamber, B.S., 2018. Volcanic crystals as time capsules of eruption history.Nature Communications, 9: 326. https://doi.org/10.1038/s41467-017-02274-w
      [115] Ubide, T., Márquez, Á., Ancochea, E., et al., 2023. Discrete magma injections drive the 2021 La Palma eruption.Science Advances, 9(27): eadg4813. https://doi.org/10.1126/sciadv.adg4813
      [116] Ubide, T., McKenna, C.A., Chew, D.M., et al., 2015. High-resolution LA-ICP-MS trace element mapping of igneous minerals: in search of magma histories.Chemical Geology, 409: 157-168. https://doi.org/10.1016/j.chemgeo.2015.05.020
      [117] Ubide, T., Mollo, S., Zhao, J.X., et al., 2019. Sector-zoned clinopyroxene as a recorder of magma history, eruption triggers, and ascent rates.Geochimica et Cosmochimica Acta, 251: 265-283. https://doi.org/10.1016/j.gca.2019.02.021
      [118] Velde, B., Kushiro, I., 1978. Structure of sodium alumino-silicate melts quenched at high pressure; infrared and aluminum K-radiation data.Earth and Planetary Science Letters, 40(1): 137-140. https://doi.org/10.1016/0012-821X(78)90083-3
      [119] Wang, J.T., Xiong, X.L., Takahashi, E., et al., 2019. Oxidation state of arc mantle revealed by partitioning of V, Sc and Ti between mantle minerals and basaltic melts.Journal of Geophysical Research: Solid Earth, 124: 4617-4638. https://doi.org/10.1029/2018JB016731
      [120] Wang, X.D., Hou, T., Wang, M., et al., 2021. A new clinopyroxene thermobarometer for mafic to intermediate magmatic systems.European Journal of Mineralogy, 33(5): 621-637. https://doi.org/10.5194/ejm-33-621-2021
      [121] Wang, X.D., Hou, T., Wieser, P.E., et al., 2025. Thermodynamic insights into the reliability of mineral-based thermobarometers.Communications earth & environment, 6: 913. https://doi.org/10.1038/s43247-025-02831-y
      [122] Wang, Z.Z., Liu, J., Xia, Q.K., et al., 2020. The distribution of water in the early Cretaceous lithospheric mantle of the North China Craton and implications for its destruction.Lithos, 360-361: 105412. https://doi.org/10.1016/j.lithos.2020.105412
      [123] 937(79)90043-4
      [124] Wei, B.W., Zhang, Z.C., Zhang, R.X., et al., 2026. Machine learning clinopyroxene hygrometry reveals slab-driven mantle hydration in the genesis of the Emeishan large igneous province, southwestern China.Geological Society of America Bulletin, https: //doi.org/10.1130/B38504.1
      [125] 23-99762-1.00024-3
      [126] Xia, Y.H., Lai, S.C., Yang, H., et al., 2024. Liquid immiscibility acting on the formation of the Miaoya carbonatite-syenite complex in the South Qinling Belt, Central China.Journal of Asian Earth Science, 264: 106072. https://doi.org/10.1016/j.jseaes.2024.106072
      [127] Xia, Y.H., Lai, S.C., Zhu, R.Z., et al., 2026. Clinopyroxene diversity reveals open magma plumbing system and melts variation of Haoti Cenozoic melilitites, northeastern Tibetan Plateau.Journal of Petrology, egag025. https://doi.org/10.1093/petrology/egag025
      [128] Xie, Y.H., Shan, W., Yu, X.F., et al., 2021. Identification of clinopyroxene antecrysts in Cretaceous lamprophyre dykes from the Jiaodong Peninsula and their geological significance.Acta Petrologica Sinica, 37(7): 2203-2233 (in Chinese with English Abstract). https://doi.org/10.18654/1000-0569/2021.07.14
      [129] Xin, Y., Xue, S.C., Wang, X.S., et al., 2023. Progress and prospect of the oxidation state of magmas in convergent tectonic settings.Acta Petrologica Sinica, 39(9): 2817-2831 (in Chinese with English Abstract). https://doi.org/10.18654/1000-0569/2023.09.16
      [130] Xing, C.M., Wang, C.Y., 2020. Periodic Mixing of Magmas Recorded by Oscillatory Zoning of the Clinopyroxene Macrocrysts from an Ultrapotassic Lamprophyre Dyke.Journal of Petrology, 61: 11-12. https://doi.org/10.1093/petrology/egaa103
