方钠石族矿物的结构构造和化学成分变化研究

梁馨心; 王连训; 邵辉; 佘振兵; 徐畅

doi:10.3799/dqkx.2025.068

方钠石族矿物的结构构造和化学成分变化研究

doi: 10.3799/dqkx.2025.068

梁馨心^1, ,,
王连训^{1, 2, , ,},
邵辉¹,
佘振兵¹,
徐畅¹

1.
中国地质大学地球科学学院, 湖北武汉 430074
2.
中国地质大学地质过程与成矿预测国家重点实验室, 湖北武汉 430074

基金项目:

国家自然科学基金项目 42072082

地质过程与矿产资源国家重点实验室开放研究基金项目 GPMR202441

中国地质大学(武汉)中央高校基本科研业务费资助项目 2024XLB36

详细信息

作者简介:
梁馨心(2002-)，女，地质学专业. ORCID：0009-0007-8516-132X. E-mail：liangxinxin@cug.edu.cn

通讯作者:
王连训，ORCID: 0000-0002-5389-6782. E-mail: lianxunwang@cug.edu.cn

中图分类号: P571;P586
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出版历程
- 收稿日期: 2025-01-12
- 刊出日期: 2025-08-25

Textural and Compositional Variation of the Sodalite Group Minerals

Liang Xinxin^{1
,
,},
Wang Lianxun^{1, 2
, ,
,},
Shao Hui¹,
She Zhenbing¹,
Xu Chang¹

1.
School of Earth Science, China University of Geosciences, Wuhan 430074, China
2.
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China

摘要

摘要: 方钠石族矿物(SGM)主要包括方钠石、蓝方石、黝方石等，是一种常产出于碱性-过碱性岩浆岩中并富含挥发性元素(如S、Cl等)的铝硅酸盐矿物. 目前，SGM的研究程度极低，特别是关于其结构构造和化学成分变化方面的研究资料非常有限，这严重制约了对该族矿物分类命名和形成机制的理解. 选取四川坪河、江苏娘娘山、苏丹敦比尔地区碱性杂岩体中的SGM，并系统收集全球其他地区的该族矿物研究资料，开展了细致的岩相学和矿物化学方面的对比分析. 提出一种利用SO₄^2-/X(X=阴离子的apfu值)及X值对该族矿物种属进行有效区分的方法. 从方钠石到黝方石再到蓝方石，矿物中的Rb/Sr、Ba/Sr、Be/Sr、B/Sr随着Sr含量增加而显著降低；而总稀土含量与轻、重稀土分异程度依次升高. 方钠石中S/Cl比值可以用来约束岩浆性质，Cl⁃S含量可以反演岩浆演化过程中熔体挥发分的变化情况. 蓝方石中常发育的“格子状构造”和黝方石中的“补丁构造”推测分别为包裹体成因及固态出溶成因. 加强了对方钠石族矿物成因机制的理解，为该族矿物分类定名提供了一个新框架，并强调了该族矿物挥发性元素、结构特征和地球化学演化之间的相互关系.
- 方钠石 /
- 黝方石 /
- 蓝方石 /
- 矿物化学 /
- 挥发分 /
- 格子状构造 /
- 补丁构造 /
- 矿物学
Abstract: The sodalite group minerals (SGM), including sodalite, haüyne, nosean, and related species, are aluminium silicate minerals that typically crystallize in alkaline⁃peralkaline rocks and are enriched in volatile elements such as sulfur (S) and chlorine (Cl). Despite their geochemical significance, research on SGM remains limited, particularly regarding their textural characteristics and geochemical compositions, which has hindered a comprehensive understanding of their classification and formation mechanisms. A detailed comparative study of the petrography and geochemistry of SGM samples was conducted, focusing on specimens from the Pinghe Complex (Sichuan Province, China), Niangniangshan Complex (Jiangsu Province, China), and Jebel Dumbier Complex (Sudan). This analysis was complemented by incorporating global SGM datasets to enhance the scope and robustness of the findings. A novel classification scheme for SGM species is proposed, based on the SO₄^2-/X ratios (where X represents the anion content in atoms per formula unit, apfu) and X values. This framework distinguishes sodalite, nosean, and haüyne along a continuum of geochemical evolution. From sodalite to nosean and finally to haüyne, the ratios of Rb/Sr, Ba/Sr, Be/Sr, and B/Sr decrease progressively as Sr content increases. Conversely, total rare earth element (REE) concentrations and the degree of differentiation between light rare earth elements (LREE) and heavy rare earth elements (HREE) increase systematically. The S/Cl ratios in sodalite serve as a proxy for magma composition, while variations in Cl and S compositions reflect changes in melt volatile content during magmatic evolution. The clathrate texture observed in haüyne and the patchy texture in nosean are interpreted as resulting from mineral inclusions and solid exsolution processes, respectively. This study advances the understanding of SGM formation mechanisms and provides a refined framework for their classification, emphasizing the interplay between volatile elements, textural features, and geochemical evolution.
- sodalite /
- nosean /
- haüyne /
- mineral chemistry /
- volatile /
- clathrate texture /
- patchy texture /
- mineralogy
注释:

1) 附件见：https://doi.org/10.3799/dqkx.2025.068

HTML全文

图 1 研究区域地质简图

a. 四川坪河碱性杂岩体地质简图(据何利，2010修改)；b. 江苏娘娘山碱性杂岩体地质简图(据史磊，2014；霍海东，2024修改)；c. 苏丹敦比尔碱性杂岩体地质简图(据Harris et al.，1983修改)

Fig. 1. Sketch maps of study areas

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图 2 方钠石族矿物产出岩石TIMA图像

a. 四川坪河方钠磷霞岩TIMA图像；b. 四川坪河方钠磷霞岩局部TIMA图像；c. 苏丹敦比尔霓辉石霞石正长岩TIMA图像；d. 苏丹敦比尔霓辉石霞石正长岩局部TIMA图像

Fig. 2. TIMA images of SGM⁃bearing rocks

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图 3 坪河方钠石岩相学特征

Cal.方解石；Ccn.钙霞石；Ne.霞石；Sdl.方钠石

Fig. 3. Petrography of Pinghe sodalite

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图 4 娘娘山蓝方石岩相学特征

Act. 阳起石；Fl. 萤石；Hem. 赤铁矿；Hyn. 蓝方石；Mag. 磁铁矿；Or. 正长石；Pyh. 磁黄铁矿；Ttn. 榍石

Fig. 4. Petrography of Niangniangshan haüyne

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图 5 敦比尔方钠石族矿物岩相学特征

Agt. 霓辉石；Nsn. 黝方石；Pth. 条纹长石；Py. 黄铁矿；Sdl. 方钠石

Fig. 5. Petrography of Dumbier nosean

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图 6 方钠石族矿物主量元素图解

a. K₂O⁃Na₂O⁃CaO图解(Lessing and Grout, 1971)；b. Na⁃(Ca+K)图解(改自Balassone et al.，2012)；c. Cl+F⁃SO₄^2⁃图解(改自Balassone et al.，2012)；d. 基于阴离子相对含量的方钠石族矿物分类图；引用数据参考文献见附表3

Fig. 6. The diagrams of major elements of SGM

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图 7 方钠石族矿物微量元素图解

a.Rb/Sr图解；b. Ba/Sr图解；c. Be/Sr⁃Sr图解；d. B/Sr⁃Sr图解；e. 总稀土元素含量箱线图；f. 轻、重稀土元素含量箱线图；引用数据参考文献见附表5

Fig. 7. The diagrams of trace elements of SGM

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图 8 方钠石S、Cl含量图解

伊利莫萨克方钠石数据引自Eggenkamp et al. (2020)；其中方钠-流霞正长岩，方钠霞石正长岩，条纹霞石正长岩，热液方钠石样品地点：伊利莫萨克

Fig. 8. The diagram of S and Cl contents of sodalite

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图 9 岩浆结晶过程中Cl含量变化模式图

Ap. 磷灰石；Bt. 黑云母；Cpx. 单斜辉石(包括透辉石、霓辉石)；Fsp. 长石；Hyn. 蓝方石；Ne. 霞石；Nsn. 黝方石；Or. 正长石；Pl. 斜长石；Ri. 钠闪石；Sdl. 方钠石

Fig. 9. The model of Cl contents variation during magmatic process

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图 10 娘娘山蓝方石BSE图像及元素分布图

Act. 阳起石；Fl. 萤石；Hem. 赤铁矿；Hyn. 蓝方石；Mag. 磁铁矿；Ttn. 榍石

Fig. 10. BSE and elements distribution images of Niangniangshan haüyne

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图 11 方钠石族矿物构造与成分变化图解

a. 蓝方石SO₄^2-/X⁃Fe²⁺/M图解；b. 蓝方石与赋存岩石FeO含量箱线图(箭头代表实际FeO含量略低)；c. 黝方石SO₄^2-/X⁃Cl^-/X图解；文献蓝方石数据引自Bellatreccia (2009)；Baudouin and Parat(2015)；娘娘山响岩全岩数据史磊(2014)；德国拉赫湖响岩全岩数据引自Baudouin and Parat (2015)；意大利兀鹫山蓝方石斑岩全岩数据引自Beccaluva et al. (2002)；主晶黝方石文献数据引自Suk et al. (2007)；无嵌晶黝方石数据引自Balassone et al. (2012)；Balassone et al. (2016)

Fig. 11. The diagrams of textural and composition change of SGM

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图 12 敦比尔黝方石BSE图像及元素分布图

Nsn. 黝方石；Pth. 条纹长石；Py. 黄铁矿；Sdl. 方钠石；Ttn. 榍石

Fig. 12. BSE and elements distribution images of Dumbier nosean

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图 13 格子状构造、补丁构造成因模式图

Fig. 13. The model of clathrate texture and patchy texture

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梁馨心附图1-方钠石族矿物分布.docx
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梁馨心附件2-测试分析方法.docx
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