      [131] Xing, C.M., Wang, C.Y., Charlier, B., 2022. Ubiquitous dendritic olivine constructs initial crystal framework of mafic magma chamber.Earth and Planetary Science Letters, 594: 117710. https://doi.org/10.1016/j.epsl.2022.117710
      [132] Yang, H., 2023. Magmatic-Hydrothermal Evolution of Early Paleozoic Alkaline Rocks in South Qinling Belt and its implication for Nb-REE enrichment. Xi'an:Northwest University, 52-56. (in Chinese with English Abstract)
      [133] Yang, H.X., Konzett, J., Frost, D.J., et al., 2009. X-ray diffraction and Raman spectroscopic study of clinopyroxenes with six-coordinated Si in the Na(Mg0.5Si0.5)Si2O6-NaAlSi2O6system.American Mineralogist, 94: 942-949. https://doi.org/10.2138/am.2009.3084
      [134] Yang, Z.P., Hou, T., Wang, D.C., et al., 2022. The Role of Magma Mixing in the Petrogenesis of Eocene Ultrapotassic Lavas, Western Yunnan, SW China.Journal of Petrology, 64(2): egac129. https://doi.org/10.1093/petrology/egac129
      [135] Zhang, C., Li, X.Y., 2025. Review of the principel and method for EPMA in-situ analysis of Fe oxidation state.Journal of Northwest University (Natural Science Edition), 55(3): 585-600 (in Chinese with English Abstract). https://doi.org/10.16152/j.cnki.xdxbzr.2025-03-008
      [136] Zhang, F.Y., Lai, S.C., Qin, J.F., et al., 2020. Vein-plus-wall rock melting model for the origin of Early Paleozoic alkali diabases in the South Qinling Belt, Central China. Lithos, 370-371: 105619. https://doi.org/10.1016/j.lithos.2020.105619
      [137] Zhang, F.Y., Lai, S.C., Stagno, V., et al., 2024b. The Redox State of the Asthenospheric Mantle and the Onset of Melting Beneath Mid-Ocean Ridges.Journal of Geophysical Research: Solid Earth, 129: e2023JB027033. https://doi.org/10.1029/2023JB027033
      [138] Zhang, F.Y., Lai, S.C., Zhu, R.Z., et al., 2025. Trace Elements in Olivine Reveal Lithological and Redox Heterogeneity in the Mantle Source of Carbonated Silicate Melts: Constraints from Cenozoic Melilitites in the West Qinling Orogen, China.Journal of Petrology, 66(9): egaf081. https://doi.org/10.1093/petrology/egaf081
      [139] Zhang, F.Y., 2022. The Oxygen Fugacity of Mantle-derived Magmas: Constrtaints from Olivine and Clinopyroxene Oxybarometers. Xi'an:Northwest University, 14-84. (in Chinese with English Abstract)
      [140] Zhang, G.K., Li, X.W., Xu, J.F., et al., 2024a. Multiple magmatic processes revealed by distinct clinopyroxene populations in the magma plumbing system: a case study from the Miocene volcano in West Qinling, Central China.American Mineralogist, 109(3): 540-555. https://doi.org/10.2138/am-2022-8744
      [141] Zhang, S.T., Long, X.P., Zhang, F.Y., et al., 2023. Transcrustal magma plumbing process in the Cenozoic Dali potassic lamprophyre dyke formation in the southeastern Tibet Plateau.Lithos, 454-455: 107281. https://doi.org/10.1016/j.lithos.2023.107281
      [142] Zhao S.R., 2017. Crystallography and Mineralogy (3rd ed.). Beijing: Higher Education Press, 316-353. (in Chinese)
      [143] Zhou, J.S., Wang, Q., Xing, C.M., et al., 2021. Crystal growth of clinopyroxene in mafic alkaline magmas.Earth and Planetary Science Letters, 568: 117005. https://doi.org/10.1016/j.epsl.2021.117005
      [144] Zhu, R. Z., Smith, D. J., Wang, F. Y., et al., 2024. Hornblendites as a record of differentiation, metasomatism and magma fertility in arc crust.Chemical Geology, 650: 121974. https://doi.org/10.1016/j.chemgeo.2024.121974
      [145] Zhu, S.Z., Huang, X.L., Yu, Y., et al., 2023. Enrichment of Incompatible Elements in Alkaline Syenites in Large Igneous Provinces Due to Magma Replenishment and Reactive Porous Flow in a Mush Reservoir.Journal of Petrology, 64: 1-26. https://doi.org/10.1093/petrology/egad002
      [146] 蔡晓芸, 徐扬, 杨振宁, 等, 2024. 扬子北缘大洪山地区新元古代辉长辉绿岩中单斜辉石成因及其构造意义. 岩石学报, 40(11): 3552-3567.
      [147] 陈厚彬, 纪伟强, 张少华, 2022. 扩散年代学原理及其在岩浆体系研究中的应用. 岩石学报, 38(05): 1499-1511.
      [148] 陈祖兴, 曾志刚, 王晓媛, 等, 2020. 岩浆房持续的时间: 矿物内元素扩散年代学研究进展及展望. 地球科学进展, 35(12): 1232-1242.
      [149] 邓李涛, 李晨伟, 陈思, 等, 2025. 基于地质大数据和机器学习的基性岩浆单斜辉石高精度温度计构建. 成都理工大学学报(自然科学版), 56(6): 1196-1209.
      [150] 胡君豪, 2018. 单斜辉石微量元素分配系数及成分环带岩浆过程示踪研究. 贵阳: 中国科学院地球化学研究所. 中国科学院大学, 1-10.
      [151] 李晓彦, 张超, 2023. 大数据和机器学习在矿物学研究中的应用. 矿物岩石地球化学通报, 42(2): 253-266+252.
      [152] 李扬, 吴黎光, 李献华, 2024. 扩散年代学:进展与展望. 地质学报, 98(3): 862-875.
      [153] 林嘉敏, 高建峰, 姜懿宸, 等, 2026. 岩浆水含量估算方法研究进展. 岩石学报, 42(3): 1139-1155.
      [154] 罗雕, 侯通, 王旭东, 等, 2022. 冷却过程对玄武岩体系结构、矿物成分以及热力学参数估算的影响. 矿物岩石地球化学通报, 41(4): 759-775+693.
      [155] 罗照华, 杨宗锋, 代耕, 等, 2013. 火成岩的晶体群与成因矿物学展望. 中国地质, 40(1):176-181.
      [156] 马昌前, 邹博文, 高珂, 等, 2020. 晶粥储存、侵入体累积组装与花岗岩成因. 地球科学, 45(12): 4332-4351.
      [157] 桑隆康, 马昌前, 王国庆, 等, 2012. 岩石学(第二版). 北京: 地质出版社, 50-60.
      [158] 田野, 侯通, 2022. 岩浆系统橄榄石Fe-Mg互扩散的理论基础及其地质应用. 大地构造与成矿学, 46(4): 814-828.
      [159] 谢元惠, 单伟, 于学峰, 等, 2021. 胶东白垩纪煌斑岩中单斜辉石再循环晶的识别及其地质意义. 岩石学报, 37(7): 2203-2233.
      [160] 辛雨, 薛胜超, 王信水, 等, 2023. 汇聚环境岩浆氧化态来源的进展与展望. 岩石学报, 39(9): 2817-2831.
      [161] 杨航, 2023. 南秦岭早古生代碱性岩类岩浆-热液演化及其对铌-稀土元素富集的指示. 西安: 西北大学, 52-56.
      [162] 张超, 李晓彦, 2025. 电子探针Fe价态原位分析的原理和方法. 西北大学学报(自然科学版), 55(3): 585-600.
      [163] 张方毅, 2022. 幔源岩浆的氧逸度: 来自橄榄石和单斜辉石氧逸度计的约束. 西安: 西北大学, 14-84.
      [164] 赵珊茸, 2017. 结晶学及矿物学(第三版). 北京: 高等教育出版社, 316-353.
    • 加载中
    计量
    • 文章访问数:  70
    • HTML全文浏览量:  0
    • PDF下载量:  13
    • 被引次数: 0
    出版历程
    • 收稿日期:  2026-03-24
    • 网络出版日期:  2026-06-29

    目录

      /

      返回文章
      返回